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1.
ACS Omega ; 9(3): 3950-3961, 2024 Jan 23.
Article in English | MEDLINE | ID: mdl-38284093

ABSTRACT

Since the diffusion coefficient is a key parameter to characterize the diffusion rate of methane molecules, its measurement and solution have always been a research hotspot. The diffusion coefficient is normally solved through analytical solutions of theoretical models, which is complex and poorly applicable. In comparison, the numerical simulation optimization method can seek a solution easily and quickly, providing a clue for solving such problem. In this paper, first, gas desorption experiments were conducted on coal samples with different initial gas equilibrium pressures, coal particle sizes, and metamorphic degrees. Combined with existing theoretical models, the numerical simulation optimization method was adopted to solve the diffusion coefficient of the coal particle. Furthermore, the applicability and advantages of the numerical simulation optimization method were discussed. Finally, the variation law of the diffusion coefficients was analyzed. The results demonstrate that the numerical simulation optimization method can not only solve the diffusion coefficient easily and quickly but also reveal the law of diffusion concentration with time. The d values between the solution results and the experimental data under different conditions are all smaller than 0.2, which proves the effectiveness and accuracy of the simulation optimization method. The diffusion coefficient of gas from coal particles is unrelated to the initial gas equilibrium pressure, yet it has a Z-shaped relationship with the coal particle size and a V-shaped relationship with the metamorphic degree.

2.
Front Plant Sci ; 12: 761148, 2021.
Article in English | MEDLINE | ID: mdl-35309952

ABSTRACT

Crop classification maps are fundamental data for global change research, regional agricultural regulation, fine production, and insurance services. The key to crop classification is samples, but it is very time-consuming in annual field sampling. Therefore, how to use historical samples in crop classification for future years at a lower cost is a research hotspot. By constructing the spectral feature vector of each historical sample in the historical year and its neighboring pixels in the target year, we produced new samples and classified them in the target year. Specifically, based on environmental similarity, we first calculated the similarities of every two pixels between each historical year and target year and took neighboring pixels with the highest local similarity as potential samples. Then, cluster analysis was performed on those potential samples of the same crop, and the class with more pixels is selected as newly generated samples for classification of the target year. The experiment in Heilongjiang province, China showed that this method can generate new samples with the uniform spatial distribution and that the proportion of various crops is consistent with field data in historical years. The overall accuracy of the target year by the newly generated sample and the real sample is 61.57 and 80.58%, respectively. The spatial pattern of maps obtained by two models is basically the same, and the classification based on the newly generated samples identified rice better. For areas with majority fields having no rotation, this method overcomes the problem of insufficient samples caused by difficulties in visual interpretation and high cost on field sampling, effectively improves the utilization rate of historical samples, and provides a new idea for crop mapping in areas lacking field samples of the target year.

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