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1.
Materials (Basel) ; 14(13)2021 Jun 28.
Article in English | MEDLINE | ID: mdl-34203128

ABSTRACT

Cu(In,Ga)Se2 (CIGS) thin films were deposited at low temperature (350 °C) and high rate (10 µm/h) by a single stage process. The effect of post-deposition treatments at 400 °C and 500 °C by indium bromide vapor were studied and compared to the effect of a simple annealing under selenium. Structural, electrical, and chemical analyses demonstrate that there is a drastic difference between the different types of annealing, with the ones under indium bromide leading to much larger grains and higher conductivity. These properties are associated with a modification of the elemental profiles, specifically for gallium and sodium.

3.
Sci Adv ; 5(1): eaas9311, 2019 Jan.
Article in English | MEDLINE | ID: mdl-30746434

ABSTRACT

Methylammonium lead iodide (MAPbI3) exhibits exceptional photovoltaic performance, but there remains substantial controversy over the existence and impact of ferroelectricity on the photovoltaic response. We confirm ferroelectricity in MAPbI3 single crystals and demonstrate mediation of the electronic response by ferroelectric domain engineering. The ferroelectric response sharply declines above 57°C, consistent with the tetragonal-to-cubic phase transition. Concurrent band excitation piezoresponse force microscopy-contact Kelvin probe force microscopy shows that the measured response is not dominated by spurious electrostatic interactions. Large signal poling (>16 V/cm) orients the permanent polarization into large domains, which show stabilization over weeks. X-ray photoemission spectroscopy results indicate a shift of 400 meV in the binding energy of the iodine core level peaks upon poling, which is reflected in the carrier concentration results from scanning microwave impedance microscopy. The ability to control the ferroelectric response provides routes to increase device stability and photovoltaic performance through domain engineering.

4.
J Am Chem Soc ; 140(41): 13223-13232, 2018 Oct 17.
Article in English | MEDLINE | ID: mdl-30281296

ABSTRACT

The design and fabrication of stable and efficient photoelectrochemical devices requires the use of multifunctional structures with complex heterojunctions composed of semiconducting, protecting, and catalytic layers. Understanding charge transport across such devices is challenging due to the interplay of bulk and interfacial properties. In this work, we analyze hole transfer across n-Si(111)- R|TiO2 photoanodes where - R is a series of mixed aryl/methyl monolayers containing an increasing number of methoxy units (mono, di, and tri). In the dimethoxy case, triethylene glycol units were also appended to substantially enhance the dipolar character of the surface. We find that hole transport is limited at the n-Si(111)- R|TiO2 interface and occurs by two processes- thermionic emission and/or intraband tunneling-where the interplay between them is regulated by the interfacial molecular dipole. This was determined by characterizing the photoanode experimentally (X-ray photoelectron spectroscopy, voltammetry, impedance) with increasingly thick TiO2 films and complementing the characterization with a multiscale computational approach (first-principles density functional theory (DFT) and finite-element device modeling). The tested theoretical model that successfully distinguished thermionic emission and intraband tunneling was then used to predict the effect of solution potential on charge transport. This prediction was then experimentally validated using a series of nonaqueous redox couples (ferrocence derivatives spanning 800 mV). As a result, this work provides a fundamental understanding of charge transport across TiO2-protected electrodes, a widely used semiconductor passivation scheme, and demonstrates the predictive capability of the combined DFT/device-modeling approach.

5.
J Am Chem Soc ; 140(46): 15655-15660, 2018 Nov 21.
Article in English | MEDLINE | ID: mdl-30370765

ABSTRACT

New deposition methods of halide perovskites are being developed with the aim of improving solar cell power conversion efficiency by controlling the physiochemical properties of the perovskite film. In the case of methylammonium lead iodide (MAPbI3), deep level traps limit efficiency by participating in charge carrier recombination. Prior work has shown that the solar cell efficiency of MAPbI3 solar cells varied significantly with deposition method; specifically, efficiencies of 13.5 and 17.7% were observed for MAPbI3 processed with a one- and two-step method, respectively. However, the origin of the difference in efficiency remains unclear. In this study, we analyze the interplay between deep level traps and efficiency by simulating the photoexcited charge carrier pathway across solar cells processed via the one- and two-step method using finite-element drift-diffusion modeling. We determined that in the case of one-step processing, the traps propagate throughout the bulk, while for two-step, the traps congregate at the interface where the MAPbI3 was grown (mesoporous TiO2). Composition and structural analysis are used to propose a plausible explanation as to why the difference in processing changes the spatial distribution of the traps.

6.
J Am Chem Soc ; 140(1): 50-53, 2018 01 10.
Article in English | MEDLINE | ID: mdl-29271201

ABSTRACT

We present an integrated computational approach combining first-principles density functional theory (DFT) calculations with wxAMPS, a solid-state drift/diffusion device modeling software, to design functionalized photocathodes for high-efficiency H2 generation. As a case study, we have analyzed the performance of p-type Si(111) photocathodes functionalized with a set of 20 mixed aryl/methyl monolayers, which have a known synthetic route for attachment to Si(111). DFT is used to screen for high-performing monolayers by calculating the surface dipole induced by the functionalization. The trend in the calculated surface dipoles was validated using previously published experimental measurements. We find that the molecular dipole moment is a descriptor of the surface dipole. wxAMPS is used to predict the open-circuit voltage (efficiency) of the photocathode by calculating the photocurrent versus voltage behavior using the DFT surface dipole calculations as inputs to the simulation. We find that Voc saturates beyond a surface dipole of ∼0.3 eV, suggesting an upper limit for achievable device performance. This computational approach provides a possibility for the rational design of functionalized photocathodes for enhanced H2 generation by combining the angstrom-scale results obtained using DFT with the micron-to-nanometer scale capabilities of wxAMPS.

7.
RSC Adv ; 8(68): 38745-38750, 2018 Nov 16.
Article in English | MEDLINE | ID: mdl-35558285

ABSTRACT

Here we show that dendritic architectures are attractive as the basis of hierarchically structured battery electrodes. Dendritically structured FeS2, synthesized via simple thermal sulfidation of electrodeposited dendritic α-Fe, was formed into an electrode and cycled vs. lithium. The reversible capacities of the dendritic FeS2 cathode were 560 mA h g-1 at 0.5C and 533 mA h g-1 at 1.0C after 50 cycles over 0.7-3.0 V. Over 0.7-2.4 V, where the electrode is more stable, the reversible capacities are 348 mA h g-1 at 0.2C and 179 mA h g-1 at 1.0C after 150 cycles. The good cycling performance and high specific capacities of the dendritic FeS2 cathodes are attributed to the ability of a dendritic structure to provide good ion and electron conducting pathways, and a large surface area. Importantly, the dendritic structure appears capable of accommodating volume changes imposed by the lithiation and delithiation process. The presence of a Li2-x FeS2 phase is indicated for the first time by high-resolution transmission electron microscopy (HRTEM) and scanning transmission electron microscopy (STEM) electron energy loss spectroscopy (EELS). We suspect this phase is what enables electrochemical cycling to possess high reversibility over 0.7-2.4 V.

8.
Inorg Chem ; 56(20): 12328-12336, 2017 Oct 16.
Article in English | MEDLINE | ID: mdl-28956597

ABSTRACT

Solid-state nuclear magnetic resonance spectroscopy, X-ray diffraction, and Raman spectroscopy were used to show that Cu2ZnSnS4 (CZTS) bulk solids grown in the presence of oxygen had improved cation ordering compared to bulk solids grown without oxygen. Oxygen was shown to have negligible solubility in the CZTS phase. The addition of oxygen resulted in the formation of SnO2, leading to Sn-deficient CZTS. At the highest oxygen levels, other phases such as Cu9S5 and ZnS were observed. Beneficial ordering was only observed in samples produced with more than 2 at. % oxygen in the precursor materials but did not occur in samples designed with excess Sn and O. Thus, it is the removal of Sn and formation of Sn-deficient CZTS that improves ordering rather than the presence of SnO2 or O alone. These results indicate that using oxygen or air annealing to tailor the Sn content of CZTS followed by an etching step to remove SnO2 may significantly improve the properties of CZTS.

9.
ACS Appl Mater Interfaces ; 9(7): 5673-5677, 2017 Feb 22.
Article in English | MEDLINE | ID: mdl-28176522

ABSTRACT

One route to decreasing the absorption in CdS buffer layers in Cu(In,Ga)Se2 and Cu2ZnSn(S,Se)4 thin-film photovoltaics is by alloying. Here we use first-principles calculations based on hybrid functionals to assess the energetics and stability of quaternary Cd, Zn, O, and S (Cd1-xZnxOyS1-y) alloys within a regular solution model. Our results identify that full miscibility of most Cd1-xZnxOyS1-y compositions and even binaries like Zn(O,S) is outside typical photovoltaic processing conditions. The results suggest that the tendency for phase separation of the oxysulfides may drive the nucleation of other phases such as sulfates that have been increasingly observed in oxygenated CdS and ZnS.

10.
Sci Technol Adv Mater ; 18(1): 681-692, 2017.
Article in English | MEDLINE | ID: mdl-31001363

ABSTRACT

Photoelectrochemical water-splitting is a promising carbon-free fuel production method for producing H2 and O2 gas from liquid water. These cells are typically composed of at least one semiconductor photoelectrode which is prone to degradation and/or oxidation. Various surface modifications are known for stabilizing semiconductor photoelectrodes, yet stabilization techniques are often accompanied by a decrease in photoelectrode performance. However, the impact of surface modification on charge transport and its consequence on performance is still lacking, creating a roadblock for further improvements. In this review, we discuss how density functional theory and finite-element device simulations are reliable tools for providing insight into charge transport across modified photoelectrodes.

11.
J Phys Chem Lett ; 7(24): 4962-4967, 2016 Dec 15.
Article in English | MEDLINE | ID: mdl-27973863

ABSTRACT

The rear surfaces of CdTe photovoltaic devices without back contacts, grown by close-spaced sublimation (CSS), were analyzed using conductive atomic force microscopy (C-AFM). As-deposited and CdCl2-treated CdTe samples were compared to clarify the effect of the treatment on charge flow through grains and grain boundaries. The CdCl2-treated samples exhibit a more homogeneous and enhanced current flow across the grains as compared to the as-deposited samples. The grain boundaries show variable current. Under high bias, grain boundaries dominate current flow when the main junction is reverse biased and with the conducting current in reverse breakdown. Under the opposite bias conditions, where the contact of the conductive tip to the surface is reverse biased and under breakdown conditions, the current flow is uniform with little contrast between grains and grain boundaries. The results are interpreted as resulting from the improved crystallinity of the CdTe with reduced p-type doping along the grain boundaries.

12.
ChemSusChem ; 9(17): 2358-64, 2016 09 08.
Article in English | MEDLINE | ID: mdl-27535100

ABSTRACT

Alane (AlH3 ) is a unique energetic material that has not found a broad practical use for over 70 years because it is difficult to synthesize directly from its elements. Using density functional theory, we examine the defect-mediated formation of alane monomers on Al(111) in a two-step process: (1) dissociative adsorption of H2 and (2) alane formation, which are both endothermic on a clean surface. Only with Ti dopant to facilitate H2 dissociation and vacancies to provide Al adatoms, both processes become exothermic. In agreement, in situ scanning tunneling microscopy showed that during H2 exposure, alane monomers and clusters form primarily in the vicinity of Al vacancies and Ti atoms. Moreover, ball milling of the Al samples with Ti (providing necessary defects) showed a 10 % conversion of Al into AlH3 or closely related species at 344 bar H2 , indicating that the predicted pathway may lead to the direct synthesis of alane from elements at pressures much lower than the 10(4)  bar expected from bulk thermodynamics.


Subject(s)
Aluminum Compounds/chemistry , Aluminum/chemistry , Chemistry Techniques, Synthetic/methods , Models, Molecular , Molecular Conformation , Surface Properties
13.
Nano Lett ; 15(10): 6506-13, 2015 Oct 14.
Article in English | MEDLINE | ID: mdl-26317408

ABSTRACT

There is growing evidence that domain walls in ferroics can possess emergent properties that are absent in the bulk. For example, 180° ferroelectric domain walls in the ferroelectric-antiferromagnetic BiFeO3 are particularly interesting because they have been predicted to possess a range of intriguing behaviors, including electronic conduction and enhanced magnetization. To date, however, ordered arrays of such domain structures have not been reported. Here, we report the observation of 180° stripe nanodomains in (110)-oriented BiFeO3 thin films grown on orthorhombic GdScO3 (010)O substrates and their impact on exchange coupling to metallic ferromagnets. Nanoscale ferroelectric 180° stripe domains with {112̅} domain walls were observed in films <32 nm thick. With increasing film thickness, we observed a domain structure crossover from the depolarization field-driven 180° stripe nanodomains to 71° ferroelastic domains determined by the elastic energy. These 180° domain walls (which are typically cylindrical or meandering in nature due to a lack of strong anisotropy associated with the energy of such walls) are found to be highly ordered. Additional studies of Co0.9Fe0.1/BiFeO3 heterostructures reveal exchange bias and exchange enhancement in heterostructures based on BiFeO3 with 180° domain walls and an absence of exchange bias in heterostructures based on BiFeO3 with 71° domain walls; suggesting that the 180° domain walls could be the possible source for pinned uncompensated spins that give rise to exchange bias. This is further confirmed by X-ray circular magnetic dichroism studies, which demonstrate that films with predominantly 180° domain walls have larger magnetization than those with primarily 71° domain walls. Our results could be useful to extract the structure of domain walls and to explore domain wall functionalities in BiFeO3.

15.
J Am Chem Soc ; 134(25): 10670-81, 2012 Jun 27.
Article in English | MEDLINE | ID: mdl-22734693

ABSTRACT

The steady-state photoelectrochemical responses of p-GaP photoelectrodes immersed in aqueous electrolytes and sensitized separately by six triphenylmethane dyes (rose bengal, rhodamine B, crystal violet, ethyl violet, fast green fcf, and brilliant green) have been analyzed. Impedance measurements indicated that these p-GaP(100) photoelectrodes operated under depletion conditions with an electric field of ∼8.5 × 10(5) V cm(-1) at the p-GaP/solution interface. The set of collected wavelength-dependent quantum yield responses were consistent with sensitization occurring specifically from adsorbed triphenylmethane dyes. At high concentrations of dissolved dye, the measured steady-state photocurrent-potential responses collected at sub-bandgap wavelengths suggested unexpectedly high (>0.1) net internal quantum yields for sensitized hole injection. Separate measurements performed with rose bengal adsorbed on p-GaP surfaces pretreated with (NH(4))(2)S verified efficient sensitized hole injection. A modified version of wxAMPS, a finite-difference software package, was utilized to assess key operational features of the sensitized p-GaP photocathodes. The net analysis showed that the high internal quantum yield values inferred from the experimental data were most likely afforded by the internal electric field present within p-GaP, effectively sweeping injected holes away from the interface and minimizing their participation in deleterious pathways that could limit the net collection yield. These simulations defined effective threshold values for the charge carrier mobilities (≥10(-6) cm(2) V(-1) s(-1) and ≥10(-1) cm(2) V(-1) s(-1) at dopant densities of 10(18) and 10(13) cm(-3), respectively), hole injection rate constants (≥10(12) s(-1)), and surface trap densities (10(12) cm(-2)) needed to attain efficient hole collection with the quality of p-GaP materials used here. The cumulative experimental and modeling data thus provide insight on design strategies for assembling new types of dye-sensitized photocathodes that operate under depletion conditions.

16.
Anal Chem ; 84(6): 2990-4, 2012 Mar 20.
Article in English | MEDLINE | ID: mdl-22369585

ABSTRACT

A noncontact chemical and electrical measurement X-ray photoelectron spectroscopy (XPS) technique is performed to investigate a CdS-based photoresistor during its operation. The main objective of the technique is to trace chemical- and location-specified surface potential variations as shifts of the XPS Cd 3d(5/2) peak position without and under photoillumination with four different lasers. The system is also modeled to extract electrical information. By analyzing the measured potential variations with this model, location-dependent resistance values are represented (i) two dimensionally for line scans and (ii) three dimensionally for areal measurements. In both cases, one of the dimensions is the binding energy. The main advantage of the technique is its ability to assess an element-specific surface electrical potential of a device under operation based on the energy deviation of core level peaks in surface domains. Detection of the variations in electrical potentials and especially their responses to the energy of the illuminating source in operando, is also shown to be capable of detecting, locating, and identifying the chemical nature of structural and other types of defects.

17.
ACS Nano ; 4(11): 6818-24, 2010 Nov 23.
Article in English | MEDLINE | ID: mdl-20964393

ABSTRACT

Sub-5 nm metallic hafnium diboride (HfB(2)) nanostructures were directly written onto Si(100)-2 × 1:H surfaces using ultrahigh vacuum scanning tunneling microscope (UHV-STM) electron beam induced deposition (EBID) of a carbon-free precursor molecule, tetrakis(tetrahydroborato)hafnium, Hf(BH(4))(4). Scanning tunneling spectroscopy data confirm the metallic nature of the HfB(2) nanostructures, which have been written down to lateral dimensions of ∼2.5 nm. To our knowledge, this is the first demonstration of sub-5 nm metallic nanostructures in an STM-EBID experiment.

18.
Nat Mater ; 7(11): 907-15, 2008 Nov.
Article in English | MEDLINE | ID: mdl-18836435

ABSTRACT

The high natural abundance of silicon, together with its excellent reliability and good efficiency in solar cells, suggest its continued use in production of solar energy, on massive scales, for the foreseeable future. Although organics, nanocrystals, nanowires and other new materials hold significant promise, many opportunities continue to exist for research into unconventional means of exploiting silicon in advanced photovoltaic systems. Here, we describe modules that use large-scale arrays of silicon solar microcells created from bulk wafers and integrated in diverse spatial layouts on foreign substrates by transfer printing. The resulting devices can offer useful features, including high degrees of mechanical flexibility, user-definable transparency and ultrathin-form-factor microconcentrator designs. Detailed studies of the processes for creating and manipulating such microcells, together with theoretical and experimental investigations of the electrical, mechanical and optical characteristics of several types of module that incorporate them, illuminate the key aspects.

19.
J Am Chem Soc ; 128(1): 131-42, 2006 Jan 11.
Article in English | MEDLINE | ID: mdl-16390140

ABSTRACT

We describe a theoretical analysis of the structures of self-organizing nanoparticles formed by Pt and Ru-Pt on carbon support. The calculations provide insights into the nature of these metal particle systems-ones of current interest for use as the electrocatalytic materials of direct oxidation fuel cells-and clarify complex behaviors noted in earlier experimental studies. With clusters deposited via metallo-organic Pt or PtRu(5) complexes, previous experiments [Nashner et al. J. Am. Chem. Soc. 1997, 119, 7760; Nashner et al. J. Am. Chem. Soc. 1998, 120, 8093; Frenkel et al. J. Phys. Chem. B 2001, 105, 12689] showed that the Pt and Pt-Ru based clusters are formed with fcc(111)-stacked cuboctahedral geometry and essentially bulklike metal-metal bond lengths, even for the smallest (few atom) nanoparticles for which the average coordination number is much smaller than that in the bulk, and that Pt in bimetallic [PtRu(5)] clusters segregates to the ambient surface of the supported nanoparticles. We explain these observations and characterize the cluster structures and bond length distributions using density functional theory calculations with graphite as a model for the support. The present study reveals the origin of the observed metal-metal bond length disorder, distinctively different for each system, and demonstrates the profound consequences that result from the cluster/carbon-support interactions and their key role in the structure and electronic properties of supported metallic nanoparticles.

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