The Macquarie Deformation-DIA facility at the Australian Synchrotron: A tool for high-pressure, high-temperature experiments with synchrotron radiation.

The Macquarie University Deformation-DIA (MQ D-DIA) multi-anvil apparatus at the Australian Synchrotron provides a new experimental facility that enables simultaneous high-pressure and high-temperature in situ synchrotron experimentation in Australia. The MQ D-DIA can be easily deployed at any of a number of beamlines at the Australian Synchrotron, and we describe its installation at the x-ray absorption spectroscopy beamline, which enables in situ x-ray absorption near-edge spectroscopy and energy-scanning x-ray diffraction. A simple, reliable, and x-ray transparent high-pressure cell assembly has been developed for the D-DIA for which load/pressure and heater power/temperature relationships have been calibrated using in situ x-ray diffraction and "offline" mineral equilibration experiments. Additionally, we have mapped temperature distribution within the assembly using a new quantitative electron microprobe mapping technique developed for fine-grained polyphase samples. We are now investigating the speciation of geologically important trace elements in silicate melts (e.g., Zr, U, and Th) measured in situ under high pressure and temperature conditions corresponding to the Earth's mantle. Pressure-dependent changes in speciation influence partitioning behavior, and therefore the distribution in the Earth, of many trace elements. However, previous ex situ investigations are hampered by uncertainty as to whether high-pressure speciation can be faithfully recorded in samples recovered to ambient conditions. We present preliminary results showing an increase in the coordination number of Zr dissolved as a trace component of a sodium-rich silicate melt with pressure. These results also indicate that silicate melt composition exerts a strong influence on Zr speciation.

The inception of plate tectonics: a record of failure.

The development of plate tectonics from a pre-plate tectonics regime requires both the initiation of subduction and the development of nascent subduction zones into long-lived contiguous features. Subduction itself has been shown to be sensitive to system parameters such as thermal state and the specific rheology. While generally it has been shown that cold-interior high-Rayleigh-number convection (such as on the Earth today) favours plates and subduction, due to the ability of the interior stresses to couple with the lid, a given system may or may not have plate tectonics depending on its initial conditions. This has led to the idea that there is a strong history dependence to tectonic evolution-and the details of tectonic transitions, including whether they even occur, may depend on the early history of a planet. However, intrinsic convective stresses are not the only dynamic drivers of early planetary evolution. Early planetary geological evolution is dominated by volcanic processes and impacting. These have rarely been considered in thermal evolution models. Recent models exploring the details of plate tectonic initiation have explored the effect of strong thermal plumes or large impacts on surface tectonism, and found that these 'primary drivers' can initiate subduction, and, in some cases, over-ride the initial state of the planet. The corollary of this, of course, is that, in the absence of such ongoing drivers, existing or incipient subduction systems under early Earth conditions might fail. The only detailed planetary record we have of this development comes from Earth, and is restricted by the limited geological record of its earliest history. Many recent estimates have suggested an origin of plate tectonics at approximately 3.0 Ga, inferring a monotonically increasing transition from pre-plates, through subduction initiation, to continuous subduction and a modern plate tectonic regime around that time. However, both numerical modelling and the geological record itself suggest a strong nonlinearity in the dynamics of the transition, and it has been noted that the early history of Archaean greenstone belts and trondhjemite-tonalite-granodiorite record many instances of failed subduction. Here, we explore the history of subduction failure on the early Earth, and couple these with insights from numerical models of the geodynamic regime at the time.This article is part of a discussion meeting issue 'Earth dynamics and the development of plate tectonics'.

Sulfur and metal fertilization of the lower continental crust.

Mantle-derived melts and metasomatic fluids are considered to be important in the transport and distribution of trace elements in the subcontinental lithospheric mantle. However, the mechanisms that facilitate sulfur and metal transfer from the upper mantle into the lower continental crust are poorly constrained. This study addresses this knowledge gap by examining a series of sulfide- and hydrous mineral-rich alkaline mafic-ultramafic pipes that intruded the lower continental crust of the Ivrea-Verbano Zone in the Italian Western Alps. The pipes are relatively small (< 300 m diameter) and primarily composed of a matrix of subhedral to anhedral amphibole (pargasite), phlogopite and orthopyroxene that enclose sub-centimeter-sized grains of olivine. The 1 to 5 m wide rim portions of the pipes locally contain significant blebby and disseminated Fe-Ni-Cu-PGE sulfide mineralization. Stratigraphic relationships, mineral chemistry, geochemical modelling and phase equilibria suggest that the pipes represent open-ended conduits within a large magmatic plumbing system. The earliest formed pipe rocks were olivine-rich cumulates that reacted with hydrous melts to produce orthopyroxene, amphibole and phlogopite. Sulfides precipitated as immiscible liquid droplets that were retained within a matrix of silicate crystals and scavenged metals from the percolating hydrous melt, associated with partial melting of a metasomatized continental lithospheric mantle. New high-precision chemical abrasion TIMS U-Pb dating of zircons from one of the pipes indicates that these pipes were emplaced at 249.1 ± 0.2 Ma, following partial melting of lithospheric mantle pods that were metasomatized during the Eo-Variscan oceanic to continental subduction (~420-310 Ma). The thermal energy required to generate partial melting of the metasomatized mantle was most likely derived from crustal extension, lithospheric decompression and subsequent asthenospheric rise during the orogenic collapse of the Variscan belt (< 300 Ma). Unlike previous models, outcomes from this study suggest a significant temporal gap between the occurrence of mantle metasomatism, subsequent partial melting and emplacement of the pipes. We argue that this multi-stage process is a very effective mechanism to fertilize the commonly dry and refractory lower continental crust in metals and volatiles. During the four-dimensional evolution of the thermo-tectonic architecture of any given terrain, metals and volatiles stored in the lower continental crust may become available as sources for subsequent ore-forming processes, thus enhancing the prospectivity of continental block margins for a wide range of mineral systems.