ABSTRACT
Poly(lactic acid) (PLA) reinforced with graphene has gained substantial interest as a biomaterial, where the tribological and mechanical behavior of PLA/graphene composites are major concerns. This study aims to develop PLA-based biocomposites reinforced with graphene oxide (GO) that have enhanced tribological capabilities. First, homogenous dispersions of GO and GO treated with the anionic surfactant dioctyl sulfosuccinate sodium salt (AOT) were retained. Then, poly(L-lactic acid) (PLLA) biopolymer and PLLA/GO, PLLA/GO(AOT), PLA/GO(AOT), and PLLA/polyethylene glycol (PEG)/GO biocomposite samples were produced via hot pressing, and their tribological behavior was examined in detail. The worn surface characteristics were examined using scanning electron microscopy (SEM), 3D confocal microscopy, and atomic force microscopy (AFM). Results showed that GO reinforcement considerably affected the sliding wear behavior of PLA. Contrary to anticipated, surface treatment of GO does not improve the PLLA/GO wear resistance; rather, it increases the wear rate. PEG positively affects the sliding wear performance of PLLA/GO. PLLA/GO and PLLA/PEG/GO biocomposites exhibited the lowest wear rate at normal loads of 5 and 8 N, respectively, which was decreased by about 50% compared to unreinforced PLLA samples. With the addition of GO, the wear mechanisms of the PLA-based biocomposites changed from adhesive wear to abrasive wear. These findings might increase the applicability of PLA-based biocomposites where tribological performance is the main concern, such as biodegradable implants for load-bearing bone fractures or scaffolds, opening up new opportunities for their use.
Subject(s)
Graphite , Biocompatible Materials , Polyethylene Glycols , PolyestersABSTRACT
Graphene has attracted extensive attention in various fields due to its intriguing properties. In this work, nanocomposite films based on poly(lactic acid) (PLA and PLLA) polymers filled with graphene oxide (GO) were developed. The impact of treating GO with the anionic surfactant dioctyl sulfosuccinate sodium salt (AOT) on the properties of the resulting nanocomposites was investigated. To determine the morphological, optical, and structural properties of the obtained materials, physicochemical analyses were performed, including scanning electron microscopy (SEM), atomic force microscopy (AFM), Fourier-transform infrared spectroscopy (FT-IR), and X-ray diffraction (XRD) analysis. Additionally, the thermal properties and wettability of neat polymers and nanocomposites were thoroughly investigated using differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and contact angle analysis. It was observed that GO was well dispersed throughout the PLA and PLLA matrix, leading to stronger interface bonding. The results demonstrate that the untreated and treated GO improved the crystallinity and thermal stability properties of the PLA and PLLA. However, the AOT-treated GO has significantly higher performance compared to the untreated GO in terms of crystallinity, melting temperature (increased by ~15 °C), and wettability (the contact angle decreased by ~30°). These findings reveal the high performance of the developed novel composite, which could be applied in tissue engineering as a scaffold.
