Advanced treatment of landfill leachate through combined Anammox-based biotreatment, O3/H2O2 oxidation, and activated carbon adsorption: technical performance, surrogate-based control strategy, and operational cost analysis.

The complexity of landfill leachate makes it difficult to treat it with a single biological/ physical/chemical process. Moreover, the dynamic leachate characteristics pose a challenge for effective process control. Therefore, a combined treatment, consisting of a one-stage partial nitrification-Anammox process, an O3/H2O2 process, and a granular activated carbon filtration (GAC) process, was investigated. Meanwhile, a novel surrogate-based ozone dose control strategy for O3/H2O2 process was evaluated. Results show that this three-stage process offers high removal of total nitrogen (> 90%), COD (chemical oxygen demand, 60-82%), and micropollutants (atrazine, alachlor, carbamazepine, and bisphenol A, > 96%), satisfying discharge requirements. In the combined post-treatment, ozone dosing for COD removal can be real-time controlled by UVA254 reduction monitoring, based on a specific correlation between COD and UVA254 changes. On the other hand, O3/H2O2 pre-treatment controlled at a 50% UVA254 reduction shows to be the optimal point, when adsorption is designed as the main step for COD removal. Cost analysis shows that post-treatment with low (high) organic load i.e., COD ≤ (≥)540 mg/L, a combination with O3/H2O2 (GAC) as the main step appears to be more cost-effective. Therefore, a dynamic operation strategy in response to the leachate change is recommended.

Surrogate-based follow-up of activated carbon adsorption preceded by ozonation for removal of bulk organics and micropollutants from landfill leachate.

Although combined ozonation with activated carbon (AC) adsorption is a promising technique for leachate treatment, little is known about how ozone-induced changes in leachate characteristics affect the organics adsorption, especially in view of emerging micropollutants (MPs) removal. Furthermore, the online monitoring of MPs is challenging but desirable for efficient treatment operation. This study investigates how preceding ozonation impacts the adsorption of bulk organics (expressed as chemical oxygen demand (COD)) and ozone-recalcitrant MPs, i.e., primidone, atrazine and alachlor, in leachate using batch and column adsorption tests. Additionally, a new surrogate-based model was evaluated for predicting MPs breakthrough. Batch tests revealed that ozonation results in a decreasing apparent affinity of COD towards AC, but the non-adsorbable part did not obviously change. The adsorption of MPs in ozonated leachate was (1-41%) higher than that in non-ozonated leachate, especially for the more hydrophobic alachlor and atrazine, due to a reduced sites competition from bulk organics. Column adsorption showed that ozonation delayed COD and MPs breakthrough due to the reduced COD loading and sites competition, respectively. An increased empty bed contact time (EBCT, 10-40 min) led to an increased COD uptake by a factor of 3.0-3.2 for ozonated and non-ozonated leachates, while MPs adsorption also increased, suggesting that pore blockage rather than site competition could be the dominant inhibitory effect. The data from column adsorption demonstrate the applicability of developed surrogate-based model for predicting MPs breakthrough. Particularly, the fitting parameters were not affected by change of leachate characteristics, while they were impacted by change of EBCT.