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Environ Sci Pollut Res Int ; 23(15): 14868-80, 2016 Aug.
Article in English | MEDLINE | ID: mdl-27072032

ABSTRACT

Cyanotoxins, microcystins and cylindrospermopsin, are potent toxins produced by cyanobacteria in potable water supplies. This study investigated the removal of cyanotoxins from aqueous media by magnetophoretic nanoparticle of polypyrrole adsorbent. The adsorption process was pH dependent with maximum adsorption occurring at pH 7 for microcystin-LA, LR, and YR and at pH 9 for microcystin-RR and cylindrospermopsin (CYN). Kinetic studies and adsorption isotherms reflected better fit for pseudo-second-order rate and Langmuir isotherm model, respectively. Thermodynamic calculations showed that the cyanotoxin adsorption process is endothermic and spontaneous in nature. The regenerated adsorbent can be successfully reused without appreciable loss of its original capacity.


Subject(s)
Bacterial Toxins , Magnetite Nanoparticles/chemistry , Microcystins , Polymers/chemistry , Pyrroles/chemistry , Water Pollutants, Chemical , Water Purification/methods , Adsorption , Bacterial Toxins/analysis , Bacterial Toxins/chemistry , Bacterial Toxins/isolation & purification , Cyanobacteria , Microcystins/analysis , Microcystins/chemistry , Microcystins/isolation & purification , Water Pollutants, Chemical/analysis , Water Pollutants, Chemical/chemistry , Water Pollutants, Chemical/isolation & purification
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