ABSTRACT
It has become necessary to develop effective strategies to prevent and reduce water pollution as a result of the increase in dangerous pollutants in water reservoirs. Consequently, there is a need to design new catalyst materials to promote the efficiency of advanced oxidation processes (AOPs) in the field of wastewater treatment plant to ensure the mineralization of trace organic contaminants. A notable approach gaining attention involves the coupling of sulfate radicals-based AOPs to photocatalysis or electrocatalysis processes, aiming to achieve the complete removal of refractory contaminants into water and carbon dioxide. Titanium dioxide as metal oxide has received great attention for its catalytic application in water purification. TiO2 catalysts offer a multitude of advantages in AOPs. They are characterized by their high photocatalytic activity under both ultraviolet and visible light, making them environmentally friendly due to the absence of toxic byproducts during oxidation. Their versatility is remarkable, finding utility in various AOPs, from photocatalysis to photo-Fenton processes. TiO2's durability ensures long-lasting catalytic activity, which is crucial for continuous treatment processes, and their cost-effectiveness is particularly advantageous. Furthermore, their chemical stability allows it to withstand varying pH conditions. However, the large band gap energy and low electrical conductivity hinder the catalytic reaction effectiveness. This review aims to examine various approaches to enhance the catalytic performance of titanium dioxide, with the objective of enabling more efficient water purification methods.
ABSTRACT
The demand for fresh and clean water sources is increasing globally, and there is a need to develop novel routes to eliminate micropollutants and other harmful species from water. Photocatalysis is a promising alternative green technology that has shown great performance in the degradation of persistent pollutants. Titanium dioxide is the most used catalyst owing to its attractive physico-chemical properties, but this semiconductor presents limitations in the photocatalysis process due to the high band gap and the fast recombination of the photogenerated carriers. Herein, a novel photocatalyst has been developed, based on titanium dioxide nanofibers (TiO2 NFs) synthesized by electrospinning. The TiO2 NFs were coated by atomic layer deposition (ALD) to grow boron nitride (BN) and palladium (Pd) on their surface. The UV-Vis spectroscopy measurements confirmed the increase of the band gap and the extension of the spectral response to the visible range. The obtained TiO2/BN/Pd nanofibers were then tested for photocatalysis, and showed a drastic increase of acetaminophen (ACT) degradation (>90%), compared to only 20% degradation obtained with pure TiO2 after 4 h of visible light irradiation. The high photocatalytic activity was attributed to the good dispersion of Pd NPs on TiO2-BN nanofibers, leading to a higher transfer of photoexcited hole carriers and a decrease of photogenerated electron-charge recombination. To confirm its reusability, recycling tests on the hybrid photocatalyst TiO2/BN/Pd have been performed, showing a good stability over 5 cycles under UV and visible light. In addition, toxicity tests as well as quenching tests were carried out to check the toxicity of the byproducts formed and to determine active species responsible for the degradation. The results presented in this work demonstrate the potential of TiO2/BN/Pd nanomaterials, and open new prospects for the preparation of tunable photocatalysts.
Subject(s)
TitaniumABSTRACT
We developed free-standing nitrogen-doped carbon nanofiber (CNF) electrodes incorporating Co/CoOx nanoparticles (NPs) as a new cathode material for removing Acid Orange 7 (AO7; a dye for wool) from wastewater by the heterogeneous electro-Fenton reaction. We produced the free-standing N-doped CNF electrodes by electrospinning a polyacrylonitrile (PAN) and cobalt acetate solution followed by thermal carbonation of the cobalt acetate/PAN nanofibers under a nitrogen atmosphere. We then investigated electro-Fenton-based removal of AO7 from wastewater with the free-standing N-doped-CNFs-Co/CoOx electrodes, in the presence or not of Fe2+ ions as a co-catalyst. The electrochemical analysis showed the high stability of the prepared N-doped-CNF-Co/CoOx electrodes in electrochemical oxidation experiments with excellent degradation of AO7 (20 mM) at acidic to near neutral pH values (3 and 6). Electro-Fenton oxidation at 10 mA/cm2 direct current for 40 min using the N-doped-CNF-Co/CoOx electrodes loaded with 25 wt% of Co/CoOx NPs led to complete AO7 solution decolorization with total organic carbon (TOC) removal values of 92.4% at pH 3 and 93.3% at pH 6. The newly developed N-doped-CNF-Co/CoOx electrodes are an effective alternative technique for wastewater pre-treatment before the biological treatment.
ABSTRACT
As organic dyes are a major source of pollution, it is important to develop novel and efficient heterogeneous catalysts with high activity for their degradation. In this work, two innovative techniques, atomic layer deposition and electrospinning, were used to prepare palladium nanoparticles (Pd NPs) supported on carbon nanofibers (CNFs). The sample morphology was investigated using scanning and transmission electron microscopy. This showed the presence of nanofibers of several micrometers in length and with a mean diameter of 200 nm. Moreover, the size of the highly dispersed Pd NPs was about 7 nm. X-ray photoelectron spectroscopy visually validated the inclusion of metallic Pd. The prepared nano-catalysts were then used to reduce methyl orange (MO) in the presence of sodium borohydride (NaBH4). The Freundlich isotherm model was the most suitable model to explain the adsorption equilibrium for MO onto the Pd/CNF catalysts. Using 5 mL MO dye-solution (0.0305 mM) and 1 mL NaBH4 (0.026 mM), a 98.9% of catalytic activity was achieved in 240 min by 0.01 g of the prepared nano-catalysts Pd/C (0.016 M). Finally, no loss of catalytic activity was observed when such catalysts were used again. These results represent a promising avenue for the degradation of organic pollutants and for heterogeneous catalysis.
