ABSTRACT
Composite materials are materials with anisotropic properties that are created by combining several different components in a way that allows the best qualities of each component to be used. In this paper, raw materials were used to obtain composite materials of the type TPU/PP/BaTiO3 powder. The thermogravimetric analysis, dynamic differential calorimetry, and scanning electron microscopy were carried out. The preliminary tests for making specific filaments for 3D printing with a diameter of 1.75 mm were carried out on a laboratory extruder. The purpose of the experiment was to develop the optimal extrusion temperatures and the speed of drawing the filament to make filaments with rigorously constant dimensions, and the variation in diameter had a maximum of 10%.
ABSTRACT
The adsorption potential of alkaline treated straw (wheat and corn) in mixture with soil, has been investigated for the removal of sulfonylurea molecules from an aqueous solutions. The surface characteristics were investigated by scanning electron microscopy and Fourier Transform Infrared - FTIR, while the adsorbent capacity was evaluated using batch sorption tests and liquid chromatography coupled with mass spectrometry. Surface analysis of alkaline treated straw samples by scanning electron microscopy - SEM showed the increasing of the surface roughness improving their functional surface activity. An increase (337.22 mg g-1) of adsorption capacity of sulfonylurea molecules was obtained for all studied straw. The Langmuir isotherm model was the best model for the mathematical description of the adsorption process indicating the forming of a surface sorption monolayer with a finite number of identical sites. The kinetics of sulfonylurea herbicide followed the pseudo-second order mechanism corresponding to strong chemical interactions. The results sustained that the alkaline treated straw have biosorption characteristics, being suitable adsorbent materials.
