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Self-association-free dimeric cinchona alkaloid organocatalysts: unprecedented catalytic activity, enantioselectivity and catalyst recyclability in dynamic kinetic resolution of racemic azlactones.
Lee, Ji Woong; Ryu, Tae Hi; Oh, Joong Suk; Bae, Han Yong; Jang, Hyeong Bin; Song, Choong Eui.
Chem Commun (Camb) ; (46): 7224-6, 2009 Dec 14.
Article in English | MEDLINE | ID: mdl-19921037

ABSTRACT

Self-association-free, bifunctional, squaramide-based dimeric cinchona alkaloid organocatalysts show unprecedented catalytic activity, enantioselectivity and catalyst recyclability in the dynamic kinetic resolution (DKR) reaction of a broad range of racemic azlactones.


Subject(s)
Catalysis , Cinchona Alkaloids/chemistry , Lactones/chemistry , Conservation of Natural Resources , Dimerization , Kinetics , Lactones/isolation & purification , Stereoisomerism
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