1.
J Org Chem
; 84(6): 3508-3523, 2019 03 15.
Article
in English
| MEDLINE
| ID: mdl-30779561
ABSTRACT
Owing to the pervasiveness of hydroxyl groups in natural isolates, alcohol derivatives are alluring directing groups. Herein, an alcohol-derived sulfamate ester guides the light-initiated xanthylation of primary, secondary, or tertiary centers. This process enables formal directed deuteration, azidation, thiolation, and vinylation reactions.