Bioenergy-producing two-stage septic tank and floating wetland for onsite wastewater treatment: Circuit connection and external aeration.

This study designed a two-stage, electrode-integrated septic tank-floating wetland system and assessed their pollutant removal performances under variable operational conditions. The two-stage system achieved mean organic, nitrogen, phosphorus, and coliform removal percentages of 99, 78, 99, and 97%, respectively, throughout the experimental run. The mean metals (chromium, cadmium, nickel, copper, zinc, lead, iron, and manganese) removal percentages ranged between 81 and 98%. Accumulated sludge, filler media, and the hanging root mass contributed to pollutant removals by supporting physicochemical and biological pathways. The mean effluent organic concentration and coliform number across the two-stage system were 20 mg/L and 1682 CFU/100 mL, respectively, during the closed-circuit protocol, which was beneath the open-circuit-based performance profiles, i.e., 32 mg/L and 2860 CFU/100 mL, respectively. Effluent organic, nitrogen, phosphorus, metals, and coliform number ranges across the two-stage system were 9-17 mg/L, 13-24 mg/L, 1-1.5 mg/L, 0.001-0.2 mg/L, and 1410-2270 CFU/100 mL, respectively during intermittent and continuous aeration periods. The air supply rate differences influenced pollutant removal depending on the associated removal mechanisms. The non-aeration phase produced higher effluent pollutant concentrations than the aeration periods-based profiles. The overall mean power density production of the septic tank ranged between 107 and 596 mW/m3; 110 and 355 mW/m3 with the floating wetland. The bioenergy production capacity of the septic tank was positively correlated to external air supply rates. This study demonstrates the potential application of the novel bioenergy-producing septic tank-floating wetland system for wastewater treatment in decentralized areas.

Influence of aeration, plants, electrodes, and pollutant loads on treatment performance of constructed wetlands: A comprehensive study with septage.

This study reports the performance of non-aerated and aerated unplanted, planted, microbial fuel cell planted wetlands for stabilizing septage and treating the drained wastewater. The wetland systems of this study were dosed with septage for a relatively shorter period, i.e., 20 weeks, followed by 60 days of sludge drying period. The sludge loading rates across the constructed wetlands ranged between 259 and 624 kg total solids (TS)/m2 per year. Organic matter, nitrogen, and phosphorus concentration of the residual sludge ranged between 8512 and 66,374 mg/kg, 12,950 and 14,050 mg/kg, 4979 and 9129 mg/kg, respectively. The presence of plants, electrode, and aeration improved sludge dewatering and decreased the organic matter and nutrient concentration of the residual sludge. The heavy metals (Cd, Cr, Cu, Fe, Pb, Mn, Ni, and Zn) concentration of the residual sludge fulfilled the guidelines for agricultural reuse in Bangladesh. Chemical oxygen demand (COD), ammoniacal nitrogen (NH4-N), total nitrogen (TN), total phosphorus (TP), and coliform removal percentages from the drained wastewater ranged between 91 and 93 %, 88 and 98 %, 90 and 99 %, 92 and 100 %, and 75 and 90 %, respectively. NH4-N removal from the drained wastewater depended upon aeration. The sludge treatment wetlands achieved metals removal percentages (from the drained wastewater) ranging between 90 and 99 %. Physicochemical and microbial routes in accumulated sludge, rhizosphere, and media contributed to pollutants removal. Input load and organic removal increment (from the drained wastewater) were positively correlated; nutrient removal showed a contradictory trend. The non-aerated and aerated microbial fuel cell planted wetlands produced maximum power densities ranging between 66 and 3417 mW/m3. Because of the shorter experimental duration, this study revealed preliminary but new information on the macro and micro pollutants removal pathways in septage sludge wetlands (with and without electrode) that could be utilized to design pilot or full-scale systems.

The race between classical microbial fuel cells, sediment-microbial fuel cells, plant-microbial fuel cells, and constructed wetlands-microbial fuel cells: Applications and technology readiness level.

Microbial fuel cell (MFC) is an interesting technology capable of converting the chemical energy stored in organics to electricity. It has raised high hopes among researchers and end users as the world continues to face climate change, water, energy, and land crisis. This review aims to discuss the journey of continuously progressing MFC technology from the lab to the field so far. It evaluates the historical development of MFC, and the emergence of different variants of MFC or MFC-associated other technologies such as sediment-microbial fuel cell (S-MFC), plant-microbial fuel cell (P-MFC), and integrated constructed wetlands-microbial fuel cell (CW-MFC). This review has assessed primary applications and challenges to overcome existing limitations for commercialization of these technologies. In addition, it further illustrates the design and potential applications of S-MFC, P-MFC, and CW-MFC. Lastly, the maturity and readiness of MFC, S-MFC, P-MFC, and CW-MFC for real-world implementation were assessed by multicriteria-based assessment. Wastewater treatment efficiency, bioelectricity generation efficiency, energy demand, cost investment, and scale-up potential were mainly considered as key criteria. Other sustainability criteria, such as life cycle and environmental impact assessments were also evaluated.

Organic media-based two-stage traditional and electrode-integrated tidal flow wetlands to treat landfill leachate: Influence of aeration strategy and plants.

Landfill leachate treatment employing normal and electrode-integrated constructed wetlands is difficult due to the presence of significant amounts of organic compounds, which frequently impede the progression of microbial-based aerobic pollutant removal pathways. As a result, this study examines the effect of supplementary air availability via intermittent and continuous aeration strategies in improving organic, nutrient, and coliform removals of the unplanted, planted (normal and electrode-integrated) two-stage tidal flow constructed wetlands designed to treat landfill leachate. The constructed wetlands were filled with coal and biochar media and planted with Canna indica. Mean chemical oxygen demand (COD), total nitrogen (TN), total phosphorus (TP), and coliform removal percentages of the externally aerated two-stage unplanted, only planted, planted-microbial fuel cell integrated constructed wetland systems ranged between 96 and 99%, 82 and 93%, 91 and 98%, 86 and 96%, respectively, throughout the experimental campaign. External aeration inhibited the development of a dominant anaerobic environment within the media of the wetland systems and improved overall pollutant removal. The electrode-integrated planted tidal flow wetlands produced better effluent quality than the unplanted or only planted tidal flow systems without electrode assistance. The first stages of the three wetland systems achieved an additional 5-7% COD, 7-12% TN, and 15-22% coliform removal during the continuous aeration period compared to the corresponding performance of the intermittent aeration phase. The pollutant removal performance of the second-stage wetlands decreased during the continuous aeration phase. The media composition supported electrochemically active and inactive microbial-based pollutant removal routes and the chemical adsorption of pollutants. Nitrogen and phosphorus accumulation percentage in plant tissues was low, i.e., 0.4-2.2% and 0.04-0.8%, respectively. During the continuous aeration period, the electrode-integrated tidal flow constructed wetlands achieved higher power density production, i.e., between 859 and 1432 mW (mW)/meter3(m3). This study demonstrates that external aeration might improve pollutant removal performance of the normal, electrodes integrated tidal flow-based constructed wetlands when employed for high organic-strength wastewater treatment such as landfill leachate.

Performance assessment of normal and electrode-assisted floating wetlands: influence of input pollutant loads, surface area, and positioning of anode electrodes.

This study reports the design and development of microbial fuel cell (MFC) assisted floating wetlands and compares treatment removal performance with a normal (without electrodes) floating wetland. Both types of floating wetlands were planted with Phragmites plant and evaluated for real municipal wastewater treatment. The effective volume of each floating wetland was 0.5 m3. The floating wetlands were operated under variable hydraulic load rates, i.e., 20 and 60 mm/day. Mean 5-day biochemical oxygen demand (BOD5), chemical oxygen demand (COD), ammoniacal nitrogen (NH4-N), total nitrogen (TN), total phosphorus (TP), total suspended solids (TSS), and coliform removal percentages ranged between 71 and 96%, 72 and 94%, 62 and 86%, 58 and 75%, 82 and 97%, 64 and 92%, and 72 and 93%, respectively within the normal and electrode-assisted MFC integrated floating wetlands. The electrode-integrated floating wetlands showed better pollutant removal performance than the normal system under unstable input pollutant loading conditions. Nitrogen and organic matter removals were achieved through both electrochemically active and inactive microbial removal routes. Physical separation processes, such as filtration and sedimentation, contributed to phosphorus, solids, and coliform removal. Plant uptake contributed to micro-scale nitrogen (≤ 1%) and phosphorus (≤ 0.1%) removal. Increment of hydraulic/pollutant load improved organic removal but decreased nutrient removal performance of the normal, electrode-integrated floating wetlands. The electrode-integrated floating wetlands produced power densities ranging between 0.7 and 1.4 mW/m3, and 0.2 and 2.3 mW/m3 during lower, upper input loading ranges, respectively. Bioenergy production of the electrode-integrated floating wetlands varied within the two operational periods due to a wider range of electrochemically inactive microbial populations in real wastewater that interfered with electrochemical organic matter oxidation. The positioning difference of the anode electrodes was a significant factor that improved pollutant removal within the electrode-integrated floating wetlands compared to the other variable, i.e., anode electrodes surface area.

Development of electrodes integrated hybrid constructed wetlands using organic, construction, and rejected materials as filter media: Landfill leachate treatment.

This study developed microbial fuel cell (MFC)-based hybrid constructed wetland systems using different filter media, i.e., organic (biochar), construction (sand), and rejected (iron particle, concrete particle, and stone dust) materials, and evaluated the performance of the developed systems for treating landfill leachate. The mean ammonium nitrogen (NH4-N), total nitrogen (TN), total phosphorus (TP), biochemical oxygen demand (BOD), chemical oxygen demand (COD) removal percentages within the hybrid systems ranged between 91 and 98%, 90 and 98%, 97 and 99%, 88 and 93%, 93 and 97%, respectively, despite higher pollutants concentration in leachate wastewater. The aerobic environment in the cathode compartment (due to intermittent load) and free-draining of wastewater (from cathode to anode compartment) supported electrochemically inactive, active pollutants removal in the electrodes integrated first stage vertical flow (VF) wetlands. The second stage electrodes integrated horizontal flow (HF) wetlands supported electrochemical-based organic removal and nitrification because of efficient organic removal in the previous VF wetland stages. Nitrogen, phosphorus accumulation percentages in plant tissues ranged between 0.3 and 7%, 0.4 and 14%, respectively. Nutrient removal was achieved through chemical and microbial routes. The biochar-packed VF wetland produced a maximum power density of 20.6 mW/m2. The coexistence of unsaturated, saturated media in the partially saturated HF wetland maintained the required environmental gradient between the electrodes and improved operational performance.

A comparative landfill leachate treatment performance in normal and electrodes integrated hybrid constructed wetlands under unstable pollutant loadings.

This study provides a comparative pollutant removal performance assessment between organic or construction materials-based four hybrid wetland systems that received landfill leachate. The hybrid systems included vertical flow (VF) followed by horizontal flow (HF)-based unplanted and planted systems, and planted electrodes incorporated microbial fuel cell (MFC) integrated hybrid wetlands systems. All the systems were run in free-draining mode. Overall mean chemical oxygen demand (COD), total nitrogen (TN), and total phosphorus (TP) removal percentage of the hybrid systems ranged between 81 and 99%, 82 and 96%, 74 and 99%, respectively, under unstable input pollutant loading conditions. Additionally, up to 27% organic and up to 14% nitrogen removal improvement was observed in electrodes integrated free-draining VF wetlands. Free-draining and additional oxygen availability from atmospheric diffusion, rootzone improved the removal performance of MFC-based VF wetlands. Input load increment decreased organic, nutrient removals in second stage HF units due to saturated media. The chemical composition of the employed media supported biotic, abiotic organic, nutrient removal pathways. Nutrient accumulation percentage in plants tissue was very low, i.e., ≤3%. Bioenergy production across the MFC-based VF-HF wetlands decreased with input pollutant load increment. The single anode electrode-based VF wetland achieved maximum power density production, i.e., 294 mW/m2.. The electrodes integrated hybrid systems achieved comparatively stable removal performance despite input pollutant/hydraulic load variation.

Intensified constructed wetlands for the treatment of municipal wastewater: experimental investigation and kinetic modelling.

This study reports organics and nutrient removal performances of the intensified constructed wetlands, i.e., tidal flow-based microbial fuel cell (MFC) and tidal flow wetlands that received municipal wastewater. The wetland systems were filled with organic (coco peat, biochar) or waste (Jhama brick, steel slag) materials, planted with Phragmites australis or Chrysopogon zizanioides (Vetiver) species, and operated under three flood periods: 8, 16, 24 h. Input ammonia nitrogen (NH3-N), total nitrogen (TN), phosphorus (P), chemical oxygen demand (COD), and biochemical oxygen demand (BOD) load across the wetland systems ranged between 3-27, 12-78, 0.1-23, 36-1130, and 11-281 g/m2day, respectively; mean removal percentages were 60-83, 74-84, 95-100, 94-98, and 93-97%, respectively, throughout the experimental run. The wetland systems achieved similar organics and P removals; operational and media variation did not influence removal kinetics. All wetland systems achieved the highest TN removal (76-87%) when subjected to 24-h flood period. TN removal performances of waste material-based wetlands were comparable to organic media-based systems. Tidal flow-based MFC wetlands achieved better TN removal than tidal flow wetlands because of supplementary electron production through fuel cell-based organics degradation kinetics. Maximum power production rates across the tidal flow-based MFC wetlands ranged between 53 and 57 mW/m2. Monod kinetics-based continuous stirred tank reactor (CSTR) models predicted NH3-N, TN, and COD removals (in wetland systems) more accurately. Kinetic models confirmed the influence of substrate (i.e., pollutant) and environmental parameters on pollutant removal routes.

Organics and nutrients removal in vertical flow wetlands: loading fluctuation and alternative media.

Two wetland systems (conventional and structurally modified) were studied for the removal of organics and nutrients from municipal wastewater. Each system consisted of three vertical flow (VF) wetlands, which were filled with agricultural, construction waste materials and planted with Phragmites australis and Canna indica. The wetland units were operated under constant and consecutive shock hydraulic load (HL). Input nutrients and organics load across the wetland units ranged between 4.0-116.0 g N/m2d, 0.5-23.0 g P/m2d, 1.0-527.0 g biochemical oxygen demand (BOD)/m2d and 16.0-686.0 g chemical oxygen demand (COD)/m2d. Nitrification and organic carbon availability controlled nitrogen (N) removals in first and third stage VF wetlands, respectively, during constant load phase; organics removals were influenced by dissolved oxygen concentration of municipal wastewater. Second stage VF wetlands (of both systems) were inefficient in terms of COD removals during shock load periods, which were counter-balanced by first and third stages. First stage VF wetlands achieved higher N removal rates than following stages during shock load periods. Wetland maturation provided a buffer against substantial HL increment and sharp input load decrease in latter shock and recovery phases, respectively. Agricultural waste (sugarcane bagasse) provided carbon to support denitrification; construction materials (recycled brick and crushed mortar) removed phosphorus (P) from wastewater through adsorption. Coliform removal in VF wetlands was achieved through media filtration. Structurally modified system achieved higher removals than the conventional system. BOD, COD, total nitrogen and NH4-N removal percentage across two systems ranged between 76-79%, 59-63%, 73-77% and 90-95%, respectively. In general, this study enlightens potential application of appropriate waste materials for wastewater treatment.

Pollutant removal from landfill leachate employing two-stage constructed wetland mesocosms: co-treatment with municipal sewage.

Constructed wetlands are low-cost, natural technologies that are often employed for the treatment of different types of wastewater. In this study, landfill leachate and municipal wastewater were co-treated by the three parallel two-stage Phragmites- or Vetiver-based constructed wetland mesocosms. Two-stage wetland mesocosms included vertical flow (VF) units as the first stage, followed by horizontal flow (HF)/surface flow (SF)/floating treatment (FT) units. VF and HF wetland mesocosms were filled with gravel, steel slag, concrete block, and intermittent carbon-saturated ceramic filters as substrates. Mean input nitrogen, organics, and phosphorus load across first stages were 75 g N/m2 day, 283 g COD/m2 day, 88 g BOD/m2 day, and 10 g P/m2 day, respectively. N and P accumulation rate was not substantial (< 10%) with respect to total removal in most wetland mesocosms. Gravel-based VF wetland mesocosm achieved better NH4-N and BOD removal (55-59%) during landfill leachate treatment phase, when compared with co-treatment periods (12-52%). Slag-concrete- and ceramic filter-based VF wetland mesocosms maintained stable NH4-N and BOD removals; the former wetland mesocosm was the most efficient VF unit (than other two wetland mesocosms) due to media characteristics. Media-based adsorption accelerated P removal (93%) in slag-concrete-based VF wetland mesocosm. Carbon scarcity limited denitrification in all VF wetland mesocosms; removal of TN was < 32%. Second stage wetland mesocosms achieved higher nitrogen (85-92%), organics (66-90%), and phosphorus (97-100%) removals regardless of operational variations; low input load, long retention time, media, and rhizosphere enhanced removal performances, particularly in HF and FT wetland mesocosms. In general, this study demonstrates potential application of two-stage wetland mesocosms for landfill leachate treatment or co-treatment with municipal sewage.

Two-stage constructed wetland systems for polluted surface water treatment.

Two pilot scale wetland systems were studied for the removal of organics, nitrogen, phosphorus and coliform from polluted surface water. Each system consisted of two units: a vertical flow (VF) wetland packed with construction materials gravel, brick or organic sugarcane bagasse, followed by a surface flow (SF) or floating treatment (FT) wetland. All wetland units were planted with Phragmites. The wetland systems were operated under constant and shock hydraulic load (HL) periods. Input COD, N, P loadings ranged between 61 and 2181, 7-1040, 2-194 g/m2d, respectively across first stages of each system. Mean removal percentages ranged between 39 and 97, 11-83, 20-100% and 4-85, 16-86, 1.4-100% across first and second stage wetlands, respectively. Mass balance analyses revealed ≤7% N and ≤14% P accumulation in plants; as such, microbial and adsorption kinetics controlled removal dynamics. Nitrification was the limiting nitrogen removal factor in first stage wetlands; organic carbon was supplied by the employed media. Aerobic organics removal and nitrification were diminished during initial stage of shock load periods. In contrast, second stage SF and FT wetlands showed stable removal performances under similar conditions. Resuspension of settled particles decreased removal performance in second stage wetlands, as shock periods progressed toward final stage. Coliform mortality was increased in second stage wetlands. Physico-chemical properties of brick materials in construction material based VF wetland and hanging root volume inside the water column of FT wetland supplemented removal performance. In general, this study provides evidence on potential application of constructed wetlands for polluted surface water treatment.

The use of biochar and crushed mortar in treatment wetlands to enhance the removal of nutrients from sewage.

An experimental study was carried out using in pilot-scale constructed wetland systems, operated in parallel to treat raw sewage. Each system consisted of a vertical flow (VF) unit that was filled with biochar as the main media, followed by a horizontal flow (HF) unit filled with crushed cement mortar. Hydraulic loading (HL) ranged 340-680 mm/day was applied on the VF wetland units, where high total nitrogen (TN) mass removal rate (20-23 g N/m2 d) was obtained, demonstrating that biochar media had a beneficial effect on the degradation of nitrogenous pollutants. Total phosphorus (TP) removal percentage (concentration based) was ≥ 86% in HF wetlands packed with mortar materials. In one system, the flow direction of the sewage was directed by the deployment of downflow pipes and vertical baffles, aiming to facilitate the formation of aerobic and anaerobic zones in the wetland matrices. The effects of such arrangement were analyzed by comparing pollutant removal efficiencies in the two systems. On average, 99, 96, 93, and 86 percentage removals were obtained for ammonia (NH4-N), TN, biochemical oxygen demand (BOD), and TP, respectively, during the experiments. Biochar and crushed mortar proved to be a highly effective combination as media in subsurface flow constructed wetlands for wastewater treatment.

Content Validity of a Tool Measuring Medication Errors.

The objective of this study was to determine content and face validity of a tool measuring medication errors among nursing students in baccalaureate nursing education. Data was collected from the Aga Khan University School of Nursing and Midwifery (AKUSoNaM), Karachi, from March to August 2014. The tool was developed utilizing literature and the expertise of the team members, expert in different areas. The developed tool was then sent to five experts from all over Karachi for ensuring the content validity of the tool, which was measured on relevance and clarity of the questions. The Scale Content Validity Index (S-CVI) for clarity and relevance of the questions was found to be 0.94 and 0.98, respectively. The tool measuring medication errors has an excellent content validity. This tool should be used for future studies on medication errors, with different study populations such as medical students, doctors, and nurses.

Water quantity and quality assessment on a tertiary treatment wetland in a tropical climate.

This study aimed to assess the quantity and quality of water in a surface flow constructed wetland in Australia's far north Queensland. Owing to tropical climate in the region, the wetland provided dual functions: retention of a treated wastewater for zero discharge during the dry season and tertiary treatment prior to discharge during the wet season. Rainfall data, permeability of wetland soil, evaporation, inflow and outflow were analysed in a water balance analysis; the results showed that based on a 72-year-average rainfall pattern, daily wastewater inflow of 85 m(3)/d is the maximum this wetland can cope with without breaching its discharge certificate. In water quality analysis, the K-C* model was used to predict changes of biochemical oxygen demand (BOD, suspended solids (SS), total nitrogen (TN), total phosphorus (TP) and faecal coliforms (FC) in the wetland. Model predictions were compared with field sampling results. It was found that the wetland was effective in removing FC (>99.9%), TN (70.7%) and TP (68.2%), for which the predictions by the K-C* model were consistent with field testing results. However, significant disparities between the predictions and testing results were found for BOD and SS. A revised K-C* equation was proposed to account for the internal generation of organics in constructed wetlands with a long retention time.

Pollutant removal from municipal wastewater employing baffled subsurface flow and integrated surface flow-floating treatment wetlands.

This article reports pollutant removal performances of baffled subsurface flow, and integrated surface flow-floating treatment wetland units, when arranged in series for the treatment of municipal wastewater in Bangladesh. The wetland units (of the hybrid system) included organic, inorganic media, and were planted with nineteen types of macrophytes. The wetland train was operated under hydraulic loading fluctuation and seasonal variation. The performance analyses (across the wetland units) illustrated simultaneous denitrification and organics removal rates in the first stage vertical flow wetland, due to organic carbon leaching from the employed organic media. Higher mean organics removal rates (656.0 g COD/(m(2)·day)) did not completely inhibit nitrification in the first stage vertical flow system; such pattern could be linked to effective utilization of the trapped oxygen, as the flow was directed throughout the media by the baffle walls. Second stage horizontal flow wetland showed enhanced biodegradable organics removal, which depleted organic carbon availability for denitrification. The final stage integrated wetland system allowed further nitrogen removal from wastewater, via nutrient uptake by plant roots (along with nitrification), and generation of organic carbon (by the dead macrophytes) to support denitrification. The system achieved higher E. coli mortality through protozoa predation, E. coli oxidation, and destruction by UV radiation. In general, enhanced pollutant removal efficiencies as demonstrated by the structurally modified hybrid wetland system signify the necessity of such modification, when operated under adverse conditions such as: substantial input organics loading, hydraulic loading fluctuation, and seasonal variation.

A lab-scale study of constructed wetlands with sugarcane bagasse and sand media for the treatment of textile wastewater.

This paper reports the pollutant removal efficiencies of two lab-scale hybrid wetland systems treating a textile wastewater. The two systems had identical configurations, each consisting of a vertical flow (VF) and a horizontal flow (HF) wetland that were filled with organic sugarcane bagasse and sylhet sand as the main media. The systems were operated under high hydraulic loading (HL) (566-5660 mm/d), and inorganic nitrogen (254-508 gN/m(2) d) and organics loadings (9840-19680 g COD/m(2) d and 2154-4307 g BOD(5)/m(2) d). Simultaneous removals of BOD(5) (74-79%) and ammonia (59-66%) were obtained in the first stage VF wetlands, demonstrating the efficiency of the media for oxygen transfer to cope with the high pollutant loads. The organic carbon (C) content of sugarcane bagasse facilitated denitrification in the VF wetlands. Second stage HF wetlands provided efficient color removal under predominantly anaerobic condition. Overall, the wetland systems showed stable removal performances under high, and unsteady, pollutant loadings.

A review on nitrogen and organics removal mechanisms in subsurface flow constructed wetlands: dependency on environmental parameters, operating conditions and supporting media.

With the unique advantages of lower operational and maintenance cost, the applications of subsurface flow constructed wetlands for the treatment of wastewater have been increasing rapidly throughout the world. The removal of nitrogen and organics by such systems has gained substantial attention in recent years. In subsurface flow wetlands, the removal of pollutants often relies on a diverse range of co-existing physical, chemical and biological routes, which are vitally dependent on numerous environmental and operational parameters. This paper provides a comprehensive review of wetland structures, classic and novel nitrogen and organics removal mechanisms along with the key environmental parameters and operational conditions that enhance removal in subsurface flow wetland systems. The critical exploration identifies the major environmental parameters such as: pH, DO, and temperature, operational factors i.e. organic carbon availability, loading, feed mode, retention time, recirculation, harvesting, and the complex role (of both parameters) on classical nitrogen and organics removal pathways. Subsequently, the necessity of further extensive research on such factors, for promoting novel nitrogen removal routes in wetland systems has also been highlighted. The expansion of the review on the influence of the unconventional wetland matrix indicates that, the structural differences and inherent properties of these media can support substantial nitrogen and organics removal from wastewater, under optimal operating conditions. Overall, the critical review illustrates the necessity of a profound knowledge on the complicated inter-relationship between nitrogen and organics removal routes, governing environmental and operational parameters, and wetland matrix for improving the treatment performances of subsurface flow wetlands.

Development of students' critical thinking: the educators' ability to use questioning skills in the baccalaureate programmes in nursing in Pakistan.

OBJECTIVE: To enhance the Critical Thinking skills of educators associated with the nursing baccalaureate programmes in Pakistan. By focusing on the type and level of questions asked by the educators. METHODS: Ninety-one faculty members from 14 out of 17 schools participated in the study. Data on the faculty's questioning skills was obtained through classroom observations and field notes. The duration of the observations was 45-60 minutes. Using Bloom's Taxonomy for cognitive thinking, questions were categorised into high and low categories. RESULTS: Most of the questions (68.9 %) asked by the participants were of lower levels, while some (5.37 %) were ambiguous. In many instances, the participants did not allow a sufficient wait-time for students to think and respond. CONCLUSION: The findings suggest that educators must learn to use the questioning strategy effectively. They should ask higher level questions if they wish to inculcate Critical Thinking in students.

Treatment of tannery wastewater in a pilot-scale hybrid constructed wetland system in Bangladesh.

This paper reports the pollutant removal performances of a hybrid wetland system in Bangladesh for the treatment of a tannery wastewater. The system consisted of three treatment stages: a subsurface vertical flow (VF) wetland, followed by a horizontal flow (HF) and a VF wetland. The wetlands were planted with common reed (Phragmites australis), but employed different media, including organic coco-peat, cupola slag and pea gravel. In the first stage, experimental results demonstrated significant removal of ammonia (52%), nitrate (54%), BOD (78%), and COD (56%) under high organics loading rate (690 g COD m(-2)d(-1)); simultaneous nitrification, denitrification, and organics degradation were attributed to the unique characteristics of the coco-peat media, which allowed greater atmospheric oxygen transfer for nitrification and organic degradation, and supply of organic carbon for denitrification. The second stage HF wetland produced an average PO(4) removal of 61%, primarily due to adsorption by the iron-rich cupola slag media. In the third treatment stage, which was filled with gravel media, further BOD removal (78%) from the tannery wastewater depleted organic carbon, causing the accumulation of NO(3) in the wastewater. Overall, the average percentage removals of NH(3)-N, NO(3)-N, BOD, COD, and PO(4) were 86%, 50%, 98%, 98% and 87%, respectively, across the whole hybrid system. The results provided a strong evidence to support widespread research and application of the constructed wetland as a low-cost, energy-efficient, wastewater treatment technology in Bangladesh.

Kinetic modelling of nitrogen and organics removal in vertical and horizontal flow wetlands.

This paper provides a comparative evaluation of the kinetic models that were developed to describe the biodegradation of nitrogen and organics removal in wetland systems. Reaction kinetics that were considered in the model development included first order kinetics, Monod and multiple Monod kinetics; these kinetics were combined with continuous-stirred tank reactor (CSTR) or plug flow pattern to produce equations to link inlet and outlet concentrations of each key pollutants across a single wetland. Using three statistical parameters, a critical evaluation of five potential models was made for vertical and horizontal flow wetlands. The results recommended the models that were developed based on Monod models, for predicting the removal of nitrogen and organics in a vertical and horizontal flow wetland system. No clear correlation was observed between influent BOD/COD values and kinetic coefficients of BOD(5) in VF and HF wetlands, illustrating that the removal of biodegradable organics was insensitive to the nature of organic matter. Higher effluent COD/TN values coincided with greater denitrification kinetic coefficients, signifying the dependency of denitrification on the availability of COD in VF wetland systems. In contrast, the trend was opposite in HF wetlands, indicating that availability of NO(3)-N was the main limiting step for nitrogen removal. Overall, the results suggested the possible application of the developed alternative predictive models, for understanding the complex biodegradation routes of nitrogen and organics removal in VF and HF wetland systems.