Nanoparticle manipulation based on chiral plasmon effects.

Chiral plasmonic structures have garnered increasing attention owing to their distinctive chiroptical response. Localized surface plasmon resonance can significantly enhance the circular dichroism and local electromagnetic field of chiral plasmonic structures, resulting in enhanced electromagnetic forces acting on surrounding nanoparticles. Moreover, the circular dichroism response of chiral structures provides an effective means for macroscopic adjustment of microscopic electromagnetic fields. However, chiral plasmon effects are naturally related to angular momentum, and particle control studies of chirality usually focus on angular momentum. This paper proposes a particle manipulation method utilizing chiral light-matter interactions. Through optimization of the optical response of the chiral structure, the direction of electromagnetic forces exerted on surrounding polystyrene particles reverses upon a change in the incident light's handedness. According to this characteristic, the movement direction control of polystyrene particles with a diameter of 100 nm was achieved. By altering the handedness of a single circularly polarized light, more than 94% high-precision particle manipulation was achieved, reducing the complexity of particle manipulation. This microfluidic method has significant implications for advancing microfluidic research and chiral applications.

Enhancement of the photoacoustic effect during the light-particle interaction.

Exogenous photoacoustic contrast agents such as gold nanoparticles are widely utilized in photoacoustic imaging. Enhancing the photoacoustic performance of gold nanoparticles is pivotal for improving the quality and expanding the application scope of photoacoustic imaging. In this work, the photothermal and photoacoustic responses of gold nanospheres surrounded by water excited with a pulsed laser are obtained via a two-temperature model. The interplay between pulse duration and interface thermal resistance and its effect on the photothermal and photoacoustic performances are uncovered quantitatively. The results reveal that, as the pulse duration decreases, increasing the interfacial thermal conductivity can substantially enhance heat transfer between the gold nanosphere and the surrounding water. However, this approach does not effectively enhance the photoacoustic performance. Interestingly, when increasing the thermal conductivity, it was found that there is an optimal pulse duration within the range of 10 ps-10 ns. Employing an incident pulse laser with this optimal pulse duration can maximize the enhancement of the photoacoustic signal.

Insight into the role of heterogeneous Fenton-like catalyst FeCo-γ-Al2O3 with dual electron-rich centers for Ni-EDTA removal.

To enhance the polarization distribution of electron cloud density on the catalyst surface, we have introduced a novel bimetallic-substituted dual-reaction center (DRC) catalyst (FeCo-γ-Al2O3) comprising iron (Fe) and cobalt (Co) for the decomplexation and mineralization of heavy metal complex Ni-EDTA in this study. Compared to the catalysts doped solely with Fe or Co, the bimetal-doped catalyst offered several advantages, including enhanced electron cloud polarization distribution, additional electron transfer pathway, and improved capacity of free radical generation. Through DFT calculations and EPR tests, we have elucidated the influences of the catalyst's adsorption toward Ni-EDTA and its decomplexation products on the electron transfer between the pollutant and the catalyst. The competition between the pollutants and H2O2 affects the generation of free radicals in both electron-rich Fe and Co centers as well as electron-deficient Al center. Building on these findings, we have proposed a plausible removal mechanism of Ni-EDTA using the heterogeneous Fenton-like catalyst FeCo-γ-Al2O3. This study sheds light on the potential of FeCo-γ-Al2O3 as a DRC catalyst and emphasizes the significance of pollutant characteristics in determining the catalyst's performance.

Influence of the temperature-dependent dielectric constant on the photoacoustic effect of gold nanospheres.

Photoacoustic imaging techniques with gold nanoparticles as contrast agents have received a great deal of attention. The photoacoustic response of gold nanoparticles strongly depends on the far-field optical properties, which essentially depend on the dielectric constant of the material. The dielectric constant of gold not only varies with wavelength but is also affected by temperature. However, the effect of the temperature dependence of the dielectric constant on gold nanoparticles' photoacoustic response has not been fully investigated. In this work, the Drude-Lorentz model and Mie theory are used to calculate the dielectric constant and absorption efficiency of gold nanospheres in aqueous solution, respectively. Then, the finite element method is used to simulate the heat transfer process of gold nanospheres and surrounding water. Finally, the one-dimensional velocity-stress equation is solved by the finite-difference time-domain method to obtain the photoacoustic response of gold nanospheres. The results show that under the irradiation of a high-fluence nanosecond pulse laser, ignoring the temperature dependence of the dielectric constant will lead to large errors in the photothermal response and the nonlinear photoacoustic signals (it can even exceed 20% and 30%). The relative error of the photothermal and photoacoustic response caused by ignoring the temperature-dependent dielectric constant is determined from both the temperature dependence of absorption efficiency and the maximum temperature increase of gold nanospheres. This work provides a new perspective for the photothermal and photoacoustic effects of gold nanospheres, which is meaningful for the development of high-resolution photoacoustic detectors and nano/microscale temperature measurement techniques.

Integrated Infrared Radiation Characteristics of Aircraft Skin and the Exhaust Plume.

Infrared radiation (IR) characteristics are important parameters for detecting, identifying, and striking military targets in the context of systematic countermeasures. Accurate calculation of IR characteristics for aircraft is significant for the simulation of war situations and the designation of combat strategy. In this work, integrated IR characteristics of aircraft skin and exhaust plume and their interaction are investigated by considering the reflection based on a bi-directional reflectance distribution function and various influence factors such as solar irradiation, ground reflection, aerodynamic heating, and projection radiation from the background. Combined with infrared emission and reflection characteristics of the skin, omnidirectional IR intensity distributions of 3-5 µm and 8-14 µm at different Mach numbers are obtained. The exhaust plume IR characteristic for different waves and wavebands are also investigated by considering the presence or absence of base and the difference in nozzle inlet temperature. On this basis, integrated IR characteristics between the skin and exhaust plume are investigated. Results show that aircraft IR characteristics of 3-5 µm are concentrated in the exhaust plume and high-temperature skin near the exhaust plume, while the signals of 8-14 µm are concentrated in the skin. The research results are expected to supply guidance for better detection and identification of typical flight targets.

Nanoparticle manipulation using plasmonic optical tweezers based on particle sizes and refractive indices.

As an effective tool for micro/nano-scale particle manipulation, plasmonic optical tweezers can be used to manipulate cells, DNA, and macromolecules. Related research is of great significance to the development of nanoscience. In this work, we investigated a sub-wavelength particle manipulation technique based on plasmonic optical tweezers. When the local plasmonic resonance is excited on the gold nanostructure arrays, the local electromagnetic field will be enhanced to generate a strong gradient force acting on nanoparticles, which could achieve particle sorting in sub-wavelength scale. On this basis, we explored the plasmonic enhancement effect of the sorting device and the corresponding optical force and optical potential well distributions. Additionally, the sorting effect of the sorting device was investigated in statistical methods, which showed that the sorting device could effectively sort particles of different diameters and refractive indices.

Magnetic TiO2/CoFe2O4 Photocatalysts for Degradation of Organic Dyes and Pharmaceuticals without Oxidants.

In the current study, CoFe2O4 and TiO2 nanoparticles were primarily made using the sol-gel method, and subsequently, the hybrid magnetic composites of TiO2 loaded with CoFe2O4 (5-15 percent w/w) were made using a hydrothermal procedure. X-ray diffraction (XRD), Fourier transform infrared (FTIR) and Raman spectroscopy, ultraviolet-visible diffuse reflectance spectroscopy (UV-vis DRS), scanning electron microscopy (SEM), and high-resolution transmission electron microscopy (HRTEM) were all used to thoroughly characterize the materials. Additionally, the zero-charge point (ZCP) determination, the examination of the pore structure by nitrogen adsorption, and an evaluation of magnetic properties were performed. Six organic dye pollutants were selected to evaluate the performance of the synthesized nanocomposites toward photocatalytic degradation, including methylene blue (MB), methyl orange (MO), crystal violet (CV), acridine orange (AO), rhodamine B (RhB), and rhodamine 6G (R-6G). Photodegradation of tetracycline (TL), a model pharmaceutical pollutant, was also studied under UV and visible light. The composites exhibited a high degradation performance in all cases without using any oxidants. The photocatalytic degradation of tetracycline revealed that the CoFe2O4/TiO2 (5% w/w) composite exhibited a higher photocatalytic activity than either pure TiO2 or CoFe2O4, and thus attained 75.31% and 50.4% degradation efficiency under UV and visible light, respectively. Trapping experiments were conducted to investigate the photodegradation mechanism, which revealed that holes and super oxide radicals were the most active species in the photodegradation process. Finally, due to the inherent magnetic attributes of the composites, their easy removal from the treated solution via a simple magnet became possible.

Photothermal conversion and transfer in photothermal therapy: From macroscale to nanoscale.

Photothermal therapy (PTT) is a promising alternative therapy for benign or even malignant tumors. To improve the selective heating of tumor cells, target-specific photothermal conversion agents are often included, especially nanoparticles. Meanwhile, some indirect methods by manipulating the radiation and heat delivery are also adopted. Therefore, to gain a clear understanding of the mechanism, and to improve the controllability of PTT, a few issues need to be clarified, including bioheat and radiation transfer, localized and collective heating of nanoparticles, etc. In this review, we provide an introduction to the typical bioheat transfer and radiation transfer models along with the dynamic thermophysical properties of biological tissue. On this basis, we reviewed the most recent advances in the temperature control methods in PTT from macroscale to nanoscale. Most importantly, a comprehensive introduction of the localized and collective heating effects of nanoparticle clusters is provided to give a clear insight into the mechanism for PPT from the microscale and nanoscale point of view.

Dependence of the Nonlinear Photoacoustic Response of Gold Nanoparticles on the Heat-Transfer Process.

Photoacoustic (PA) imaging using the nonlinear PA response of gold nanoparticles (GNPs) can effectively attenuate the interference from background noise caused by biomolecules (e.g., hemoglobin), thus offering a highly potential noninvasive biomedical imaging method. However, the mechanism of the nonlinear PA response of GNPs based on the thermal expansion mechanism, especially the effect of heat-transfer ability, still lacks quantitative investigation. Therefore, this work investigated the effect of heat-transfer ability on the nonlinear PA response of GNPs using the critical energy and fluence concept, taking into account the Au@SiO2 core-shell nanoparticles (weakened heat transfer) and gold nanochains (enhanced heat transfer). The results showed that the stronger the heat transferability, the smaller the critical energy, indicating that the nonlinear PA response of different nanoparticles cannot be contrasted directly through the critical energy. Moreover, the critical fluence can directly contrast the proportion of nonlinear components in the PA response of different GNPs as governed by the combined effect of heat transferability and photothermal conversion ability.

Plasmonic Optical Tweezers for Particle Manipulation: Principles, Methods, and Applications.

Inspired by the idea of combining conventional optical tweezers with plasmonic nanostructures, a technique named plasmonic optical tweezers (POT) has been widely explored from fundamental principles to applications. With the ability to break the diffraction barrier and enhance the localized electromagnetic field, POT techniques are especially effective for high spatial-resolution manipulation of nanoscale or even subnanoscale objects, from small bioparticles to atoms. In addition, POT can be easily integrated with other techniques such as lab-on-chip devices, which results in a very promising alternative technique for high-throughput single-bioparticle sensing or imaging. Despite its label-free, high-precision, and high-spatial-resolution nature, it also suffers from some limitations. One of the main obstacles is that the plasmonic nanostructures are located over the surfaces of a substrate, which makes the manipulation of bioparticles turn from a three-dimensional problem to a nearly two-dimensional problem. Meanwhile, the operation zone is limited to a predefined area. Therefore, the target objects must be delivered to the operation zone near the plasmonic structures. This review summarizes the state-of-the-art target delivery methods for the POT-based particle manipulating technique, along with its applications in single-bioparticle analysis/imaging, high-throughput bioparticle purifying, and single-atom manipulation. Future developmental perspectives of POT techniques are also discussed.

Anisotropic scattering characteristics of nanoparticles in different morphologies: improving the temperature uniformity of tumors during thermal therapy using forward scattering.

Precise control of the thermal damage area is the key issue during thermal therapy, which can be achieved by manipulating the light propagation in biological tissue. In the present work, a method is proposed to increase the uniformity of the specific absorption rate (SAR) distribution in tumors during laser-induced thermal therapy, which is proved to be effective in reducing the thermal damage of healthy tissue. In addition, a better way of manipulating light propagation in biological tissue is explored. It is found that the anisotropic scattering characteristics of nanoparticles are strongly dependent on their shapes, sizes, orientations, and incident wavelengths, which will strongly affect the light propagation in nanoparticle embedded biological tissue. Therefore, to obtain a better outcome from photothermal therapy, the scattering properties of nanoparticles are very important factors that need to be taken into consideration, along with the absorption efficiency. Further investigation finds that nanoparticles that predominantly scatter to the forward direction are favorable in obtaining a larger penetration depth of light, which will improve the uniformity of SAR and temperature distributions. This paper is meaningful for the application of nanoparticle-assisted laser-induced thermal therapy.

A Parametric Investigation of Corneal Laser Surgery Based on the Multilayer Dynamic Photothermal Model.

Corneal laser surgery is a widely used method for the treatment of ocular myopia, hyperopia, and astigmatism. Although it is a well-established technique, the photothermal properties of the cornea are often overlooked, causing unexpected changes in temperature during laser irradiation. Therefore, there is a need for further investigation of the temperature response of the cornea under laser irradiation. In the present work, a photothermal corneal numerical model is presented, assuming the stratification of the cornea with laser ablation in an uncoagulated layer, a coagulated layer, a dehydrating layer, a dried layer, and a carbonized layer. The modified Pennes' bioheat transfer equation and Lambert-Beer's law are applied to simulate heat transfer in the corneal tissue during laser irradiation. And the corneal dynamic photothermal parameters are considered in the proposed model. The central surface temperature, the boundary and thickness of each layer, and the thermal damage during laser irradiation are investigated. From the model, it was found that in the steady-state process, the thickness of the coagulated layer was 2.6, 14.4, and 52.4 times larger than that of the dehydrating layer, the dried layer, and the carbonized layer, respectively. The thickness of the corneal thermal damage gradually increased, and reached a peak of 0.196 mm at about 18.2 ms. Subsequently, it sharply decreased by 0.01 mm before stabilizing. On this basis, the influence of laser intensity is investigated. The parametric investigation and analysis presented provide a theoretical basis for corneal laser surgery, which can be used to improve our understanding of laser-tissue surgery.

Simultaneous determination of primary particle size distribution and thermal accommodation coefficient of soot aggregates using low-fluence LII.

For the ill-posed inverse problem of LII-based nanoparticle size measurement, recovered primary particle size distribution (PPSD) is sensitive to the uncertainty of LII model parameters. In the absence of reliable prior knowledge, the thermal accommodation coefficient (TAC) and fractal-dependent shielding factor are often required to be inferred simultaneously with the PPSD. In the simplified LII model for low fluence regime, TAC and fractal-dependent shielding factor are combined to define a new fractal-dependent TAC. The present study theoretically verified the feasibility of inferring PPSD and fractal-dependent TAC from the normalized LII signals. Moreover, the inversion is independent of prior knowledge of most full LII model parameters, which is attributed to low laser fluence, normalized signal, and fractal-dependent TAC.

Radiative thermal switch driven by anisotropic black phosphorus plasmons.

Black phosphorus (BP), as a two-dimensional material, has exhibited unique optoelectronic properties due to its anisotropic plasmons. In the present work, we theoretically propose a radiative thermal switch (RTS) composed of BP gratings in the context of near-field radiative heat transfer. The simply mechanical rotation between the gratings enables considerable modulation of radiative heat flux, especially when combined with the use of non-identical parameters, i.e., filling factors and electron densities of BP. Among all the cases including asymmetric BP gratings, symmetric BP gratings, and BP films, we find that the asymmetric BP gratings possess the most excellent switching performance. The optimized switching factors can be as high as 90% with the vacuum separation d=50 nm and higher than 70% even in the far-field regime d=1 µm. The high-performance switching is basically attributed to the rotatable-tunable anisotropic BP plasmons between the asymmetric gratings. Moreover, due to the twisting principle, the RTS can work at a wide range of temperature, which has great advantage over the phase change materials-based RTS. The proposed switching scheme has great significance for the applications in optoelectronic devices and thermal circuits.

Magnetoplasmon-surface phonon polaritons' coupling effects in radiative heat transfer.

In this work, the coupling of magnetoplasmon polaritons (MPP) to surface phonon polaritons (SPhPs) in near-field radiative heat transfer is theoretically investigated. The system is composed of two parallel graphene-coated SiO2 substrates. By applying an external magnetic field, the separated branches of MPPs can couple with SPhPs to form tunable modes. The behavior remolds the energy transport of the system. The relative thermal magnetoresistance ratio can reach values of up to 160% for a magnetic field of 8 T. In addition, the thermal stealthy for the coated graphene is realized by tuning the intensity of fields. This work has substantial importance to graphene-based magneto-optical devices.

Periodic trapezoidal VO2-Ge multilayer absorber for dynamic radiative cooling.

Nowadays, the requirement for achieving dynamic radiative cooling is more and more intense, so a cooling system is proposed and developed to meet the demand in this paper. This cooling system is composed of a filter and a periodic trapezoidal VO2-Ge multilayer absorber (VGMA). The filter on the top enables the VGMA to reflect most of the solar irradiation at daytime and the absorptance or emittance of the VGMA is very different in the spectrum band of 8-13 µm for insulating and metallic VO2 due to the phase transition characteristic of VO2. With this cooling system, close-to-zero absorptance in the range of 0.3-2.5 µm and high (low) absorptance from 8 to 13 µm are achieved for metallic (insulating) VO2. Based on changing the temperature and absorptivity or emissivity simultaneously, radiative heat can be transferred dynamically to the outer space. When VO2 is in the insulating phase, the absorption mechanism of the absorber is magnetic resonance and surface plasmon polariton resonance, and broadband high absorptivity is achieved by exciting slowlight waveguide mode at broadband wavelengths when VO2 is in metallic phase. The spectral absorptance characteristics of the absorber in the two phase states are investigated as a function of the layer number and the incident angle of the electromagnetic waves. The results show that the absorber designed is insensitive to the incident angle. Moreover, the net cooling power of the VGMA of metallic VO2 is instantly 4 times more than that of insulating VO2 once the phase change temperature is reached. This work will be beneficial to the advancement of dynamic radiative cooling.

Active control of near-field radiative heat transfer by a graphene-gratings coating-twisting method.

In this Letter, active control of near-field radiative heat transfer (NFRHT) between two isotropic materials is realized by a coating-twisting method. The two slabs are coated with graphene gratings, and then the NFRHT can be not only enhanced but also weakened, by tuning the twisted angle between the two gratings. The physical mechanism is attributed to the modes coupled by the graphene gratings and the isotropic material, which can vary with the twisted angle. The proposed method is also applicable for other kinds of anisotropic films and may provide a way to realize high-precision nanoscale thermal management, nimble thermal communications, and thermal switch.

Efficient optical parameter mapping based on time-domain radiative transfer equation combined with parallel programming.

A two-dimensional optical parameter mapping based on the time-domain radiative transfer equation (TD-RTE) is studied in this work. The finite element method with structured and unstructured grids is employed to solve TD-RTE and OpenMP parallel technology is employed to improve the computing efficiency. The sequential quadratic programming algorithm is used as a powerful optimization method to reconstruct absorption and scattering parameter fields and the maximum a posteriori estimation is employed by introducing the regularization term into the objective function to improve the ill-posed inverse problem. In addition, the effects of measurement errors on reconstruction accuracy are investigated thoroughly. All the simulation results demonstrate that the reconstructed scheme we developed is accurate and efficient in optical parameter mapping based on TD-RTE.

Near-field radiative heat transfer in multilayered graphene system considering equilibrium temperature distribution.

In the present work, the near-field radiative heat transfer of a multilayered graphene system is investigated within the framework of the many-body theory. For the first time, the temperature distribution corresponding to the steady state of the system is investigated. Unique temperature steps are observed near both boundaries of the system, especially in the strong near-field regime. By utilizing the effective radiative thermal conductance, the thermal freedom of heat flux in different regions of the system is analyzed quantitatively, and the cause of various temperature distributions is explained accordingly. To characterize the heat transfer ability of the whole system, we evaluate the system with two heat transfer coefficients (HTC), transient heat transfer coefficient (THTC), and steady heat transfer coefficient (SHTC). A unique many-body enhancement is observed, which causes a red-shift of resonance peak corresponding to graphene surface plasmon polaritons. Furthermore, a three-body enhancement of SHTC emerges thanks to the relay effect and the complexity of the system. The regime of heat transport can be tuned by changing the chemical potentials of graphene and undergoes a transition from diffusive to quasi-ballistic transport in the strong near-field regime.

Optimal temperature control of tissue embedded with gold nanoparticles for enhanced thermal therapy based on two-energy equation model.

Thermal therapy is a very promising method for cancer treatment, which can be combined with chemotherapy, radiotherapy and other programs for enhanced cancer treatment. In order to get a better effect of thermal therapy in clinical applications, optimal internal temperature distribution of the tissue embedded with gold nanoparticles (GNPs) for enhanced thermal therapy was investigated in present research. The Monte Carlo method was applied to calculate the heat generation of the tissue embedded with GNPs irradiated by continuous laser. To have a better insight into the physical problem of heat transfer in tissues, the two-energy equation was employed to calculate the temperature distribution of the tissue in the process of GNPs enhanced therapy. The Arrhenius equation was applied to evaluate the degree of permanent thermal damage. A parametric study was performed to investigate the influence factors on the tissue internal temperature distribution, such as incident light intensity, the GNPs volume fraction, the periodic heating and cooling time, and the incident light position. It was found that period heating and cooling strategy can effectively avoid overheating of skin surface and heat damage of healthy tissue. Lower GNPs volume fraction will be better for the heat source distribution. Furthermore, the ring heating strategy is superior to the central heating strategy in the treatment effect. All the analysis provides theoretical guidance for optimal temperature control of tissue embedded with GNP for enhanced thermal therapy.