ABSTRACT
Surface interactions between emulsion drops and substrate surfaces play an important role in many phenomena in industrial processes, such as fouling issues in oil production. Investigating the interaction forces between the water-in-oil emulsion drops with interfacially adsorbed asphaltenes and various substrates is of fundamental and practical importance in understanding the fouling mechanisms and developing efficient antifouling strategies. In this work, the surface interactions between water drops with asphaltenes and Fe substrates with or without an electroless nickel-phosphorus (EN) coating in organic media have been directly quantified using the atomic force microscope drop probe technique. The effects of asphaltene concentration, organic solvent type, aging time, contact time, and loading force were investigated. The results demonstrated that the adhesion between water drops and the substrates was enhanced with higher asphaltene concentration, better organic solvent to asphaltenes, longer aging time, longer contact time, and stronger loading force, which was due to the growing amount and conformational change of asphaltenes adsorbed at the water/oil interface. Meanwhile, the adhesion between the water drop and the EN substrate was much weaker than that with the Fe substrate. The bulk fouling tests also showed that EN coating had a very good antifouling performance, which was in consistence with the force measurement results. Our work sheds light on the fundamental understanding of emulsion-related fouling mechanisms in the oil industry and provides useful information for developing new coatings with antifouling performances.
ABSTRACT
In petroleum engineering, the transport phenomenon of proppants in a fracture caused by hydraulic fracturing is captured by hyperbolic partial differential equations (PDEs). The solution of this kind of PDEs may encounter smooth transitions, or there can be large gradients of the field variables. The numerical challenge posed in a shock situation is that high-order finite difference schemes lead to significant oscillations in the vicinity of shocks despite that such schemes result in higher accuracy in smooth regions. On the other hand, first-order methods provide monotonic solution convergences near the shocks, while giving poorer accuracy in the smooth regions. Accurate numerical simulation of such systems is a challenging task using conventional numerical methods. In this paper, we investigate several shock-capturing schemes. The competency of each scheme was tested against one-dimensional benchmark problems as well as published numerical experiments. The numerical results have shown good performance of high-resolution finite volume methods in capturing shocks by resolving discontinuities while maintaining accuracy in the smooth regions. These methods along with Godunov splitting are applied to model proppant transport in fractures. It is concluded that the proposed scheme produces non-oscillatory and accurate results in obtaining a solution for proppant transport problems.
