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Angew Chem Int Ed Engl ; 55(23): 6689-93, 2016 06 01.
Article in English | MEDLINE | ID: mdl-27088754

ABSTRACT

A practical and highly stereoselective iron-catalyzed cross-coupling reaction of stereodefined enol carbamates and Grignard reagents to yield tri- and tetrasubstituted acrylates is reported. A facile method for the stereoselective generation of these enol carbamates has also been developed.


Subject(s)
Carbamates/chemistry , Iron/chemistry , Acrylates/chemistry , Catalysis , Magnetic Resonance Spectroscopy , Stereoisomerism
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