The high dose of biochar reduces polycyclic aromatic hydrocarbons losses during co-composting of sewage sludge and wheat straw.

The aim of the study was to investigate the effect of the biochar (BC) dose on solvent extractable (Ctot) and freely dissolved (Cfree) polycyclic aromatic hydrocarbons (PAHs) content during co-composting. A significantly better reduction of Σ16 Ctot PAHs after 98 days occurred during composting with BC (for 1% of BC - 44% and for 5% of BC - 23%) than in the control (15%). Despite the relatively high reduction of Ctot PAHs in the experiment with 5% BC rate, the content of the PAHs was still the highest compared to other variants. Regarding Cfree PAHs, 5% rate of BC resulted in the best reduction of PAHs, while the 1% BC dose resulted in a lower reduction of Cfree than the control. For 1% BC, PAHs losses was more effective, and sequestration processes played a less significant role than in the experiment with 5% dose of BC. The total and dissolved organic carbon, and ash were predominantly responsible for Ctot and Cfree losses, and additionally pH for Cfree. The results of the experiment indicate that BC performs a crucial role in composting, affecting the Ctot and Cfree PAHs in the compost but the final effect strictly depends on the BC dose.

Adsorption and desorption of antiviral drugs (ritonavir and lopinavir) on sewage sludges as a potential environmental risk.

The aim of this work was to evaluate the adsorption capacity and mechanism of two antiviral drugs AVDs (lopinavir (LOP) and ritonavir (RIT)) on three various sewage sludges (SSLs). The results showed that SSLs differed in the structure and chemical composition and LOP and RIT had a high affinity to the studied SSLs (Kd in ranges 2076-3449 L/kg). The adsorption capacities differed between SSLs and ranged 7.55-8.71 mg/g (RIT) and 8.10-8.64 mg/g (LOP). The Freundlich model provided a best fitting of adsorption isotherms of all AVDs-SSLs. The adsorption kinetics were best described by pseudo-second order kinetic model. The adsorption of LOP and RIT on SSLs was exothermic, spontaneous, and thermodynamically feasible. The sorption of LOP and RIT to SSLs was complex due to the diverse chemical composition of SSLs and the differences in the chemical structure of AVDs. Analysis of binary solution of both AVDs showed the competition effect between AVDs and a decrease in adsorption efficiency (3-17%) compared to single solutions. The amount of desorbed AVDs from all SSLs was low (less than 15%). The findings of the present work are significant in the prediction of fate and persistence of AVDs on SSLs in the context of their further transmission and possible environmental contamination.

Sustainable biochar-based soil fertilizers and amendments as a new trend in biochar research.

Today's world is struggling with many environmental problems. Due to the ever-growing size of the population, it is necessary to produce more and more food. The consequence of such a large demand for food is excessive fertilization of soils, often in an uncontrolled manner. The paper presents an overview of the different types of biochar (BC) fertilizers obtained by: coating BCs with a protective layer, coating commercial fertilizers with a layer of BCs, or mixing BCs with commercial fertilizers. Although the use of these new types of fertilizers has a positive effect on soil properties and crop yields, the production and use of "simple" inorganic fertilizers are dominant. The solution to starting the change of this trend may be the use of BC-compost systems as an effective soil amendment, due to the fact that composts are still the most frequently used products by farmers. The review summarized two types of BC-compost soil amendments: BC mixed with ready-made compost and BC co-composted with compost raw material. These types of soil amendments contribute to a significant reduction in the consumption of commercial inorganic fertilizers, and thus less pollution of the natural environment, while allowing for a high yield of safe food.