Jahn-teller dynamics in charge-ordered manganites from raman spectroscopy

The Raman spectra of the charge-ordered manganite Pr0.65Ca0.35MnO3 were studied as functions of temperature and excitation energy and compared to magnetic moment and electrical conductivity behaviors. Both the charge ordering ( T(co) approximately 225 K) and the antiferromagnetic transitions ( T(N) approximately 175 K) affect the spectral shape and intensity, indicating strong charge-lattice and spin-lattice couplings. Below T(co) a transition from dynamic Jahn-Teller distortions to a collective static distortion takes place. A change of the spectra is observed on increasing the excitation energy above 2.5 eV and it is attributed to a resonant polaron excitation.

Nonlinear-optical response in polythiophene films using four-wave mixing techniques.

We report measurement of X(3) in polythiophene and a homologous series of polycondensed thiophene-based polymers above and below the absorption edge using the folded-boxcar four-wave mixing technique. Above gap the nonlinear coefficient X(3) was found to be one of the largest and fastest in a polymer.