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1.
Environ Res ; 212(Pt E): 113635, 2022 09.
Article in English | MEDLINE | ID: mdl-35688220

ABSTRACT

The use of visible-driven photocatalysts has fascinated attention as a capable and sustainable approach for wastewater remediation. In this work, BiOBr/carbon quantum dot (CQDs)/saponite composites (CQDs/Clay@BiOBr) were fabricated via hydrothermally using two different CQDs/Clay precursors (in-situ synthesis (IS) and physical mixing (PM)). The obtained products were characterized, and the photocatalytic performances of the prepared samples were evaluated in the photocatalytic decomposition of emerging ciprofloxacin (CIP) pharmaceutical waste. The highest CIP mineralization performance was achieved when a combination of BiOBr and CQDs/Clay (IS) with the appropriate proportion because the strong adhesion between CQDs and clay generate a great heterojunction in the composite. The stronger interaction of CQDs and better distribution of CQDs on the surface of clay in the CQDs/Clay (IS) enhanced the interaction of BiOBr and CQDs, and avoided the re-agglomeration of excess of CQDs on surface of BiOBr which reduce the active surface to receive the light and react with CIP. The ultrafast degradation rate of the optimized CQDs/Clay@BiOBr composite was better compared to others. The significant improvement in the CIP degradation efficiency of the CQDs/Clay@BiOBr composite was attributed to the excellent separation and transportation of photogenerated electrons and holes, as confirmed by photoluminescence, photocurrent density, and electrochemical impedance spectroscopy results. Moreover, the photocatalytic degradation mechanism of CIP in the CQDs/Clay@BiOBr composite was proposed based on the electronic states of each material in the composite and on a scavenger test. Thus, the proposed CQDs/Clay@BiOBr composite can be employed as a potential visible-light-driven photocatalyst for the decomposition of organic contaminants in wastewater.


Subject(s)
Quantum Dots , Aluminum Silicates , Bismuth , Carbon , Catalysis , Ciprofloxacin , Clay , Light , Quantum Dots/chemistry , Wastewater
2.
RSC Adv ; 12(14): 8283-8289, 2022 Mar 15.
Article in English | MEDLINE | ID: mdl-35424817

ABSTRACT

We here report a practical and green approach to the development of luminescent composites through in situ solvent-free formation of carbon dots on layered inorganic compounds. The composites exhibit higher solid-state photoluminescence than those prepared by mixing of synthesized carbon dots and layered clay minerals. Tuning of the emission color of the composites has also been achieved by the addition of small molecules into phloroglucinol as starting materials for carbonization. The carbon dots synthesized in clay compounds in the solvent-free conditions are well-dispersed to obtain homogeneous composites. Furthermore, we have demonstrated that highly luminescent carbon dots are formed by carbonization in the presence of layered inorganic compounds. The one-step solvent-free approach presented in this work may allow not only facile, economical, and sustainable production of nanostructured carbon dot-based composites but also improvement of their luminescence properties.

3.
Biosci Biotechnol Biochem ; 75(7): 1312-6, 2011.
Article in English | MEDLINE | ID: mdl-21737935

ABSTRACT

A rapid method for predicting the buckwheat flour ratio of dried buckwheat noodles was developed by using the fluorescence fingerprint and partial least squares regression. Fitting the calibration model to validation datasets showed R(2)=0.78 and SEP=12.4%. The model was refined for a better fit by deleting several samples containing additional ingredients. The best fit was finally obtained (R(2)=0.84 and SEP=10.4%) by deleting the samples containing vinegar, green tea, seaweed, polysaccharide thickener, and yam. This result demonstrates that a calibration model with high accuracy could be constructed based on samples similar in material composition. The developed methodology requires no complex preprocessing, enables rapid measurement with a small sample amount, and would thus be suitable for practical application to the food industry.


Subject(s)
Fagopyrum/chemistry , Flour/analysis , Fluorescence , Food Analysis/methods , Calibration , Food , Food Industry , Least-Squares Analysis , Plant Proteins/analysis
4.
Shokuhin Eiseigaku Zasshi ; 52(1): 18-23, 2011.
Article in Japanese | MEDLINE | ID: mdl-21383529

ABSTRACT

The thermoluminescence (TL) method using X-rays was investigated for the purpose of detection of irradiated food, and the method was validated at a single laboratory level. A small X-ray irradiator was developed as an alternative radiation source for normalization, and X-ray irradiation conditions equivalent to gamma-ray irradiation from (60)Co were established. Gamma-ray irradiated spices were used for the method validation. The detection limits (MDL) and lower limit of integrated TL intensities (MDL×10) for the spices were checked and the separation of silicate minerals from the spices was confirmed to be sufficient for TL analysis. There was no significant difference in TL glow ratio obtained using two sets of X-ray irradiation equipment including the newly developed equipment. Repeatability and intermediate precision showed no influence of analysts, X-ray irradiation equipments, or measurement days on the TL ratios. From these results, this detection method was validated in a single laboratory.


Subject(s)
Food Irradiation , Luminescent Measurements/methods , Gamma Rays , Luminescent Measurements/instrumentation , Spices , X-Rays
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