Phase separation enabled silver nano-array.

The surface-supported silver nanoparticles have been studied and applied in various applications. Many unique nanostructures have been introduced into this field to improve the functionalities of the surfaces depending on application purposes. We created featured silver nano-array surfaces by utilizing the solvent-mediated phase transition on the surface grafted with poly (acrylic) acids polymer chains and taking advantage of the low temperature of argon gas discharged plasma as a reducing agent. The applied solvents and grafted polymer chain densities affected the phase transition and thus determined the outcome of surface nano-array patterns. However, the total loaded silver ions on the surface affected silver nano-array structures at the sub-micron levels. The featured silver patterned surfaces made in the optimal conditions present a favorable surface-enhanced Raman spectroscopy enhancement as well as recyclability for detection re-usage. This novel method prepares tunable silver nanopatterned surfaces and provides a new approach to various potential applications.

Tunable Properties of Polydopamine Nanoparticles and Coated Surfaces.

Polydopamine (PDA) nanoparticles and PDA-coated surfaces have wide applications due to PDA's unique reactivity and efficient coating ability on nearly any surface. However, challenges in manipulating and controlling dopamine polymerization and thus the PDA nanoparticle formations and surface coatings still exist. Here, dopamine with a tetraborate (borax)-protected catechol group was utilized to tune the properties of PDA nanoparticles and PDA coatings. This method allows us to (1) synthesize PDA nanoparticles with a narrow size distribution and low aggregation and (2) create surface coating with the desired PDA layer thickness and varying water contact angles. PDA nanoparticles and PDA-coated surfaces of varying but tunable chemical and physical properties will find wide applications. For example, such PDA-coated surfaces were successfully used to construct Ag nanoparticle patterned surfaces with varying Ag particle sizes and densities.

Stereochemical Strategy Advances Microbially Antiadhesive Cotton Textile in Safeguarding Skin Flora.

Microbial contamination on cotton textiles (CT) negatively affects people's health as well as the textile itself during use and storage. Using antimicrobial CT in a body-safe manner is currently still a challenge because it is difficult to balance killing microbes and protecting skin flora. Herein, a borneol-decorated CT (BDCT) through coupling of borneol 4-formylbenzoate molecules onto the amino-modified CT is reported. This BDCT shows strong and broad-spectrum microbially antiadhesive activities against gram-positive bacteria (Staphylococcus aureus and S. epidermidis), gram-negative bacteria (Escherichia coli and Pseudomonas aeruginosa), and fungi (Aspergillus niger, Mucor racemosus, and Candida albicans). Because of its unique stereochemical microbial antiadhesion mechanism, BDCT is harmless to skin flora. In addition, BDCT exhibits prominent durability of microbially antiadhesive capability by bearing 50 times of accelerated laundering. Therefore, this stereochemical BDCT strategy shows great potential for applications in the new generation of textiles, food packaging, and medical protection.