1.
Acta Crystallogr Sect E Struct Rep Online
; 67(Pt 7): m886, 2011 Jul 01.
Article
in English
| MEDLINE
| ID: mdl-21836878
ABSTRACT
In the title coordination polymer, [CdBr(2)(C(8)H(8)N(2)S(2))](n), the Cd(II) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from a 2,2'-dimethyl-4,4'-bi-1,3-thia-zole ligand and four bridging Br atoms. The bridging function of the Br atoms leads to a chain structure along [100]. Inter-chain C-Hâ¯Br hydrogen bonds and π-π contacts between the thia-zole rings [centroid-centroid distances = 3.810â (5) and 3.679â (5)â Å] are observed.