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Chem Commun (Camb) ; 58(63): 8862-8865, 2022 Aug 04.
Article in English | MEDLINE | ID: mdl-35856288

ABSTRACT

The use of terephthalate ligands with CnH2n+1NH-chains (n ≥ 6) led to the isolation of the first examples of Zr4+-terephthalate MOFs with 6-connected frameworks. The material with hexyl-amino functional groups has been proved to be an exceptional sorbent for the removal of As(III/V) toxic species from aqueous media, whereas MOFs with heptyl to dodecyl-amino moieties are superhydrophobic with promising oil-water separation properties.


Subject(s)
Phthalic Acids , Hydrophobic and Hydrophilic Interactions , Water/chemistry
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