Analysis of EUV spectra from N-shell tungsten ions observed with an electron beam ion trap.

Extreme ultraviolet spectra of highly charged tungsten ions were produced with an electron beam ion trap at the National Institute of Standards and Technology and recorded with a flat-field grazing-incidence spectrometer. The spectra were measured in the wavelength range 2.7-17.3 nm while the beam energy varied between 1.65 and 2.00 keV. At these energies, the ionization stages from Zr-like W34+ to Se-like W40+ ions were observed. Large-scale collisional-radiative modelling was used to identify the strong lines, including 15 new ones, which represent electric dipole n = 4-4 transitions in these ions. While a good quantitative agreement between theoretical and experimental data was found for almost all ions, some of the tentatively identified wavelengths in W35+ significantly disagree from all available calculations.

Spectrum and Energy Levels of Five-Times Ionized Zirconium (Zr VI).

We carried out a new analysis of the spectrum of five-times-ionized zirconium Zr VI. For this we used sliding-spark discharges together with normal- and grazing-incidence spectrographs to observe the spectrum from 160 to 2000 Å. These observations showed that the analysis of this spectrum by Khan Z. A. et al. 1985 Phys. Scr.31 837 contained a significant number of incorrect energy levels. We have now classified ∼420 lines as transitions between 23 even-parity levels 73 odd-parity levels. The 4s24p5, 4s4p6, 4s24p44d, 5s, 5d, 6s configurations are now complete, although a few levels of 4s24p45d are tentative. We determined Ritz-type wavelengths for ∼135 lines from the optimized energy levels. The uncertainties range from 0.0003 to 0.0020 Å. Hartree-Fock calculations and least-squares fits of the energy parameters to the observed levels were used to interpret the observed configurations. Oscillator strengths for all classified lines were calculated with the fitted parameters. The results are compared with values for the level energies, percentage compositions, and transition probabilities from recent ab initio theoretical calculations. The ionization energy was revised to 777380±300 cm-1 (96.38±0.04 eV).

Measurement of wavelengths with phosphor storage image plates on a grazing incidence spectrograph.

We recorded the spectra emitted by a Ne/Mg Penning discharge and by sliding spark discharges of Y and Mo in the 150-450 A range with phosphor storage image plates on a 10.7 m grazing incidence spectrograph. To obtain better conformance of the image plates to the focal surface of the concave grating, the plates were mounted on the curved surface with a backing of flexible steel plates. The exposed plates were read by a rotary drum scanner. With these techniques we achieved a wavelength accuracy of approximately 0.003 A. This is comparable to what is normally obtained with photographic plates on this instrument.

Reference wavelengths for strong lines of atomic hydrogen and deuterium.

Wavelengths of the individual fine-structure components of the n = 1-2 (Ly(alpha)), n = 1-3 (Ly(beta)), n = 1-4 (Ly(gamma)), n = 1-5 (Ly(delta)), n = 1-6 (Ly(epsilon)), n = 1-7 (Ly(zeta)), n = 2-3 (H(alpha)), n = 2-4 (H(beta)), n = 2-5 (H(gamma)), n = 2-6 (H(delta)), and n = 2-7 (H(epsilon)) transitions of H and D are determined from theoretical values for the binding energies. Theoretical line strengths are used to obtain recommended values for the peaks of unresolved blends of these components as likely to be observed with discharge light sources and spectrometers with low to moderate resolution.

High-resolution spectrum of xenon ions at 13.4 nm.

The spectrum of xenon excited in a low-inductance vacuum spark was photographed at high resolution in the region of 9.5-15.5 nm. The observed transitions were identified as belonging to ions from Xe8+ to Xe13+. In the region of importance for extreme-ultraviolet lithography around 13.4 nm, the strongest lines were identified as 4d8-4d7 5p transitions in Xe10+. The identifications were made by use of energy parameters extrapolated along the isoelectronic sequence.

Atlas of the Spectrum of a Platinum/Neon Hollow-Cathode Reference Lamp in the Region 1130-4330 Å.

The spectrum of a platinum hollow-cathode lamp containing neon carrier gas was recorded photographically and photoelectrically with a 10.7 m normal-incidence vacuum spectrograph. Wavelengths and intensities were determined for about 5600 lines in the region 1130-4330 Å. An atlas of the spectrum is given, with the spectral lines marked and their intensities, wavelengths, and classifications listed. Lines of impurity species are also identified. The uncertainty of the photographically measured wavelengths is estimated to be ± 0.0020 Å. The uncertainty of lines measured in the photoelectric scans is 0.01 Å for wavelengths shorter than 2030 Å and 0.02 Å for longer wavelengths. Ritz-type wavelengths are given for many of the classified lines of Pt II with uncertainties varying from ±0.0004 to ± 0.0025 Å. The uncertainty of the relative intensities is estimated to be about 20%.

Fundamental Energy Levels of Neutral Promethium (Pm I).

The spectrum of atomic promethium has been observed with a variety of light sources and spectrographs. The Zeeman effect has also been recorded. Analysis of the spectrum shows that the ground configuration of the neutral promethium atom is 4f 56s 2. The relative positions (in cm-1) of the low levels of this configuration are: [Table: see text] This group represents all levels of 4f 56s 2 expected below 14,000 cm-1. From these results the following values of interaction parameters and their estimated uncertainties have been inferred: ζ 4 f = 925 ± 20 cm - 1 E 3 = 510 ± 20 cm - 1 Data on 209 upper levels of even parity and 714 classified lines are given.