ABSTRACT
In this work, the hydrothermal method was employed to produce SnO2/rGO as anode material. Nanostructured SnO2 was prepared to enhance reversibility and to deal with the undesirable volume changes during cycling. The SnO2/rGO hybrid exhibits long cycle life in lithium-ion storage capacity and rate capability with an initial discharge capacity of 1327 mAh/g at 0.1 C rate. These results demonstrate that a fabricated SnO2/rGO matrix will be a possible way to obtain high rate performance.
ABSTRACT
To develop the next-generation energy storage systems, lithium-sulfur batteries represent an attractive option due to its high theoretical capacity, and energy density. In this work, MoS2/rGO (reduced graphene oxide) was prepared by hydrothermal synthesis and sulfur added by the melt diffusion method. The as-prepared MoS2/rGO has strong polysulfides entrapping, high conductivity, large surface area, and high catalytic activity, consequently resulting in enhanced rate performance and cycling capability of Li-S batteries. The coin cells were constructed with the MoS2/rGO/S cathode material, exhibit a high reversible capacity of nearly 1380 mAh/g at 0.1 C, outstanding cycling stability with a low capacity fading rate. Present work reveals that the hierarchal MoS2/rGO/S cathodes are potential candidate materials for future high-performance lithium-sulfur batteries.