Emission and gas-particle partitioning characteristics of atmospheric halogenated and organophosphorus flame retardants in decabromodiphenyl ethane-manufacturing functional areas.

The emission and gas-particle partitioning characteristics in various functional areas of production lines are still unknown. However, flame-retardant manufacturing activities are the primary emission source of flame retardants. Thus, fine particles and gases were investigated in three functional areas of a decabromodiphenyl ethane production line, i.e., polybrominated diphenyl ethers (PBDEs), novel brominated flame retardants (NBFRs), dechlorane plus (DPs), and organophosphorus flame retardants (OPFRs) in a flame-retardant manufacturing factory. High levels of PBDEs (8.02 × 103-4.16 × 104 pg/m3), NBFRs (6.05 × 103-1.92 × 105 pg/m3), and DPs (89.5-5.20 × 103 pg/m3) were found in various functional areas, suggesting manufacturing activities were a primary emission source. In contrast, OPFRs were derived from long-range transport or other non-industrial sources. Varied concentrations of PBDEs, NBFRs, and DPs were observed in different production lines, higher in the reaction zone area than others. As the predominant compounds, decabromodiphenyl ether, decabromodiphenyl ethane, syn-DP, and tris(chloropropyl) phosphate accounted for 54.7%, 89.3%, 93.4%, and 34.7% of PBDEs, NBFRs, DPs, and OPFRs, respectively. Three models were used to predict the gas-particle partitioning of the halogenated flame retardants emitted from manufacturing activities. The Li-Jia Empirical Model predicted the gas-particle partitioning behavior well. This research shows that the adsorption-desorption process of the halogenated flame retardants between the gaseous and particulate phases did not reach equilibrium.

Heterologous spatial distribution of soil polycyclic aromatic hydrocarbons and the primary influencing factors in three industrial parks.

Soil polycyclic aromatic hydrocarbons (PAHs) generated from industrial processes are highly spatially heterologous, with limited quantitative studies on their main influencing factors. The present study evaluated the soil PAHs in three types of industrial parks (a petrochemical industrial park, a brominated flame retardant manufacturing park, and an e-waste dismantling park) and their surroundings. The total concentrations of 16 PAHs in the parks were 340-2.43 × 103, 26.2-2.63 × 103, and 394-2.01 × 104 ng/g, which were significantly higher than those in the surrounding areas by 1-2 orders of magnitude, respectively. The highest soil PAH contamination was observed in the e-waste dismantling park. Nap can be considered as characteristic pollutant in the petrochemical industrial park, while Phe in the flame retardant manufacturing park and e-waste dismantling park. Low molecular weight PAHs (2-3 rings) predominated in the petrochemical industrial park (73.0%) and the surrounding area of brominated flame retardant manufacturing park (80.3%). However, high molecular weight PAHs (4-6 rings) were enriched in the other sampling sites, indicating distinct sources and determinants of soil PAHs. Source apportionment results suggested that PAHs in the parks were mainly derived from the leakage of petroleum products in the petroleum manufacturing process and pyrolysis or combustion of fossil fuels. Contrarily, the PAHs in the surrounding areas could have been derived from the historical coal combustion and traffic emissions. Source emissions, wind direction, and local topography influenced the PAH spatial distributions.

Identification of specific halogenated polycyclic aromatic hydrocarbons in surface soils of petrochemical, flame retardant, and electronic waste dismantling industrial parks.

Halogenated polycyclic aromatic hydrocarbons (Cl/Br-PAHs) have received tremendous attention due to their high toxicity. To identify the emission pattern of Cl/Br-PAHs from various industrial productions, understand the formation mechanisms and the influence on the surroundings, this study investigated the surface soils of three typical industrial parks. Generally, traces of Cl-PAHs were much lower than Br-PAHs. The mean Cl-PAH concentrations followed the trend of petrochemical industrial park (3.12 ng/g), brominated flame retardant (BFR) manufacturing park (1.48 ng/g), and electronic waste dismantling park (0.26 ng/g). However, the BFR manufacturing park had the highest mean Br-PAH concentration (21.6 ng/g), significantly higher than the other two parks. Generally, higher levels of the chemicals were found in the parks than in their surroundings, except for the electronic waste dismantling park. The massive addition of chlorine additives in crude oil and its by-products, plus the enormous quantity of brominated brines used in BFR productions, favor Cl/Br-PAH formation. Analyzing the homolog compositions of Cl/Br-PAHs suggested that 3- or 4-ring Cl/Br-PAHs were typically come from the petrochemical industrial park and electronic waste dismantling park. Contrarily, 4- or 5-ring Cl/Br-PAHs were predominantly come from the BFR manufacturing activity. This study provides fingerprints to trace the Cl/Br-PAH emissions during industrial production and analyzes the formation mechanism.

Bioaccessibilities of metal(loid)s and organic contaminants in particulates measured in simulated human lung fluids: A critical review.

Particle-bound pollutants can pose a health risk to humans. Inhalation exposure evaluated by total contaminant concentrations significantly overestimates the potential risk. To assess the risk more accurately, bioavailability, which is the fraction that enters into the systemic circulation, should be considered. Researchers have replaced bioavailability by bioaccessibility due to the rapid and cost-efficient measurement for the latter, especially for assessment by oral ingestion. However, contaminants in particulates have different behavior when inhaled than when orally ingested. Some of the contaminants are exhaled along with exhalation, and others are deposited in the lung with the particulates. In addition, a fraction of the contaminants is released into the lung fluid and absorbed by the lung, and another fraction enters systemic circulation under the action of cell phagocytosis on particulates. Even if the release fraction, i.e., release bioaccessibility, is considered, the measurement faces many challenges. The present study highlights the factors influencing release bioaccessibility and the incorporation of inhalation bioaccessibility into the risk assessment of inhaled contaminants. Currently, there are three types of extraction techniques for simulated human lung fluids, including simple chemical solutions, sequential extraction techniques, and physiologically based techniques. The last technique generally uses three kinds of solution: Gamble's solution, Hatch's solution, and artificial lysosomal fluid, which are the most widely used physiologically based simulated human lung fluids. External factors such as simulated lung fluid composition, pH, extraction time, and sorption sinks can affect release bioaccessibility, whereas particle size and contaminant properties are important internal factors. Overall, release bioaccessibility is less used than bioaccessibility considering the deposition fraction when assessing the risk of contaminants in inhaled particulates. The release bioaccessibility measurement poses two main challenges: developing a unified, accurate, stable, simple, and systematic biologically based method, and validating the method through in-vivo assays.

Residual effects of organochlorine pesticides (OCPs) in an e-waste recycling area compared with heavy metal pollution.

Disposal of e-waste is a global issue and has caused serious pollution in recycling areas. Most of these areas had once developed intensive agriculture and might incur organochlorine pesticides (OCPs) pollution. However, this used to be neglected. Here we discuss the joint effects via analyzing OCPs and heavy metals in a notorious e-waste recycling area. The OCPs showed higher (p = 0.005) pollution levels in soils from agricultural zone than in core e-waste recycling zone, which is opposite for heavy metals (p = 0.02). The OCPs and heavy metals showed the highest concentrations in the open burning site locating in the boundary between the e-waste and agricultural zones. Composition profiles further indicated that the land use changes from agriculture to e-waste industry might accelerate the release of buried OCPs. Worse still, the OCPs and heavy metals might pose carcinogenic and non-carcinogenic risks to local residents, respectively.

The health concern of polychlorinated biphenyls (PCBs) in a notorious e-waste recycling site.

Polychlorinated biphenyls (PCBs) remain a relatively high level in e-waste recycling regions 3 decades after ban on use. Illegal recycling activities cunningly moved under the environmental law enforcement. Here, we analyzed PCBs in soils and plants from Guiyu, China (one of the world's largest recycling areas) to understand the relationship between PCBs pollution and the transition of recycling activities (locations and techniques). High concentrations of PCBs were found in soil and plant samples from emerging recycling sites, up to 234 ng g-1 and 236 ng g-1 (dry weight), respectively. The recycling activities, specifically the open burning process, would obviously aggravate the PCB pollution levels in its environment. The calculated values of estimated daily intake and hazard ratios of PCBs in dietary routes showed that health risks should be taken seriously.