1.
Acta Crystallogr Sect E Struct Rep Online
; 67(Pt 7): m857, 2011 Jul 01.
Article
in English
| MEDLINE
| ID: mdl-21836856
ABSTRACT
The coordination geometry at the Mo(VI) atom in the title compound, [Mo(C(16)H(14)N(2)O(4))O(2)(C(2)H(6)OS)], is distorted octa-hedral. The phenolate O, imino N, oxide O from the enolized carbonyl group and one of the terminal O atoms form the equatorial plane; the axial positions are occupied by the other terminal O atom of the dioxidomolybdenum group and the donor O atom of DMSO. The O=Mo=O angle is 105.31â (6)°. An intra-molecular O-Hâ¯N hydrogen bond and weak inter-molecular C-Hâ¯O hydrogen bonds are present in the structure.