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1.
Phys Chem Chem Phys ; 24(16): 9576-9588, 2022 Apr 20.
Article in English | MEDLINE | ID: mdl-35403183

ABSTRACT

In the framework of first-principles calculations, we comprehensively investigate the external electric-field (EF) manipulation of the magnetic anisotropy energy (MAE) of alloyed CoPt dimers deposited on graphene. In particular, we focus on the possibility of tuning the MAE barriers under the action of external EFs and on the effects of Co-substitution. Among the various considered structures, the lowest-energy configurations were the hollow-upright and top-upright, having the Co-atom closest to the graphene layer. The optimal and higher energy configurations were related to the electronic structure through the local density of states and hybridizations between the transition-metal (TM) atoms of the dimer and graphene. In contrast to Co2/graphene [M. Tanveer, J. Dorantes-Dávila and G. M. Pastor, Phys. Rev. B, 2017, 96(22), 224413.], the CoPt dimer having the hollow-upright ground-state configuration, exhibits a much lower value of the MAE (about |ΔE| ≃ 4.5 meV per atom) and the direction of the magnetization lies in the graphene layer. Moreover, we observe a spin-reorientation transition occurring at εz ≃ 0.5 V Å-1, which opens the possibility of inducing magnetization switching by external electric fields. The microscopic origin of the changes of the MAE associated with changes in the EF has been qualitatively related to the details of the electronic structure by analyzing the local density of states and to the spin-dependent electronic densities close to the Fermi energy. Finally, the role of local environment was quantified by performing electronic structure and magnetic calculations on several higher-energy structure configurations.

2.
Epidemiol Infect ; 147: e255, 2019 08 23.
Article in English | MEDLINE | ID: mdl-31439067

ABSTRACT

Tick-borne diseases (TBDs) can sometimes cause severe symptoms and lead to hospitalisation, but they often go unnoticed in the Emergency Department (ED). The aim of this study was twofold: (i) to describe the profile of patients hospitalised by TBDs; and (ii) to evaluate the data collected in the medical records from the ED in order to analyse their potential clinical consequences. A total of 84 cases that included all TBD diagnoses registered in the ED records were identified and analysed. These corresponded to all the hospitalisations by TBDs in the last 10 years (2009-2019) in two tertiary hospitals in Granada, Spain. Statistical analyses were made using RStudio. Coinciding with the absence of patient's report of exposure to ticks, 64.3% of TBDs were not suspected in the ED. Intensive care unit admission was required in 8.3% of cases, and the mortality rate was 2.4%. Non-suspected cases showed longer hospital stay (P < 0.001), treatment duration (P = 0.02) and delay in the initiation of antibiotic treatment (P < 0.001). Our findings indicate that symptoms associated with TBDs are highly non-specific. In the absence of explicit information related to potential tick exposure, TBDs are not initially suspected. As a consequence, elective treatment administration is delayed and hospitalisation time is prolonged. In conclusion, our results highlight the importance of addressing potential exposure to ticks during the ED contact with patients presenting with febrile syndrome.


Subject(s)
Hospitalization/statistics & numerical data , Tick-Borne Diseases/epidemiology , Tick-Borne Diseases/pathology , Adult , Aged , Aged, 80 and over , Critical Care/statistics & numerical data , Female , Humans , Male , Middle Aged , Spain/epidemiology , Survival Analysis , Tertiary Care Centers , Tick-Borne Diseases/mortality
3.
Phys Rev Lett ; 110(26): 267203, 2013 Jun 28.
Article in English | MEDLINE | ID: mdl-23848916

ABSTRACT

Our ab initio studies show clear evidence that magnetic anisotropy (MA) and the direction of magnetization in metallic magnetic multilayers can be tailored at once by surface charging. By taking Fe-Pt multilayers as a representative example, we demonstrate that surface charging has a deep effect on the magnitude of the MA, which is composition dependent, achieving remarkably large values for systems featuring a single Fe layer capped with Pt. More intriguing is the behavior of the multilayers capped with iron bilayers, for which surface charging not only affects the value of the anisotropy but an easy-axis switching is also revealed. By analyzing the electronic structure of the magnetic layers and relating the MA to the orbital moment anisotropy, some insights about the origin of the MA from a local perspective can be inferred.

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