Effects of Additives on the Mechanical and Fire Resistance Properties of Pultruded Composites.

Under high temperatures, fiber-reinforced polymers are destroyed, releasing heat, smoke, and harmful volatile substances. Therefore, composite structural elements must have sufficient fire resistance to meet the requirements established by building codes and regulations. Fire resistance of composite materials can be improved by using mineral fillers as flame-retardant additives in resin compositions. This article analyzes the effect of fire-retardant additives on mechanical properties and fire behavior of pultruded composite profiles. Five resin mixtures based on vinyl ester epoxy and on brominated vinyl ester epoxy modified with alumina trihydrate and triphenyl phosphate were prepared for pultrusion of strip profiles of 150 mm × 3.5 mm. A series of tests have been conducted to determine mechanical properties (tensile, flexural, compression, and interlaminar shear) and fire behavior (ignitability, flammability, combustibility, toxicity, smoke generation, and flame spread) of composites. It was found that additives impair mechanical properties of materials, as they the take place of reinforcing fibers and reduce the volume fraction of reinforcing fibers. Profiles based on non-brominated vinyl ester epoxy have higher tensile, compressive, and flexural properties than those based on brominated vinyl ester epoxy by 7%, 30%, and 36%, respectively. Profiles based on non-brominated epoxy resin emit less smoke compared to those based on brominated epoxy resin. Brominated epoxy-based profiles have a flue gas temperature which is seven times lower compared to those based on the non-brominated epoxy. Mineral fillers retard the spread of flame over the composite material surface by as much as 4 times and reduce smoke generation by 30%.

Thermal and Electrical Properties of Additively Manufactured Polymer-Boron Nitride Composite.

The efficiency of electronic microchip-based devices increases with advancements in technology, while their size decreases. This miniaturization leads to significant overheating of various electronic components, such as power transistors, processors, and power diodes, leading to a reduction in their lifespan and reliability. To address this issue, researchers are exploring the use of materials that offer efficient heat dissipation. One promising material is a polymer-boron nitride composite. This paper focuses on 3D printing using digital light processing of a model of a composite radiator with different boron nitride fillings. The measured absolute values of the thermal conductivity of such a composite in the temperature range of 3-300 K strongly depend on the concentration of boron nitride. Filling the photopolymer with boron nitride leads to a change in the behavior of the volt-current curves, which may be associated with the occurrence of percolation currents during the deposition of boron nitride. The ab initio calculations show the behavior and spatial orientation of BN flakes under the influence of an external electric field at the atomic level. These results demonstrate the potential use of photopolymer-based composite materials filled with boron nitride, which are manufactured using additive techniques, in modern electronics.

The Effects of Eccentric Web Openings on the Compressive Performance of Pultruded GFRP Boxes Wrapped with GFRP and CFRP Sheets.

Pultruded fiber-reinforced polymer (PFRP) profiles have started to find widespread use in the structure industry. The position of the web openings on these elements, which are especially exposed to axial pressure force, causes a change in the behavior. In this study, a total of 21 pultruded box profiles were tested under vertical loads and some of them were strengthened with carbon-FRP (CFRP) and glass-FRP (GFRP). The location, number and reinforcement type of the web openings on the profiles were taken into account as parameters. As a result of the axial test, it was understood that when a hole with a certain diameter is to be drilled on the profile, its position and number are very important. The height-centered openings in the middle of the web had the least effect on the reduction in the load-carrying capacity and the stability of the profile. In addition, it has been determined that the web openings away from the center and especially the eccentric opening significantly reduces the load carrying capacity. Furthermore, when double holes were drilled close to each other, a significant decrease in the capacity was observed and strengthening had the least effect on these specimens. It was also determined that the specimens reinforced with carbon FRP contribute more to the load-carrying capacity than GFRP.

Compressive Behavior of Pultruded GFRP Boxes with Concentric Openings Strengthened by Different Composite Wrappings.

Web openings often need to be created in structural elements for the passage of utility ducts and/or pipes. Such web openings reduce the cross-sectional area of the structural element in the affected region, leading to a decrease in its load-carrying capacity and stiffness. This paper experimentally studies the effect of web openings on the response of pultruded fiber-reinforced polymer (PFRP) composite profiles under compressive loads. A number of specimens have been processed to examine the behavior of PFRP profiles strengthened with one or more web openings. The effects of the size of the web opening and the FRP-strengthening scheme on the structural performance of PFRP profiles with FRP-strengthened web openings have been thoroughly analyzed and discussed. The decrease in load-carrying capacity of un-strengthened specimens varies between 7.9% and 66.4%, depending on the diameter of the web holes. It is observed that the diameter of the hole and the type of CFRP- or GFRP-strengthening method applied are very important parameters. All CFRP- and GFRP-strengthening alternatives were successful in the PFRP profiles, with diameter-to-width (D/W) ratios between 0.29 and 0.68. In addition, the load-carrying capacity after reinforcements made with CFRP and GFRP increased by 3.1-30.2% and 1.7-19.7%, respectively. Therefore, the pultruded profiles with openings are able to compensate for the reduction in load-carrying capacity due to holes, up to a D/W ratio of 0.32. The capacity significantly drops after a D/W ratio of 0.32. Moreover, the pultruded profile with CFRP wrapping is more likely to improve the load-carrying capacity compared to other wrappings. As a result, CFRP are recommended as preferred composite materials for strengthening alternatives.

Effect of Fiber Wrapping on Bending Behavior of Reinforced Concrete Filled Pultruded GFRP Composite Hybrid Beams.

The application of pultruded fiber reinforced polymer (FRP) composites in civil engineering is increasing as a high-performance structural element or reinforcing material for rehabilitation purposes. The advantageous aspects of the pultrusion production technique and the weaknesses arising from the 0° fiber orientation in the drawing direction should be considered. In this direction, it is thought that the structural performance of the profiles produced by the pultrusion technique can be increased with 90° windings by using different fiber types. This paper presents experimental studies on the effect of FRP composite wrapping on the flexure performance of reinforced concrete (RC) filled pultruded glass-FRP (GFRP) profile hybrid beams with damage analysis. The hybrid beams are wrapped fully and partially with Glass fiber reinforced polymer (GFRP) and carbon fiber reinforced polymer (CFRP) composites. Hybrid beam specimens with 0° to 90° fiber orientations were tested under three- and four-point bending loads. Based on the experimental load-displacement relationship results, initial stiffness, ductility, and energy dissipation capacity were compared. The experimental findings revealed that the maximum load-carrying capacities of beams produced with pultrude profiles increased by 24% with glass wrapping and 64.4% with carbon wrapping due to the change in the damages. A detailed damage analysis is provided. Similarly, significant increases were observed in structural performance ratios such as initial stiffness and ductility ratio.

Effects of the Pre-Consolidated Materials Manufacturing Method on the Mechanical Properties of Pultruded Thermoplastic Composites.

The choice of a manufacturing process, raw materials, and process parameters affects the quality of produced pre-consolidated tapes used in thermoplastic pultrusion. In this study, we used two types of pre-consolidated GF/PP tapes-commercially available (ApATeCh-Tape Company, Moscow, Russia) and inhouse-made tapes produced from commingled yarns (Jushi Holdings Inc., Boca Raton, FL, USA)-to produce pultruded thermoplastic Ø 6 mm bars and 75 mm × 3.5 mm flat laminates. Flat laminates produced from inhouse-made pre-consolidated tapes demonstrated higher flexural, tensile, and apparent interlaminar shear strength compared to laminates produced from commercial pre-consolidated tapes by as much as 106%, 6.4%, and 27.6%, respectively. Differences in pre-consolidated tape manufacturing methods determine the differences in glass fiber impregnation and, thus, differences in the mechanical properties of corresponding pultruded composites. The use of commingled yarns (consisting of matrix and glass fibers properly intermingled over the whole length of prepreg material) makes it possible to achieve a more uniform impregnation of inhouse-made pre-consolidated tapes and to prevent formation of un-impregnated regions and matrix cracks within the center portion of the fiber bundles, which were observed in the case of commercial pre-consolidated tapes. The proposed method of producing pre-consolidated tapes made it possible to obtain pultruded composite laminates with larger cross sections than their counterparts described in the literature, featuring better mechanical properties compared to those produced from commercial pre-consolidated tapes.

Multifunctional Elastic Nanocomposites with Extremely Low Concentrations of Single-Walled Carbon Nanotubes.

Stretchable and flexible electronics has attracted broad attention over the last years. Nanocomposites based on elastomers and carbon nanotubes are a promising material for soft electronic applications. Despite the fact that single-walled carbon nanotube (SWCNT) based nanocomposites often demonstrate superior properties, the vast majority of the studies were devoted to those based on multiwalled carbon nanotubes (MWCNTs) mainly because of their higher availability and easier processing procedures. Moreover, high weight concentrations of MWCNTs are often required for high performance of the nanocomposites in electronic applications. Inspired by the recent drop in the SWCNT price, we have focused on fabrication of elastic nanocomposites with very low concentrations of SWCNTs to reduce the cost of nanocomposites further. In this work, we use a fast method of coagulation (antisolvent) precipitation to fabricate elastic composites based on thermoplastic polyurethane (TPU) and SWCNTs with a homogeneous distribution of SWCNTs in bulk TPU. Applicability of the approach is confirmed by extra low percolation threshold of 0.006 wt % and, as a consequence, by the state-of-the-art performance of fabricated elastic nanocomposites at very low SWCNT concentrations for strain sensing (gauge factor of 82 at 0.05 wt %) and EMI shielding (efficiency of 30 dB mm-1 at 0.01 wt %).

Modeling Spring-In of L-Shaped Structural Profiles Pultruded at Different Pulling Speeds.

Cure-induced deformations are inevitable in pultruded composite profiles due to the peculiarities of the pultrusion process and usually require the use of costly shimming operations at the assembly stage for their compensation. Residual stresses formed at the production and assembly stages impair the mechanical performance of pultruded elements. A numerical technique that would allow the prediction and reduction of cure-induced deformations is essential for the optimization of the pultrusion process. This study is aimed at the development of a numerical model that is able to predict spring-in in pultruded L-shaped profiles. The model was developed in the ABAQUS software suite with user subroutines UMAT, FILM, USDFLD, HETVAL, and UEXPAN. The authors used the 2D approach to describe the thermochemical and mechanical behavior via the modified Cure Hardening Instantaneous Linear Elastic (CHILE) model. The developed model was validated in two experiments conducted with a 6-month interval using glass fiber/vinyl ester resin L-shaped profiles manufactured at pulling speeds of 200, 400, and 600 mm/min. Spring-in predictions obtained with the proposed numerical model fall within the experimental data range. The validated model has allowed authors to establish that the increase in spring-in values observed at higher pulling speeds can be attributed to a higher fraction of uncured material in the composite exiting the die block and the subsequent increase in chemical shrinkage that occurs under unconstrained conditions. This study is the first one to isolate and evaluate the contributions of thermal and chemical shrinkage into spring-in evolution in pultruded profiles. Based on this model, the authors demonstrate the possibility of achieving the same level of spring-in at increased pulling speeds from 200 to 900 mm/min, either by using a post-die cooling tool or by reducing the chemical shrinkage of the resin. The study provides insight into the factors significantly affecting the spring-in, and it analyzes the methods of spring-in reduction that can be used by scholars to minimize the spring-in in the pultrusion process.

Thermoplastic Pultrusion: A Review.

Pultrusion is one of the most efficient methods of producing polymer composite structures with a constant cross-section. Pultruded profiles are widely used in bridge construction, transportation industry, energy sector, and civil and architectural engineering. However, in spite of the many advantages thermoplastic composites have over the thermoset ones, the thermoplastic pultrusion market demonstrates significantly lower production volumes as compared to those of the thermoset one. Examining the thermoplastic pultrusion processes, raw materials, mechanical properties of thermoplastic composites, process simulation techniques, patents, and applications of thermoplastic pultrusion, this overview aims to analyze the existing gap between thermoset and thermoplastic pultrusions in order to promote the development of the latter one. Therefore, observing thermoplastic pultrusion from a new perspective, we intend to identify current shortcomings and issues, and to propose future research and application directions.

Porous Open-Сell UHMWPE: Experimental Study of Structure and Mechanical Properties.

Ultra-high molecular weight polyethylene (UHMWPE) is a bioinert polymer that is widely used as bulk material in reconstructive surgery for structural replacements of bone and cartilage. Porous UHMWPE can be used for trabecular bone tissue replacement, and it can be used in living cell studies as bioinert 3D substrate permeable to physiological fluids. It is important to develop techniques to govern the morphology of open-cell porous UHMWPE structures (pore size, shape, and connectivity), since this allows control over proliferation and differentiation in living cell populations. We report experimental results on the mechanical behavior of porous open-cell UHMWPE obtained through sacrificial removal (desalination) of hot-molded UHMWPE-NaCl powder mixtures with pore sizes in the range 75 µm to 500 µm. The structures were characterized using SEM and mechanically tested under static compression and dynamic mechanical analysis (DMA), bending, and tensile tests. Apparent elastic modulus and complex modulus were in the range of 1.2 to 2.5 MPa showing a weak dependence on cell size. Densification under compression caused the apparent elastic modulus to increase to 130 MPa.

Author Correction: Natural Erosion of Sandstone as Shape Optimisation.

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Natural Erosion of Sandstone as Shape Optimisation.

Natural arches, pillars and other exotic sandstone formations have always been attracting attention for their unusual shapes and amazing mechanical balance that leave a strong impression of intelligent design rather than the result of a stochastic process. It has been recently demonstrated that these shapes could have been the result of the negative feedback between stress and erosion that originates in fundamental laws of friction between the rock's constituent particles. Here we present a deeper analysis of this idea and bridge it with the approaches utilized in shape and topology optimisation. It appears that the processes of natural erosion, driven by stochastic surface forces and Mohr-Coulomb law of dry friction, can be viewed within the framework of local optimisation for minimum elastic strain energy. Our hypothesis is confirmed by numerical simulations of the erosion using the topological-shape optimisation model. Our work contributes to a better understanding of stochastic erosion and feasible landscape formations that could be found on Earth and beyond.