1.
Acta Crystallogr Sect E Struct Rep Online
; 69(Pt 3): m137-8, 2013 Mar 01.
Article
in English
| MEDLINE
| ID: mdl-23476487
ABSTRACT
The title compound, [Ag(C9H13N5S)Cl(C18H15P)2], crystallizes with four independent mol-ecules in the asymmetric unit, in each of which the Ag atom is in a distorted tetra-hedral coordination, defined by the chloride ligand, the S atom of the neutral ligand and two P atoms derived from the triphenyl phosphine ligands. The thio-semicarbazone acts as a monodentate ligand through its thione S atom. An intra-molecular N-Hâ¯Cl hydrogen bond occurs in two of the independent mol-ecules. In the crystal, the mol-ecules are assembled through N-Hâ¯Cl hydrogen bonds, forming chains along [101].