Pressure threshold for inhibition of dense granular film opening.

Controlling the stability of a granular film is essential in a wide range of industrial applications, from aerated building materials to recovering ore by flotation and treating wastewater. We therefore carry out experiments of granular film opening where particles of hundred of micrometers above random close packing zip the two interfaces of a soap film which liquid pressure is controlled. We create a hole at the center of this dense granular film and, surprisingly, we observe that the opening is not always inhibited. Different behaviours are identified: total bursting of the granular film, intermittent opening and jammed state for which the hole does not evolve. The liquid pressure drives the transition from one opening behaviour to another. Lower is the liquid pressure, more jammed is the system. The critical pressure transition scales as the surface tension over the particle size until the finite size of the granular film is only few tens of the particle size. Ultimately we evidence that spontaneous hole in thin film between particle do not lead to the granular film failure.

The Life of a Surface Bubble.

Surface bubbles are present in many industrial processes and in nature, as well as in carbonated beverages. They have motivated many theoretical, numerical and experimental works. This paper presents the current knowledge on the physics of surface bubbles lifetime and shows the diversity of mechanisms at play that depend on the properties of the bath, the interfaces and the ambient air. In particular, we explore the role of drainage and evaporation on film thinning. We highlight the existence of two different scenarios depending on whether the cap film ruptures at large or small thickness compared to the thickness at which van der Waals interaction come in to play.

Trapping of swimming microalgae in foam.

Massive foam formation in aquatic environments is a seasonal event that has a significant impact on the stability of marine ecosystems. Liquid foams are known to filter passive solid particles, with large particles remaining trapped by confinement in the network of liquid channels and small particles being freely advected by the gravity-driven flow. By contrast, the potential role of a similar retention effect on biologically active particles such as phytoplankton cells is still relatively unknown. To assess if phytoplankton cells are passively advected through a foam, the model unicellular motile alga Chlamydomonas reinhardtii (CR) was incorporated in a bio-compatible foam, and the number of cells escaping the foam at the bottom was measured in time. Comparing the escape dynamics of living and dead CR cells, we found that dead cells are totally advected by the liquid flow towards the bottom of the foam, as expected since the diameter of CR remains smaller than the typical foam channel diameter. By contrast, living motile CR cells escape the foam at a significantly lower rate: after 2 hours, up to 60% of the injected cells may remain blocked in the foam, while 95% of the initial liquid volume in the foam has been drained out of the foam. Microscopic observation of the swimming CR cells in a chamber mimicking the cross-section of foam internal channels revealed that swimming CR cells accumulate near channels corners. A theoretical analysis based on the probability density measurements in the micro chambers has shown that this trapping at the microscopic scale contributes to explain the macroscopic retention of the microswimmers in the foam. At the crossroads of distinct fields including marine ecology of planktonic organisms, fluid dynamics of active particles in a confined environment and the physics of foam, this work represents a significant step in the fundamental understanding of the ecological consequences of aquatic foams in water bodies.

Stability of big surface bubbles: impact of evaporation and bubble size.

Surface bubbles have attracted much interest in the past few decades. In this article, we aim to explore the lifetime and thinning dynamics of centimetric surface bubbles. We study the impact of the bubble size as well as that of the atmospheric humidity through a careful control and systematic variation of the relative humidity in the measuring chamber. We first address the question of the drainage under saturated water vapor conditions and show that a model including both capillary and gravity driven drainage provides the best prediction for this process. Additionally, unprecedented statistics on the bubble lifetimes confirm experimentally that this parameter is set by evaporation to leading order. We make use of a model based on the overall thinning dynamics of the thin film and assume a rupture thickness of the order 10-100 nm to obtain a good representation of these data. For experiments conducted far from saturation, the convective evaporation of the bath is shown to dominate the overall mass loss in the cap film due to evaporation.

Low gas permeability of particulate films slows down the aging of gas marbles.

Introducing solid particles into liquid films drastically changes their properties: "gas marbles" can resist overpressure and underpressure ten times larger than their pure liquid counterparts - also known as soap bubbles - before deforming. Such gas marbles can therefore prove to be useful as gas containers able to support stresses. Yet, as their liquid counterparts, they can undergo gas transfer, which can reduce the scope of their applications. However, their permeability has never been characterized. In this paper, we measure the gas permeability of gas marbles through dedicated experiments. Our results show that particulate films are less permeable to gas than their pure liquid counterparts. We attribute this limited overall gas flux to the particles that reduce the surface area through which gas diffuses.

Gas Marbles: Much Stronger than Liquid Marbles.

Enwrapping liquid droplets with hydrophobic particles allows the manufacture of so-called "liquid marbles" [Aussillous and Quéré Nature (London) 411, 924 (2001); NATUAS0028-083610.1038/35082026Mahadevan Nature (London)411, 895 (2001)NATUAS0028-083610.1038/35082164]. The recent intensive research devoted to liquid marbles is justified by their very unusual physical and chemical properties and by their potential for various applications, from microreactors to water storage, including water pollution sensors [Bormashenko Curr. Opin. Colloid Interface Sci. 16, 266 (2011)COCSFL1359-029410.1016/j.cocis.2010.12.002]. Here we demonstrate that this concept can be successfully applied for encapsulating and protecting small gas pockets within an air environment. Similarly to their liquid counterparts, those new soft-matter objects, that we call "gas marbles," can sustain external forces. We show that gas marbles are surprisingly tenfold stronger than liquid marbles and, more importantly, they can sustain both positive and negative pressure differences. This magnified strength is shown to originate from the strong cohesive nature of the shell. Those interesting properties could be exploited for imprisoning valuable or polluted gases or for designing new aerated materials.

Viscosity of particulate soap films: approaching the jamming of 2D capillary suspensions.

We compute the effective viscosity of particulate soap films thanks to local velocity fields obtained by Particle Image Velocimetry (PIV) during film retraction experiments. We identify the jamming of these 2D capillary suspensions at a critical particle surface fraction (≃0.84) where effective viscosity diverges. Pair correlation function and number of neighbors in contact or close to contact reveal the cohesive nature of this 2D capillary granular media. The experimental 2D dynamic viscosities can be predicted by a model considering viscous dissipation at the liquid interfaces induced by the motion of individual particles.

Yield-stress fluids foams: flow patterns and controlled production in T-junction and flow-focusing devices.

We study the formation of yield-stress fluid foams in millifluidic flow-focusing and T-junction devices. First, we provide a phase diagram for the unsteady operating regimes of bubble production when the gas pressure and the yield-stress fluid flow rate are imposed. Three regimes are identified: a co-flow of gas and yield-stress fluid, a transient production of bubble and a flow of yield-stress fluid only. Taking wall slip into account, we provide a model for the pressure at the onset of bubble formation. Then, we detail and compare two simple methods to ensure steady bubble production: regulation of the gas pressure or flow-rate. These techniques, which are easy to implement, thus open pathways for controlled production of dry yield-stress fluid foams as shown at the end of this article.

Drainage in a rising foam.

Rising foams created by continuously blowing gas into a surfactant solution are widely used in many technical processes, such as flotation. The prediction of the liquid fraction profile in such flowing foams is of particular importance since this parameter controls the stability and the rheology of the final product. Using drift flux analysis and recently developed semi-empirical expressions for foam permeability and osmotic pressure, we build a model predicting the liquid fraction profile as a function of height. The theoretical profiles are very different if the interfaces are considered as mobile or rigid, but all of our experimental profiles are described by the model with mobile interfaces. Even the systems with dodecanol are well known to behave as rigid in forced drainage experiments. This is because in rising foams the liquid fraction profile is fixed by the flux at the bottom of the foam. Here the foam is wet with higher permeability and the interfaces are not in equilibrium. These results demonstrate once again that it is not only the surfactant system that controls the mobility of the interface, but also the hydrodynamic problem under consideration. For example liquid flow through the foam during generation or in forced drainage is intrinsically different.

Bubble Formation in Yield Stress Fluids Using Flow-Focusing and T-Junction Devices.

We study the production of bubbles inside yield stress fluids (YSFs) in axisymmetric T-junction and flow-focusing devices. Taking advantage of yield stress over capillary stress, we exhibit a robust break-up mechanism reminiscent of the geometrical operating regime in 2D flow-focusing devices for Newtonian fluids. We report that when the gas is pressure driven, the dynamics is unsteady due to hydrodynamic feedback and YSF deposition on the walls of the channels. However, the present study also identifies pathways for potential steady-state production of bubbly YSFs at large scale.

Dynamics of yielding observed in a three-dimensional aqueous dry foam.

We study the onset of yielding in stable three-dimensional dry foams following the start up of steady shear flow. By means of a charge-coupled device camera equipped with a small depth-of-field objective, we visualize the Plateau border network in the bulk of the foam. The onset of yielding is identified with the deformation gamma(c) for which shear induced rearrangements start occurring. We show that gamma(c) is independent of shear rate gamma; in a quasistatic regime whereas at high strain rates, a rapid increase of gamma(c) with gamma; is observed, in qualitative agreement with theoretical models. Moreover, spatiotemporal image analyses are used to determine the velocity profile in the gap. We find that this profile remains linear up to strains far beyond gamma(c). Moreover, we have studied the strain history dependence of gamma(c).