Evaluation and application of organic micro-pollutants (OMPs) as indicators in karst system characterization.

This study presents chances and challenges associated with the application of organic micro-pollutants (OMPs) as indicators in karst system characterization. The methodology and options of possible indications were evaluated based on the interpretation of the spatial distribution of 54 compounds in groundwater in combination with a complex geological setting consisting of multiple aquifer horizons and tectonic faults. A high variety of OMPs are released mainly in an urban area leading to concentrations of several nanograms per liter up to micrograms per liter, which are detectable using a high-performance liquid chromatography with subsequent tandem mass spectrometry (HPLC-MS/MS) method. Since characteristic patterns of spatial distribution were repeatedly observed during a 2-year observation period, important criteria of the aforementioned indicator application are fulfilled. Triazoles, compounds with recent high emission rates, could be successfully applied for the identification of flow directions and the delineation of catchment areas. Concentrations and the number of OMPs are believed to be dependent on properties of covering rock layers. Therefore, OMPs can also be used as a validation tool for vulnerability mapping. Compounds, such as triazines, persistent in the system for more than two decades, demonstrate the interaction between different parts of the aquifer system and the hydraulic characteristics of a tectonic fault zone. Such indicator potentials complement those of artificial tracer tests. Point sources of OMPs and their impact on groundwater could be identified qualitatively. In combination with the interpretation of the geological setting, the distribution of OMPs provides essential information for the development of a conceptual hydrogeological model.

Occurrence and spatial distribution of organic micro-pollutants in a complex hydrogeological karst system during low flow and high flow periods, results of a two-year study.

Fifty-four different organic micro-pollutants (OMPs) including pharmaceuticals, pesticides, corrosion inhibitors and other typical wastewater compounds such as caffeine are repeatedly analyzed in approximately fifty groundwater observation points in a complex faulted and fractured carbonate aquifer system consisting of three spring catchment areas. With the applied HPLC-MS/MS method, achieving method quantification limits (MQL) of 1.2-28 ng L(-1), forty-four of the OMPs are detected in groundwater. Regarding the vertical distribution in the aquifer system the highest variety of OMPs occurs in the shallow aquifer. Most frequently detected compounds are atrazine together with the metabolites of several triazines, desethylatrazine (DEA) and desisopropylatrazine (DIA), the corrosion inhibitors 1H-benzotriazole and tolytriazoles and as pharmaceutical residues the anti-epileptic drug carbamazepine as well as the analgesic drug phenazone. Median OMP concentrations are in the range of 20-40 ng L(-1) with occasionally and locally higher concentrations of up to 6000 ng L(-1). Defined combinations of OMPs occur repeatedly in the same observation wells and allow to distinguish different input functions. The comparison of detection frequency with the number of prescribed doses gives information about the specific persistence of pharmaceuticals. The analgesic phenazone exhibits a peculiar high detection frequency, although it is recently not prescribed in significant amounts. The detection of the estrogen antagonist tamoxifen (6-17 ng L(-1)) in a groundwater flow system is reported for the first time.