The estimation of infiltration and inflow in a sewage network by combining continuous monitoring of hydrological parameters, flow and temperature with stable isotopes of oxygen and hydrogen.

The failure of sewage network systems can lead to the introduction of external water, impacting the capacity, performance, and environmental sustainability of urban infrastructures. This study examined methods for identifying and quantifying external water in a sewage system in cold climate conditions through the analysis of stable isotope of oxygen (δ18O) and hydrogen (δ2H) from samples, and continuous temperature monitoring, followed by the simulation of the network's hydraulics and temperature profile. The assessment was conducted during periods of low and high groundwater levels, specifically during dry weather flow. In comparison, the yearly trends of infiltration and inflow rates were assessed utilizing the moving minimum method. Using δ18O as a tracer, daily infiltration rates of 5.8 % and 35 % were estimated for periods of low and high groundwater levels, respectively. Using the outputs of the thermodynamic model, temperature was used as a tracer and the daily infiltration rates were found to be 1.5 % and 21.9 % for the same periods. The infiltration and inflow rate for the year in question was estimated to be 23 % using the moving minimum method. The findings of this study demonstrate the temporal variability of infiltration in networks and highlight the need for, as well as the potential of, a multi-faceted approach and continuous monitoring for the accurate estimation of external water before sewage network renovations are carried out.

Implementing risk-based approaches to improve drinking water quality in small water supplies in the Nordic region - barriers and solutions.

Small water supplies face similar problems worldwide, regardless of ownership or management type. Non-compliance with water quality regulations is more frequent in small supplies than in large ones, as are waterborne disease outbreaks. The new European Union Drinking Water Directive requires risk-based approach (RBA) to secure water safety as is recommended in the World Health Organization's Guidelines for drinking water quality through 'water safety plans'. This is already in regulation in the Nordic countries, although less used in small supplies. In this research, we explore the challenges, barriers and possible solutions to implementing RBA and improving compliance in small supplies. This was achieved by conducting and analysing interviews with 53 stakeholders from all eight Nordic countries to produce recommendations for action by the different implicated actors. Our findings suggest the centrality of governmental policy, including support for continuous training, provision of simple RBA guidelines and increasing cooperation in the water sector. The Nordic experience reflects global challenges with small water supplies and the trend towards systematic preventive management epitomized in the framework for drinking water safety advocated by the World Health Organization since 2004.

Treatment efficiency of package plants for on-site wastewater treatment in cold climates.

Package plants (PP) are implemented around the world to provide on-site sanitation in areas not connected to a sewage network. The efficiency of PP has not been comprehensively studied at full scale, and the limited number of available studies have shown that their performance varies greatly. Their performance under cold climate conditions and the occurrence of micropollutants in PP effluents have not been sufficiently explored. PP are exposed to environmental factors such as low temperature, especially in cold regions with low winter temperatures and deep frost penetration, that can adversely influence the biochemical processes. The aim of this study was to investigate the treatment efficiency and possible effects of cold temperatures on PP performance, with focus on traditional contaminants (organics, solids, nutrients and indicator bacteria) and an additional assessment of micropollutants on two PP. Eleven PP hosting different treatment processes were monitored. Removal of biological oxygen demand (BOD) was high in all plants (>91%). Six out of the 11 PP provided good phosphorus removal (>71%). Small degrees of nitrification were observed in almost all the facilities, despite the low temperatures, while denitrification was only observed in two plants which achieved the highest nitrification rates (>51%) and had sludge recirculation. No strong correlation between wastewater temperature and BOD, nutrients and indicator bacteria concentration in the effluents was found. The high data variability and the effects of other process parameters as well as snow-melt water infiltration are suggested as possible reasons for the lack of correlation. However, weak negative relations between effluent concentrations and wastewater temperatures were detected in specific plants, indicating that temperature does have effects. When managed adequately, package plants can provide high BOD and phosphorus removal, but nitrogen and bacteria removal remain challenging, especially at low temperatures. Pharmaceutical compounds were detected in the effluents at concentrations within or above ranges reported for large treatment plants while phthalate ester concentrations were below commonly reported effluent concentrations.

Monitoring groundwater quality with real-time data, stable water isotopes, and microbial community analysis: A comparison with conventional methods.

Groundwater provides much of the world's potable water. Nevertheless, groundwater quality monitoring programmes often rely on a sporadic, slow, and narrowly focused combination of periodic manual sampling and laboratory analyses, such that some water quality deficiencies go undetected, or are detected too late to prevent adverse consequences. In an effort to address this shortcoming, we conducted enhanced monitoring of untreated groundwater quality over 12 months (February 2019-February 2020) in four shallow wells supplying potable water in Finland. We supplemented periodic manual sampling and laboratory analyses with (i) real-time online monitoring of physicochemical and hydrological parameters, (ii) analysis of stable water isotopes from groundwater and nearby surface waters, and (iii) microbial community analysis of groundwater via amplicon sequencing of the 16S rRNA gene and 16S rRNA. We also developed an early warning system (EWS) for detecting water quality anomalies by automating real-time online monitoring data collection, transfer, and analysis - using electrical conductivity (EC) and turbidity as indirect water quality indicators. Real-time online monitoring measurements were largely in fair agreement with periodic manual measurements, demonstrating their usefulness for monitoring water quality; and the findings of conventional monitoring, stable water isotopes, and microbial community analysis revealed indications of surface water intrusion and faecal contamination at some of the studied sites. With further advances in technology and affordability expected into the future, the supplementary methods used here could be more widely implemented to enhance groundwater quality monitoring - by contributing new insights and/or corroborating the findings of conventional analyses.

Stable water isotopes as a tool for assessing groundwater infiltration in sewage networks in cold climate conditions.

Effective identification and quantification of groundwater (GW) infiltration into sewage collection networks represents an important step towards sustainable urban water management. In many countries, including northern regions, sewage networks are aging to the point where renovation is needed. This study focused on the utilization of stable water isotopes as tracer substances for GW infiltration detection. The main objectives were to investigate the validity of the method for quantifying GW infiltration in cold climate conditions and to test the robustness of this method under assumed low GW infiltration rates. In general, the stable water isotopes (δ18O) produced reliable results regarding origin identification and quantification of GW infiltration rates in winter conditions (continuous below zero temperatures and snow accumulation during preceding months). The 1.6‰ distinction between the δ18O isotope composition signals of the two water sources (drinking water from river and groundwater) in the studied network was sufficient to allow source separation. However, a larger distinction would reduce the uncertainties connected to GW-fraction identification in situations where low GW infiltration rates (<8%) are expected. Due to the climate conditions (no surface water inflow), GW infiltration to the network branch monitored represented the totality of I/I (infiltration/surface inflow) flows and was estimated to reach a maximum daily rate of 6.5%. This being substantially lower than the 29% yearly average I/I rate of ca 29% reported for the city's network. Overall, our study tested the stable water isotope method for GW infiltration detection in sewage networks successfully and proved the suitability of this method for network assessment in cold climate conditions. Isotope sampling could be part of frequent monitoring campaigns revealing potential infiltration and, consequently, the need for renovation.

Surface Water Intrusion, Land Use Impacts, and Bacterial Community Composition in Shallow Groundwater Wells Supplying Potable Water in Sparsely Populated Areas of a Boreal Region.

Rural communities often rely on groundwater for potable water supply. In this study, untreated groundwater samples from 28 shallow groundwater wells in Finland (<10 m deep and mostly supplying untreated groundwater to <200 users in rural areas) were assessed for physicochemical water quality, stable water isotopes, microbial water quality indicators, host-specific microbial source tracking (MST) markers, and bacterial community composition, activity, and diversity (using amplicon sequencing of the 16S rRNA gene and 16S rRNA). Indications of surface water intrusion were identified in five wells, and these indications were found to be negatively correlated, overall, with bacterial alpha diversity (based on amplicon sequencing of the 16S rRNA gene). High levels of turbidity, heterotrophs, and iron compromised water quality in two wells, with values up to 2.98 nephelometric turbidity units (NTU), 16,000 CFU/ml, and 2,300 µg/liter, respectively. Coliform bacteria and general fecal indicator Bacteroidales bacteria (GenBac3) were detected in 14 and 10 wells, respectively (albeit mostly at low levels), and correlations were identified between microbial, physicochemical, and environmental parameters, which may indicate impacts from nearby land use (e.g., agriculture, surface water, road salt used for deicing). Our results show that although water quality was generally adequate in most of the studied wells, the continued safe use of these wells should not be taken for granted. IMPORTANCE Standard physicochemical water quality analyses and microbial indicator analyses leave much of the (largely uncultured) complexity of groundwater microbial communities unexplored. This study combined these standard methods with additional analyses of stable water isotopes, bacterial community data, and environmental data about the surrounding areas to investigate the associations between physicochemical and microbial properties of 28 shallow groundwater wells in Finland. We detected impaired groundwater quality in some wells, identified potential land use impacts, and revealed indications of surface water intrusion which were negatively correlated with bacterial alpha diversity. The potential influence of surface water intrusion on groundwater wells and their bacterial communities is of particular interest and warrants further investigation because surface water intrusion has previously been linked to groundwater contamination, which is the primary cause of waterborne outbreaks in the Nordic region and one of the major causes in the United States and Canada.

Bacterial communities at a groundwater-surface water ecotone: gradual change or abrupt transition points along a contamination gradient?

Microbial communities contribute greatly to groundwater quality, but the impacts of land-use practices on bacteria in groundwaters and groundwater-dependent ecosystems remain poorly known. With 16S rRNA gene amplicon sequencing, we assessed bacterial community composition at the groundwater-surface water ecotone of boreal springs impacted by urbanization and agriculture, using spring water nitrate-N as a surrogate of contamination. We also measured the rate of a key ecosystem process, organic matter decomposition. We documented a recurrent pattern across all major bacterial phyla where diversity started to decrease at unexpectedly low nitrate-N concentrations (100-300 µg L-1 ). At 400 NO3 - -N µg L-1 , 25 bacterial exact sequence variants showed a negative response, resulting in a distinct threshold in bacterial community composition. Chthonomonas, Acetobacterales and Hyphomicrobium were the most sensitive taxa, while only three taxa (Duganella, Undibacterium and Thermoanaerobaculaceae) were enriched due to increased contamination. Decomposition rate responded unimodally to increasing nitrate-N concentration, with a peak rate at ~400 NO3 - -N µg L-1 , parallelly with a major shift in bacterial community composition. Our results emphasize the utility of bacterial communities in the assessment of groundwater-dependent ecosystems. They also call for a careful reconsideration of threshold nitrate values for defining groundwater ecosystem health and protecting their microbial biodiversity.

Status of risk-based approach and national framework for safe drinking water in small water supplies of the Nordic water sector.

Reliable safe water supply is a pillar of society and a key to public health. The Nordic countries have an abundance of clean fresh water as a source for drinking water supplies. They have followed developments in safeguarding water, both the recommendations of the World Health Organization framework for safe drinking water and European legislation. Worldwide, including the Nordic countries, small water supplies are less compliant with water safety regulation. The forthcoming EU directive on drinking water require risk-based approaches and improved transparency on water quality. This research looks at the Nordic frameworks for safe water supply, with emphasis on risk-based approaches and smaller systems. We analyzed the legal frameworks for safe water, the structure of the water sector across the Nordic countries and explored how prepared these countries are to meet these requirements. Our findings show that, while legal requirements are mostly in place, delivery of information to the public needs to be improved. Most Nordic countries are in the process of implementing risk-based management in large and medium size water supplies, whereas small supplies are lagging. We conclude that a key to success is increased training and support for small supplies. We suggest wider adoption of the Nordic model of cooperation with benchmarking of safe water for all to transfer knowledge between the countries. This work provides insights into challenges and opportunities for the Nordic countries and provides insights relevant to countries worldwide in their effort towards realization of SDG Target 6.1.

RiMARS: An automated river morphodynamics analysis method based on remote sensing multispectral datasets.

Assessment and monitoring of river morphology own an important role in river engineering; since, changes in river morphology including erosion and sedimentation affect river cross-sections and flow processes. An approach for River Morphodynamics Analysis based on Remote Sensing (RiMARS) was developed and tested on the case of Mollasadra dam construction on the Kor River, Iran. Landsat multispectral images obtained from the open USGS dataset are used to extract river morphology dynamics by the Modified Normalized Difference Water Index (MNDWI). RiMARS comes with a river extraction module which is independent of threshold segmentation methods to produce binary-level images. In addition, RiMARS is equipped with developed indices for assessing the morphological alterations. Five characteristics of river morphology (spatiotemporal Sinuosity Index (SI), Absolute Centerline Migration (ACM), Rate of Centerline Migration (RCM), River Linear Pattern (RLP), and Meander Migration Index (MMI)), are applied to quantify river morphology changes. The results indicated that the Kor River centerline underwent average annual migration of 40 cm to the southwest during 1993-2003 (pre-construction impact), 20 cm to the northeast during 2003-2011, and 40 cm to the south-west during 2011-2017 (post-construction impact). Spatially, as the Kor River runs towards the Doroudzan dam, changes in river morphology have increased from upstream to downstream; particularly evident where the river flows in a plain instead of the valley. Based on SI values, there was a 5% change in the straight sinuosity class in the pre-construction period, but an 18% decrease in the straight class during the post-construction period. Here we demonstrate the application of RiMARS in assessing the impact of dam construction on morphometric processes in Kor River, but it can be used to assess other riverine changes, including tracking the unauthorized water consumption using diverted canals. RiMARS can be applied on multispectral images.

Predicting iron transport in boreal agriculture-dominated catchments under a changing climate.

Increases in iron (Fe) concentration have been reported in boreal regions in recent decades, raising concerns about the fate of ecosystems along water courses. In this study, the SWAT (Soil and Water Assessment Tool) model was applied to the river Mustijoki catchment in southern Finland to determine the current state of Fe transport and to evaluate possible effects of ongoing environmental change in this agriculture-dominated catchment. The model was calibrated using five-year discharge, suspended solids, and Fe data, and validated with a three-year dataset of the same parameters. Further, the model was run with spatially downscaled and bias-corrected climate change scenario data to the year 2100 obtained using five different global climate models. The results were divided into 20-year time steps (2020-2039, 2040-2059, 2060-2079, 2080-2099) and compared against a reference modeling period (1997-2016). With present catchment characteristics of the river Mustijoki, Fe transport was shown to be related to soil erosion and suspended solids transport, driven by hydrological conditions. Arable fields, especially with steeper slopes, were identified as the most likely source of Fe loading. Climate change-induced alterations in riverine Fe transport were simulated as concentrations and as annual mass fluxes. High Fe transport season is already shifting from spring snowmelt events to autumn and winter, and this change is likely to increase in coming decades. Based on modeling results, annual peak concentration in the River Mustijoki was projected to decrease by up to 32% (from 6.2 mg L-1 to 4.2 mg L-1 in scenarios RCP4.5 and RCP8.5) in the coming 20-year period, while lowest winter concentration was projected to increase by 126% (from 1.5 mg L-1 in the reference period (1997-2016) to 3.5 mg L-1 in 2080-2099 in scenario RCP8.5. To compensate for these changes in Fe transport dynamics, water protection and land use management planning must be improved.

Groundwater contamination and land drainage induce divergent responses in boreal spring ecosystems.

Degradation of freshwater ecosystems has engendered legislative mandates for the protection and management of surface waters while groundwater-dependent ecosystems (GDEs) have received much less attention. This is so despite biodiversity and functioning of GDEs are currently threatened by several anthropogenic stressors, particularly intensified land use and groundwater contamination. We assessed the impacts of land drainage (increased input of dissolved organic carbon, DOC, from peatland drainage) and impaired groundwater chemical quality (NO3--N enrichment from agricultural or urban land use) on biodiversity and ecosystem functioning in 20 southern Finnish cold-water springs using several taxonomic and functional measures. Groundwater contamination decreased macroinvertebrate and bacterial diversity and altered their community composition. Changes in macroinvertebrate and bacterial communities along the gradient of water-quality impairment were caused by the replacement of native with new taxa rather than by mere disappearance of some of the original taxa. Also species richness of habitat specialist (but not headwater generalist) bryophytes decreased due to impaired groundwater quality. Periphyton accrual rate showed a subsidy-stress response to elevated nitrate concentrations, with peak values at around 2500 µg L-1, while drainage-induced spring water brownification (increased DOC) reduced both periphyton accrual and leaf decomposition rates already at very low concentrations. Our results highlight the underutilized potential of ecosystem-level functional measures in GDE bioassessment as they seem to respond to the first signs of spring ecosystem impairment, at least for the anthropogenic stressors studied by us.

Climate-induced warming imposes a threat to north European spring ecosystems.

Interest in climate change effects on groundwater has increased dramatically during the last decade. The mechanisms of climate-related groundwater depletion have been thoroughly reviewed, but the influence of global warming on groundwater-dependent ecosystems (GDEs) remains poorly known. Here we report long-term water temperature trends in 66 northern European cold-water springs. A vast majority of the springs (82%) exhibited a significant increase in water temperature during 1968-2012. Mean spring water temperatures were closely related to regional air temperature and global radiative forcing of the corresponding year. Based on three alternative climate scenarios representing low (RCP2.6), intermediate (RCP6) and high-emission scenarios (RCP8.5), we estimate that increase in mean spring water temperature in the region is likely to range from 0.67 °C (RCP2.6) to 5.94 °C (RCP8.5) by 2086. According to the worst-case scenario, water temperature of these originally cold-water ecosystems (regional mean in the late 1970s: 4.7 °C) may exceed 12 °C by the end of this century. We used bryophyte and macroinvertebrate species data from Finnish springs and spring-fed streams to assess ecological impacts of the predicted warming. An increase in spring water temperature by several degrees will likely have substantial biodiversity impacts, causing regional extinction of native, cold-stenothermal spring specialists, whereas species diversity of headwater generalists is likely to increase. Even a slight (by 1 °C) increase in water temperature may eliminate endemic spring species, thus altering bryophyte and macroinvertebrate assemblages of spring-fed streams. Climate change-induced warming of northern regions may thus alter species composition of the spring biota and cause regional homogenization of biodiversity in headwater ecosystems.