ABSTRACT
Due to the different uses of radioactivity during the last decades, there has been an increase in the concentration of natural and artificial radionuclides in the environment. This, along with some accidents with a high affect public opinion (for example, Chernobyl and Fukushima), have led to the growth and establishment of environmental radioactivity monitoring programs. Currently, trends in legislation and research are focused on the development of accurate, precise, reliable and fast analytical methods with low limits of detection (LOD) for radionuclides determination, such as strontium and yttrium, in environmental samples. In this paper, two comprehensive reviews and four automated analytical systems for total and isotopic determination of yttrium and strontium are presented. The developed methods have been applied in the analysis of environmental samples with low concentrations of these analytes. These methodologies have been automated by exploiting flow analysis techniques, such as multi-syringe flow injection analysis (MSFIA), Sequential injection analysis (SIA) and laboratory-on-valve (LOV) systems, achieving a minimal handling and low consumption of samples and reagents, a significant reduction in waste generation and a high frequency of analysis. In the developed methodologies, some spectrometric methods such as ICP-OES and ICP-MS have been implemented as detection techniques instead of radiometric detectors obtaining a fully automated, low-cost and fast yttrium and strontium determinations.
ABSTRACT
The presence of artificial and natural radioactivity in the environment is currently a topic of great relevance and ecological interest, even in human health issue, due to the increase of different anthropogenic activities. The use of multicommuted flow analysis techniques (e.g. Multi-Syringe Flow Injection Analysis - MSFIA, Lab-On-Valve - LOV and Lab-In-Syringe - LIS) has allowed the automation of radiochemical procedures to separate and preconcentrate radionuclides in environmental and biological samples. In comparison with the manual approach commonly used in routine analysis for radioactivity monitoring, the automation has enabled the development of highly reproducible methodologies with a great analysis frequency. Moreover, during the analytical procedure, the intervention of the analyst is drastically reduced, minimizing the radiological risk. The automation also offers significant advantages such as minimum consumption of time and reagents, reducing the cost and the generation of waste, contributing to the green chemistry. In this review, several multicommuted flow analysis techniques (MSFIA, LOV and LIS) reported in the last decade applied for the development of automatic sample treatment methodologies, used to separate, preconcentrate and quantify 90Sr, 99Tc, natural U and 226Ra in biological and environmental samples are described and critically compared.
