Magmatic connectivity among six Galápagos volcanoes revealed by satellite geodesy.

Shallow magmatic reservoirs that produce measurable volcanic surface deformation are often considered as discrete independent systems. However, petrological analyses of erupted products suggest that these may be the shallowest expression of extensive, heterogeneous magmatic systems that we show may be interconnected. We analyse time series of satellite-radar-measured displacements at Western Galápagos volcanoes from 2017 to 2022 and revisit historical displacements. We demonstrate that these volcanoes consistently experience correlated displacements during periods of heightened magma supply to the shallow crust. We rule out changes in static stress, shallow hydraulic connections, and data processing and analysis artefacts. We propose that episodic surges of magma into interconnected magmatic systems affect neighbouring volcanoes, simultaneously causing correlations in volcanic uplift and subsidence. While expected to occur globally, such processes are uniquely observable at the dense cluster of Western Galápagos volcanoes, thanks to the high rate of surface displacements and the wealth of geodetic measurements.

The source scaling and seismic productivity of slow slip transients.

Slow slip events (SSEs) represent a slow faulting process leading to aseismic strain release often accompanied by seismic tremor or earthquake swarms. The larger SSEs last longer and are often associated with intense and energetic tremor activity, suggesting that aseismic slip controls tremor genesis. A similar pattern has been observed for SSEs that trigger earthquake swarms, although no comparative studies exist on the source parameters of SSEs and tremor or earthquake swarms. We analyze the source scaling of SSEs and associated tremor- or swarm-like seismicity through our newly compiled dataset. We find a correlation between the aseismic and seismic moment release indicating that the shallower SSEs produce larger seismic moment release than deeper SSEs. The scaling may arise from the heterogeneous frictional and rheological properties of faults prone to SSEs and is mainly controlled by temperature. Our results indicate that similar physical phenomena govern tremor and earthquake swarms during SSEs.

Photochemical oxidative addition of B-H bonds at ruthenium and rhodium.

Metal phosphine hydrides of type RuP(4)H(2) and RhP(3)H(3) react photochemically with HB(pin)(pin = pinacolate) to form metal boryl hydride complexes via 16-electron intermediates generated by H(2) loss; the second order rate constants for reaction of the intermediates with HB(pin) are even larger than those for reaction with Et(3)SiH.