ABSTRACT
Krypton-81 was applied to investigate the age of groundwater in the aquifer system in the Bangkok metropolitan and vicinity areas. Stable (2H, 18O and 13C) and radioactive (3H, 85Kr and 14C) isotopes and noble gases were applied in parallel. Low levels of 14C and significant radiogenic 4He confirm that groundwater in the deep aquifers is older than 30 ka. 81Kr analysis identified groundwater with ages ranging from 17 to 300 ka. At some sites, large age discrepancies between 81Kr and 14C indicated that inter-aquifer mixing is likely occurring. The interpretation of the noble gases suggests that groundwaters in the deeper aquifers, with apparent ages of 300 to 10 ka, have recharged in slightly colder and wetter climates than those found in the upper aquifers with apparent ages < 10 ka. Degradation of water quality from seawater intrusion was identified in the upper four aquifers. This was also evidenced by higher δ18O and δ2H values, typical of seawater. The four deeper aquifers contain high quality water characterised by less enriched 18O and 2H. This work presents new findings of very old groundwater in the Bangkok aquifer system.
ABSTRACT
Tritium, whether naturally occurring or caused by human nuclear activity, can result in a large amount of tritium contamination in the environment, especially in the water cycle, causing a high concentration of tritium in rainfall. The objective of this research was to measure the level of tritium in the environment from rainfall in two different areas as a basis for monitoring tritium contamination in the environment. Rainwater samples were collected in Thailand every 24 h for a period of 1 year during 2021-2022 at the Kasetsart University Station, Sriracha Campus, Chonburi province and at the Mae Hia Agricultural Meteorological Station, Chiang Mai province. The tritium levels were measured in rainwater samples using the electrolytic enrichment method combined with liquid scintillation counting. The chemical composition of the rainwater was analyzed based on ion chromatography. The results (presented with ± combined uncertainty) showed that the tritium content in the rainwater samples at Kasetsart University Station Sriracha Campus was in the range 0.9 ± 0.2-1.6 ± 0.3 TU (0.11 ± 0.02-0.19 ± 0.03 Bq.L-1). The mean concentration was 1.0 ± 0.2 TU (0.12 ± 0.03 Bq.L-1). The most common ions found in the rainwater samples were SO42-, Ca2+, and NO3-, with mean concentrations of 1.52 ± 0.82, 1.08 ± 0.51, and 1.05 ± 0.78 mg.L-1, respectively. The tritium content in rainwater collected from the Mae Hia Agricultural Meteorological Station was in the range 1.6 ± 0.2-4.9 ± 0.4 TU (0.19 ± 0.02-0.58 ± 0.05 Bq.L-1). The mean concentration was 2.4 ± 0.4 TU (0.28 ± 0.05 Bq.L-1). The most common ions found in the rainwater were NO3-, Ca2+, and SO42-, with mean concentrations of 1.21 ± 1.02, 0.67 ± 0.43, and 0.54 ± 0.41 mg.L-1, respectively. The tritium concentration in the rainwater at both stations differed but remained at a natural level (less than 10 TU). There was no correlation between the tritium concentration and the chemical composition of the rainwater. The tritium levels obtained from this study could be used as a basis for reference and monitoring of future environmental changes due to nuclear accidents or activities, both domestically and internationally.
