Mesoporous CuS nanospheres decorated rGO aerogel for high photocatalytic activity towards Cr(VI) and organic pollutants.

Mesoporous CuS nanospheres (CuS-NS) decorated reduced graphene oxide (rGO) aerogel composite (3D CuS-NS/rGO) was prepared by chemical reduction process and used for the synergistic removal of Cr(VI) and cationic dyes. The porosity of the as prepared samples was determined by Bruner-Emmet-Teller (BET) surface Area. Structural and morphological properties were studied by Scanning electron microscopy (SEM) and Transmission electron microscope (TEM). These analysis revealed that the as obtained hybrid CuS-NS/rGO composite with three dimensional (3D) structure was composed of mesoporous CuS nanospheres clearly induced onto the interconnected network of rGO sheets. The photocatalytic performance of 3D CuS-NS/rGO composites was studied against the reduction of Cr(VI) and degradation of cationic dyes (MB and RhB) under visible light spectrum. Excellent photocatalytic performance was observed with 3D CuS/rGO hybrid composites as compared to the as prepared CuS nanospheres. This high photocatalytic activity was attributed to the efficient charge transfer from the mesoporous CuS nanospheres to nanosheets of rGO, which was confirmed by UV-Vis spectrometry (UV-Vis). Electrical conductivity of the prepared samples was also investigated using electrochemical impedance spectroscopy (EIS). Additionally, the as prepared hybrid composites was easy to recycle by using simple tweezers and can be a best candidate for industrial applications.

High incidence of hepatitis B infection after treatment for paediatric cancer at a teaching hospital in Baghdad.

This study estimated the incidence of viral hepatitis in children treated for cancer, to identify variables that could affect this incidence and to assess the role of hepatitis B virus (HBV) vaccination in preventing infection. Between September 2007 and June 2008, 256 children in the haemato-oncology unit at the Children's Welfare Teaching Hospital, Baghdad, were studied prospectively. Demographic and clinical data and vaccination history were recorded. Patients were tested for HBV at the time of diagnosis (all were negative) and after starting chemotherapy. On admission to the unit, 231 patients (90.2%) were revaccinated. At reassessment after treatment for cancer, HBV infection was found in 70 patients (27.3%). The variables that significantly increased the risk for HBV infection were a diagnosis of leukaemia and receiving more than 3 units of blood. A higher number of HBV vaccinations in hospital reduced the risk for HBV infection. The high rate of acquisition of HBV infection found in this study indicates the need for better screening of blood products and adherence to aseptic techniques in management of this group of patients.

High incidence of hepatitis B infection after treatment for paediatric cancer at a teaching hospital in Baghdad

This study estimated the incidence of viral hepatitis in children treated for cancer, to identify variables that could affect this Incidence and to assess the role of hepatitis B virus [HBV] vaccination In preventing infection. Between September 2007 and June 2008, 256 children in the haemato-oncology unit at the Children's Welfare Teaching Hospital, Baghdad, were studied prospectively. Demographic and clinical data and vaccination history were recorded. Patients were tested for HBV at the time of diagnosis [all were negative] and after starting chemotherapy. On admission to the unit, 231 patients [90.2%] were revaccinated. At reassessment after treatment for cancer, HBV infection was found in 70 patients [27.3%]. The variables that significantly increased the risk for HBV infection were a diagnosis of leukaemia and receiving more than 3 units of blood. A higher number of HBV vaccinations in hospital reduced the risk for HBV infection. The high rate of acquisition of HBV infection found in this study indicates the need for better screening of blood products and adherence to aseptic techniques In management of this group of patients

On the ferromagnetic structure of the intermetallic borocarbide TbCo(2)B(2)C.

Based on magnetization, specific heat, magnetostriction and neutron-diffraction studies on single-crystal TbCo(2)B(2)C, it is found out that the paramagnetic properties, down to liquid nitrogen temperatures, are well described by a Curie-Weiss behavior of the Tb(3+) moments. Furthermore, below T(c) = 6.3 K, the Tb sublattice undergoes a ferromagnetic (FM) phase transition with the easy axis being along the (100) direction and, concomitantly, the unit cell undergoes a tetragonal-to-orthorhombic distortion. The manifestation of an FM state in TbCo(2)B(2)C is unique among all other isomorphous borocarbides, in particular TbNi(2)B(2)C (T(N) = 15 K, incommensurate modulated magnetic state) even though the Tb ions in both isomorphs have almost the same crystalline electric field properties. The difference among the magnetic modes of these Tb-based isomorphs is attributed to a difference in their exchange couplings which are in turn caused by a variation in their lattice parameters and in the position of their Fermi levels.