New Features of Laboratory-Generated EPFRs from 1,2-Dichlorobenzene (DCB) and 2-Monochlorophenol (MCP).

The present research is primarily focused on investigating the characteristics of environmentally persistent free radicals (EPFRs) generated from commonly recognized aromatic precursors, namely, 1,2-dichlorobenzene (DCB) and 2-monochlorophenol (MCP), within controlled laboratory conditions at a temperature of 230 °C, termed as DCB230 and MCP230 EPFRs, respectively. An intriguing observation has emerged during the creation of EPFRs from MCP and DCB utilizing a catalyst 5% CuO/SiO2, which was prepared through various methods. A previously proposed mechanism, advanced by Dellinger and colleagues (a conventional model), postulated a positive correlation between the degree of hydroxylation on the catalyst's surface (higher hydroxylated, HH and less hydroxylated, LH) and the anticipated EPFR yields. In the present study, this correlation was specifically confirmed for the DCB precursor. Particularly, it was observed that increasing the degree of hydroxylation at the catalyst's surface resulted in a greater yield of EPFRs for DCB230. The unexpected finding was the indifferent behavior of MCP230 EPFRs to the surface morphology of the catalyst, i.e., no matter whether copper oxide nanoparticles are distributed densely, sparsely, or completely agglomerated. The yields of MCP230 EPFRs remained consistent regardless of the catalyst type or preparation protocol. Although current experimental results confirm the early model for the generation of DCB EPFRs (i.e., the higher the hydroxylation is, the higher the yield of EPFRs), it is of utmost importance to closely explore the heterogeneous alternative mechanism(s) responsible for generating MCP230 EPFRs, which may run parallel to the conventional model. In this study, detailed spectral analysis was conducted using the EPR technique to examine the nature of DCB230 EPFRs and the aging phenomenon of DCB230 EPFRs while they exist as surface-bound o-semiquinone radicals (o-SQ) on copper sites. Various aspects concerning bound radicals were explored, including the hydrogen-bonding tendencies of o-semiquinone (o-SQ) radicals, the potential reversibility of hydroxylation processes occurring on the catalyst's surface, and the analysis of selected EPR spectra using EasySpin MATLAB. Furthermore, alternative routes for EPFR generation were thoroughly discussed and compared with the conventional model.

Nanomaterial-Based CO2 Sensors.

The detection of carbon dioxide (CO2) is critical for environmental monitoring, chemical safety control, and many industrial applications. The manifold application fields as well as the huge range of CO2 concentration to be measured make CO2 sensing a challenging task. Thus, the ability to reliably and quantitatively detect carbon dioxide requires vastly improved materials and approaches that can work under different environmental conditions. Due to their unique favorable chemical, optical, physical, and electrical properties, nanomaterials are considered state-of-the-art sensing materials. This mini-review documents the advancement of nanomaterial-based CO2 sensors in the last two decades and discusses their strengths, weaknesses, and major applications. The use of nanomaterials for CO2 sensing offers several improvements in terms of selectivity, sensitivity, response time, and detection, demonstrating the advantage of using nanomaterials for developing high-performance CO2 sensors. Anticipated future trends in the area of nanomaterial-based CO2 sensors are also discussed in light of the existing limitations.

Coaxial nanofibers outperform uniaxial nanofibers for the loading and release of pyrroloquinoline quinone (PQQ) for biomedical applications.

Pyrroloquinoline quinone (PQQ), present in breast milk and various foods, is highly recommended as an antioxidant, anti-inflammatory agent, and a cofactor in redox reactions in several biomedical fields. Moreover, PQQ has neuroprotective effects on nervous system disorders and immunosuppressive effects on different diseases. Herein, we report on the optimum fabrication of electrospun CS/PVA coaxial, core/shell, and uniaxial nanofibers. The morphological, elemental, and chemical structure of the fabricated nanofibers were investigated and discussed. PQQ, as a drug, was loaded on the uniaxial nanofibers and in the core of the coaxial nanofibers and the sustained and controlled release of PQQ was compared and discussed. The results revealed the privilege of the coaxial over the uniaxial nanofibers in the sustained release and reduction of the initial burst of PQQ. Remarkably, the results revealed a higher degree of swelling for CS/PVA hollow nanofibers compared to that of the uniaxial and the coaxial nanofibers. The coaxial nanofibers showed a lower release rate than the uniaxial nanofibers. Moreover, the CS/PVA coaxial nanofibers loaded with PQQ were found to enhance cell viability and proliferation. Therefore, the CS/PVA coaxial nanofibers loaded with PQQ assembly is considered a superior drug delivery system for PQQ release.

Robust photoactive nanoadsorbents with antibacterial activity for the removal of dyes.

ZnO nanostructures (NS)/guar gum (GG) nanocomposites have been successfully synthesized and tested as sorbents for photodegradation, adsorption and antimicrobial activity for dye removal. The addition of ZnO improves the thermal stability of GG based on the ratio of the oxygen in the OH form and the total oxygen in the samples as indicated via XPS and FTIR analyses. Among all tested composites, the ZnO NPs/GG nanocomposite showed the highest photocatalytic activity and hence used in extended adsorption and degradation studies against the anionic dye reactive red (RR195) and the cationic dye Rhodamine B (RhB). The adsorption mechanism and kinetics were studied in details. The ZnO NPs/GG nanocomposite showed quite high removal efficiency for both dyes reaching about 96 degradation percent of the initial dye concentration as well as a high adsorption capacity reaching 70 mg g-1. The adsorption of both dyes on ZnO NPs/GG was found to obey the Freundlich adsorption model with pseudo-second-order kinetics. The antibacterial assay showed an enhanced antibacterial effect of ZnO/GG against E-Coli/TOP10 (PTA 10989) strain compared to pristine ZnO or pure guar gum. The obtained results were proved to be of high significance based on the statistical analysis using one-way ANOVA followed by Tukey's analysis.

Recent advances in the use of TiO2 nanotube powder in biological, environmental, and energy applications.

The use of titanium dioxide nanotubes in the powder form (TNTP) has been a hot topic for the past few decades in many applications. The high quality of the fabricated TNTP by various synthetic routes may meet the required threshold of performance in a plethora of fields such as drug delivery, sensors, supercapacitors, and photocatalytic applications. This review briefly discusses the synthesis techniques of TNTP, their use in various applications, and future perspectives to expand their use in more applications.