Investigation of PAHs, nitrated PAHs and oxygenated PAHs in PM10 urban aerosols. A comprehensive data analysis.

Polycyclic aromatic compounds (PACs) in particulate matter contribute considerably to the health risk of air pollution. As such, we have optimized a method to determine the levels of polycyclic aromatic hydrocarbons, especially nitrated and oxygenated polycyclic aromatic hydrocarbons, in samples of PM10 particulate matter using microwave-assisted extraction (MAE) and gas chromatography coupled to a triple quadrupole mass spectrometer (GC-MS/MS). The proposed method was applied to the analysis of real samples collected in the urban area of Ciudad Real (Spain) during one year. The median total concentrations of eighteen PAHs (∑PAHs) and seven OPAHs (∑OPAHs) were 0.54 and 0.23 ng m-3, respectively, with the corresponding value for NPAH (∑NPAHs) being 0.03 ng m-3 (only detected in 40% of samples). A clear seasonal trend was observed, with higher levels in the cold season and lower in the warm season for ∑PAHs. The same effect was observed for ∑OPAHs, which exhibited a median concentration of 0.72 ng m-3 in the cold season and 0.10 ng m-3 in the warm season, and for ∑NPAH, which exhibited a median of 0.04 ng m-3 in the cold season but were not detected in the warm season. Molecular diagnostic ratios and PCA (principal component analysis) showed a predominantly traffic origin for PACs. The sources of PAHs also depend on meteorological conditions and/or atmospheric reactions, as confirmed by means of statistical analysis. The ∑OPAH/∑PAH and ∑NPAH/∑PAH ratios were higher in the cold season than the warm season, thus suggesting that PAH derivatives originated from primary combustion emission sources together with their parent PAHs. The concentration range found for benzo(a)pyrene was 0.006-0.542 ng m-3, which is below the threshold value of 1 ng m-3 established in European legislation as the annual average value. The lifetime lung risk from inhalation of PM10-bound PACs was estimated to be six cancer cases per million people using the World Health Organization method.

Atmospheric degradation of 3-ethoxy-1-propanol by reactions with Cl, OH and NO3.

An experimental kinetic and mechanistic study of the reactions of 3-ethoxy-1-propanol (CH3CH2OCH2CH2CH2OH) with Cl atoms and OH and NO3 radicals has been carried out at room temperature and atmospheric pressure. FTIR (Fourier Transform Infrared Spectroscopy) and GC-MS (Gas Chromatography/Mass Spectrometry) were used as detection techniques. The rate coefficients were measured with a relative method (units cm3 molecule-1 s-1): (3.46 ± 0.22) × 10-10, (3.48 ± 0.19) × 10-11 and (1.08 ± 0.07) × 10-14 for Cl, OH and NO3 reactions, respectively. Qualitative and quantitative products analysis was carried out and formaldehyde, ethyl formate, ethyl 3-hydroxypropanoate and nitrated compounds were positively identified. A reaction mechanism has been proposed which involves attack by the oxidant at the methylene group in the α-position to an oxygen atom of the ether or alcohol groups, followed by the subsequent reactions of the resulting radicals. The tropospheric reactivity of 3-ethoxy-1-propanol (3E1P) has been compared with the reactivity of other hydroxy ethers to extend our knowledge of this type of compound. The atmospheric implications for 3E1P have been established by estimating parameters such as lifetimes, global warming potential (GWP) and the Photochemical Ozone Creation Potential (POCPE). According to the calculated tropospheric lifetimes, the dominant loss process of 3E1P is its daytime reaction with the OH radical and this has an impact on a local scale.

Assessment of CO2 and aerosol (PM2.5, PM10, UFP) concentrations during the reopening of schools in the COVID-19 pandemic: The case of a metropolitan area in Central-Southern Spain.

Public health authorities have been paramount in guaranteeing that adequate fresh air ventilation is promoted in classrooms to avoid SARS-CoV-2 transmission in educational environments. In this work it was aimed to assess ventilation conditions (carbon dioxide, CO2) and suspended particulate matter (PM2.5, PM10 and UFP) levels in 19 classrooms - including preschool, primary and secondary education - located in the metropolitan area of Ciudad Real, Central-Southern Spain, during the school's reopening (from September 30th until October 27th, 2020) after about 7 months of lockdown due to COVID-19 pandemic. The classrooms that presented the worst indoor environmental conditions, according to the highest peak of concentration obtained, were particularly explored to identify the possible influencing factors and respective opportunities for improvement. Briefly, findings suggested that although ventilation promoted through opening windows and doors according to official recommendations is guaranteeing adequate ventilation conditions in most of the studied classrooms, thus minimizing the risk of SARS-CoV-2 airborne transmission, a total of 5 (26%) surveyed classrooms were found to exceed the recommended CO2 concentration limit value (700 ppm). In general, preschool rooms were the educational environments that registered better ventilation conditions, while secondary classrooms exhibited the highest peak and average CO2 concentrations. In turn, for PM2.5, PM10 and UFP, the concentrations assessed in preschools were, on average about 2-fold greater than the levels obtained in both primary and secondary classrooms. In fact, the indoor PM2.5 and PM10 concentrations substantially exceeded the recommended limits of 8hr-exposure, established by WHO, in 63% and 32% of the surveyed classrooms, respectively. Overall, it is expected that the findings presented in this study will assist the establishment of evidence-based measures (namely based on ensuring proper ventilation rates and air filtration) to mitigate preventable environmental harm in public school buildings, mainly at local and national levels.