Reduced Graphene Oxide/Au Nanocomposite for NO2 Sensing at Low Operating Temperature.

A reduced grapheme oxide (rGO)/Au hybrid nanocomposite has been synthesized by hydrothermal treatment using graphite and HAuCl4 as the precursors. Characterization, including X-ray diffraction (XRD), Raman spectra, X-ray photoelecton spectroscopy (XPS) and transmission electron microscopy (TEM), indicates the formation of rGO/Au. A gas sensor fabricated with rGO/Au nanocomposite was applied for NO2 detection at 50 °C. Compared with pure rGO, rGO/Au nanocomposite exhibits higher sensitivity, a more rapid response-recovery process and excellent reproducibility.

Co-Rich ZnCoO Nanoparticles Embedded in Wurtzite Zn1-xCoxO Thin Films: Possible Origin of Superconductivity.

Co-rich ZnCoO nanoparticles embedded in wurtzite Zn0.7Co0.3O thin films are grown by pulsed laser deposition on a Si substrate. Local superconductivity with an onset Tc at 5.9 K is demonstrated in the hybrid system. The unexpected superconductivity probably results from Co3+ in the Co-rich ZnCoO nanoparticles or from the interface between the Co-rich nanoparticles and the Zn0.7Co0.3O matrix.

Electronic Band Structures and Native Point Defects of Ultrafine ZnO Nanocrystals.

Ultrafine ZnO nanocrystals with a thickness down to 0.25 nm are grown by a metalorganic chemical vapor deposition method. Electronic band structures and native point defects of ZnO nanocrystals are studied by a combination of scanning tunneling microscopy/spectroscopy and first-principles density functional theory calculations. Below a critical thickness of ∼1 nm ZnO adopts a graphitic-like structure and exhibits a wide band gap similar to its wurtzite counterpart. The hexagonal wurtzite structure, with a well-developed band gap evident from scanning tunneling spectroscopy, is established for a thickness starting from ∼1.4 nm. With further increase of the thickness to 2 nm, VO-VZn defect pairs are easily produced in ZnO nanocrystals due to the self-compensation effect in highly doped semiconductors.

Observations of three types of pulses in an erbium-doped fiber laser by incorporating a graphene saturable absorber.

We experimentally observed three types of pulses generated in an erbium-doped fiber laser by incorporating a homemade graphene saturable absorber (GSA). The generated pulses from the laser oscillator include dual-wavelength dark pulses, fundamentally step-like pulses, and non-soliton second-harmonic pulses. These operation regimes are first reported by using graphene as the saturable absorber. Our results will further indicate that the GSA can function well for obtaining various ultrafast pulse phenomena, highlighting the practical potential of graphene in ultrafast photonics technologies.

Theoretical and experimental analysis of splicing between the photonic crystal fiber and the conventional fiber using grin fibers.

Photonic crystal fibers (PCFs) are widely used in all-fiber, high-power lasers and supercontinuum sources. However, the splice loss between PCFs and conventional fibers limits its development. Grin fibers and coreless fibers were used as a fiber lens to achieve low-loss, high-strength splicing between PCFs and single-mode fibers (SMFs). The beam propagation method was used to optimize the lengths of grin fibers and coreless fibers for a minimum splice loss. The splice loss changing with the lengths of grin fiber, coreless fiber, and the air-hole collapsed region was systematically studied theoretically and experimentally. Ultimately, a minimum splice loss of 0.26 dB at 1064 nm was realized between a high-nonlinear PCF and a conventional SMF with this method.

High-stability erbium-doped photonic crystal fiber source.

A single-pass backward configuration superfluorescent fiber source (SFS) based on erbium-doped photonic crystal fiber (EDPCF) with a high mean wavelength stability was proposed. The EDPCF was used to improve the intrinsic temperature dependence of the SFS. Using the optimal EDPCF length of 24.2 m and pump power of 204 mW, a 20.7 ppm mean wavelength stability of a prototype SFS was demonstrated with increased temperature from -40 °C to 60 °C. The mean wavelength had an ultra stability of 10.3 ppm with increased temperature from -20 °C to 60 °C.

Geometry, phase stability, and electronic properties of isolated selenium chains incorporated in a nanoporous matrix.

We report the fabrication process of isolated one-dimensional Se chains incorporated in the matrix of AlPO4-5 single crystals and the experimental investigation of the geometry, phase stability, electronic properties, and electron-phonon coupling effect of these Se chains. The structure of the helical Se chains inside the channels is discussed on the basis of X-ray scattering measurements. Thermal analysis and temperature-dependent micro-Raman measurements show that Se single chains are flexible and can convert from a weak distorted phase into another phase with strongly disordered structure ("melting" state) around 340 K. Since the electrons are confined in the one-dimensional channels, the absorption band of the Se chain is obviously blue shifted compared with that of trigonal Se. With increasing temperature, this band shifts linearly to the lower energy side, in sharp contrast to the nonlinear temperature coefficient of trigonal Se, which is attributed to the greatly diminished interchain interaction and the weakening of the electron-optical phonon coupling in a low-dimensional system. In the vicinity of the absorption band, both first-order and second-order Raman signals for the Se chain are enhanced, due to the strong electron-phonon coupling when the excitation laser energy matches the electronic transition in isolated Se chains.