ABSTRACT
Given the safety issues associated with flammability characteristics of alternative environmentally-friendly refrigerants, it is vital to establish measurement systems to accurately analyse the flammability of these mildly flammable refrigerants. In this study, we used a customised Hartmann bomb analogue to measure the minimum ignition energy (MIE) and laminar burning velocity (BV) for refrigerant/air mixtures of pure ammonia (R717), R32, R1234yf and mixtures of R32 and R1234yf with non-flammable refrigerants of R134a, R125 and carbon dioxide (R744). The MIEs of R717, R32, and R1234yf were measured at an ambient temperature of 24 °C to be (18.0 ± 1.4), (8.0 ± 1.5) and (510 ± 130) mJ at equivalence ratios of 0.9, 1.27 and 1.33, respectively. Adding the non-flammable refrigerants R134a, R125 and R744 along with R32 at volumetric concentrations of 5% each to R1234yf reduced the latter compound's flammability and increased its MIE by one order of magnitude. The laminar burning velocities of pure R717 and R32 were measured at an equivalence ratio of 1.1 using the flat flame method and found to be 8.4 and 7.4 cm/s, respectively. Adding 5% R1234yf to R32 decreased the laminar burning velocity by 11%, while a further 5% addition of R1234yf resulted in a decrease of over 30% in the laminar burning velocity.
ABSTRACT
An exergy analysis of a novel integrated power system is represented in this study. A Solid Oxide Fuel Cell (SOFC), which has been assisted with a Gas Turbine (GT) and Organic Rankine Cycle (ORC) by employing liquefied natural gas (LNG) as a heat sink in a combined power system is simulated and investigated. Initially in this paper, the integrated power system and the primary concepts of the simulation are described. Subsequently, results of the simulation, exergy analysis, and composite curves of heat exchangers are represented and discussed. The equations of the exergy efficiency and destruction for the main cycle's units such as compressors, expanders, pumps, evaporators, condensers, reformers, and reactors are presented. According to the results, the highest exergy destruction is contributed to the SOFC reactor, despite its acceptable exergy efficiency which is equal to 75.7%. Moreover, the exergy efficiencies of the ORC cycle and the whole plant are determined to be 64.9% and 39.9%, respectively. It is worth noting that the rational efficiency of the integrated power system is 53.5%. Among all units, the exergy efficiency of the LNG pump is determined to be 11.7% the lowest exergy efficiency among the other investigated components, indicating a great potential for improvements.
