ABSTRACT
We present a laboratory study of the polycyclic aromatic hydrocarbon (PAH) anthracoronene (AntCor, C36H18) in simulated interstellar ices in order to determine its possible contribution to the broad infrared absorption bands in the 5-8 µm wavelength interval. The Fourier transform infrared (FTIR) spectrum of AntCor, codeposited with water ice, was collected. The FTIR spectrum of the sample irradiated with ultraviolet photons was also collected. Unirradiated and UV-irradiated AntCor embedded in water ice have not been studied before; therefore, the molecule's band positions and intensities were compared to published data on AntCor in an argon matrix and theoretical calculations (DFT), as well as the published results of its parent molecules, coronene and anthracene, in water ice. The experimental band strengths for unirradiated AntCor exhibit variability as a function of PAH:H2O concentration, with two distinct groupings of band intensities. AntCor clustering occurs for all concentrations and has a significant effect on PAH degradation rates and photoproduct variability. Near-IR spectra of irradiated AntCor samples show that AntCor+ production increases as the concentration of AntCor in water ice decreases. Photoproduct bands are assigned to AntCor+, cationic alcohols, protonated AntCor, and ketones. We report the rate constants of the photoproduct production for the 1:1280 AntCor:H2O concentration. CO2 production from AntCor is much less than what was previously reported for Ant and Cor and exhibits two distinct regimes as a function of AntCor:H2O concentration. The contribution of AntCor photoproducts to astronomical spectra can be estimated by comparison with the observed intensities in the 7.4-8.0 µm range.
ABSTRACT
PAH clusters are one candidate species for the interstellar "very small grains" or "VSGs", i.e., dust grains small enough to be stochastically heated and contribute to the aromatic infrared emission bands (AIBs). This possibility motivated laboratory experiments on the infrared spectroscopy of PAH clusters using matrix isolation spectroscopy. The spectral shifts due to PAH clustering in argon matrices provide clues for the AIB contribution from PAH clusters in the interstellar medium. Here we review results from a number of small PAH species, extrapolation to the much larger PAHs believed to be present in the interstellar medium, and the implications for a PAH cluster contribution to the VSG population.
ABSTRACT
We have investigated the mid-infrared spectral characteristics of a series of polycyclic aromatic hydrocarbons (PAHs) with straight edges and containing an even or odd number of carbons using density functional theory (DFT). For several even and odd-carbon PAHs, the 8.6/6.2 and 7.6/6.2 intensity ratios computed in emission after the absorption of a 8 eV photon match the observed ratios obtained for three reflection nebulae (RNe), namely NGC 1333, NGC 7023, and NGC 2023. Odd-carbon PAHs are favored, particularly for NGC 1333. Both cations and anions are present with the cations being predominant. Relevant PAHs span sizes ranging from 46 to 103-113 carbons for NGC 7023 and NGC 2023 and from 38 to 127 carbons for NGC 1333 and have symmetries ranging from D2h to C s . Our work suggests that even and odd-carbon PAHs with straight edges are viable candidates for the PAH emission seen towards irradiated Photo-Dissociation Regions (PDRs).
