1.
Acta Crystallogr Sect E Struct Rep Online
; 70(Pt 10): o1120-1, 2014 Oct 01.
Article
in English
| MEDLINE
| ID: mdl-25484706
ABSTRACT
In the title compound, C27H19N3O, the dihedral angles between the plane of the pyridine ring and those of the indole (r.m.s. deviation = 0.018â Å), phenyl and meth-oxy-benzene substituents are 33.60â (6), 25.28â (7) and 49.31â (7)°, respectively. The N atom of the carbo-nitrile group is significantly displaced [0.288â (2)â Å] from the plane of the pyridine ring, perhaps due to steric crowding. In the crystal, inversion dimers linked by pairs of N-Hâ¯Nn (n = nitrile) hydrogen bonds generate R 2 (2)(16) loops. Aromatic π-π stacking [centroid-centroid separation = 3.6906â (7)â Å] and very weak C-Hâ¯π inter-actions are also observed".