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Dalton Trans ; 42(30): 11012-20, 2013 Aug 14.
Article in English | MEDLINE | ID: mdl-23797618

ABSTRACT

Here, we propose a mathematical model that gives a good fit to the experimental data for water oxidation by Mn oxide-coated montmorillonite with different Mn content. Our data show that the water oxidation may progress by cooperation among only neighbor Mn ions on montmorillonite. It is a promising model for finding more about the mechanism of multi-electron reactions.


Subject(s)
Bentonite/chemistry , Manganese Compounds/chemistry , Models, Theoretical , Oxides/chemistry , Water/chemistry , Catalysis , Nanoparticles/chemistry , Oxidation-Reduction
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