Crosslinked carboxymethyl cellulose colloidal solution for cotton thread coating in wound dressing: A rheological study.

Cotton thread therapeutic properties as a wound dressing can be enhanced by utilising carboxymethyl cellulose-nanoparticles (CMC/NPs) colloidal solution as a coating solution. Nanoparticles such as graphene oxide (GO), graphene quantum dots (GQD), and silver nanoparticles (AgNP) stability in CMC was investigated through the rheological analysis and UV-Vis spectroscopy of the colloidal solutions. Citric acid (CA) acted as a crosslinker and was utilised to crosslink the colloidal solution with cotton thread. These CMC/NPs coated threads were subjected to mechanical properties and antibacterial activity analysis. Results obtained indicate less nanoparticle agglomeration and were stable in the CMC-based nanofluid. CMC/NPs rheological study suggested that colloidal solutions exhibited shear thinning behaviour and behaved as non-Newtonian fluids with n < 1. Crosslinked CMC/NPs appeared in a gel-like state as the viscoelasticity of the solution increased. Among the colloidal solutions, CMC/AgNP showed the highest enhancement with a significant difference at p < 0.05 in terms of mechanical and antibacterial properties. Consequently, the rheological properties and stability of CMC/NPs might influence the coating solution's appearance and refine the cotton thread's microstructure for a functional wound dressing to be further utilised as a coating solution for antibacterial cotton thread wound dressing material.

Macro-Size Regenerated Cellulose Fibre Embedded with Graphene Oxide with Antibacterial Properties.

Macro-size regenerated cellulose fibres (RCFs) with embedded graphene oxide (GO) were fabricated by dissolving cellulose in a pre-cooled sodium hydroxide (NaOH)/urea solution and regenerated in sulphuric acid (H2SO4) coagulant. Initially, GO was found to disperse well in the cellulose solution due to intercalation with the cellulose; however, this cellulose-GO intercalation was disturbed during the regeneration process, causing agglomeration of GO in the RCF mixture. Agglomerated GO was confirmed at a higher GO content under a Dino-Lite microscope. The crystallinity index (CrI) and thermal properties of the RCFs increased with increasing GO loadings, up to 2 wt.%, and reduced thereafter. Cellulose-GO intercalation was observed at lower GO concentrations, which enhanced the crystallinity and thermal properties of the RCF-GO composite. It was shown that the GO exhibited antibacterial properties in the RCF-GO composite, with the highest bacterial inhibition against E. coli and S. aureus.

Thermally Treated Berberine-Loaded SA/PVA/PEO Electrospun Microfiber Membranes for Antibacterial Wound Dressings.

This study aimed to develop a safe and advanced antibacterial material of electrospun microfiber membranes (MFMs) for wound dressings. Combinations of several materials were investigated; thermal treatment and electrospinning techniques were used to form the best quality of MFMs to suit its end applications. By comparing the fiber morphology, diameter changes, and fracture strength, the suitable ratio of raw materials and thermal treatment were obtained before and after adding Trition X-100 as a surfactant for MFMs of sodium alginate/polyvinyl alcohol/polyethylene oxide (SA/PVA/PEO). The electrospinning solution was mixed with berberine as an antibacterial substance; meanwhile, calcium chloride (CaCl2) was used as the crosslinking agent. The antibacterial properties, water dissolution resistance, water content, and fracture strength were thoroughly investigated. The results showed that the antibacterial rates of MFMs with different mass fractions of berberine (0, 3, and 5 wt.%) to Escherichia coli (E. coli) were 14.7, 92.9, and 97.2%, respectively. The moisture content and fracture strength of MFMs containing 5 wt.% berberine were 72.0% and 7.8 MPa, respectively. In addition, the produced MFMs embodied great water dissolution resistance. Berberine-loaded SA/PVA/PEO MFMs could potentially serve as an antibacterial wound dressing substrate with low cost and small side effects.

Hydrogel Application in Urban Farming: Potentials and Limitations-A Review.

Urban agriculture plays a vital role in ensuring the self-sufficiency of a great variety of fresh vegetables and nutrients. It promotes a sustainable food system as well as reducing the dependency on imports for the growing population. Urban farming has made it possible for agriculture practices to be implemented anywhere at any time in a sophisticated way. Hydrogel has been introduced in urban agriculture in the past few decades. However, the application of hydrogel in urban agriculture is still being explored in terms of hydrogel types, structure, physical and chemical properties, change due to external factors, and its suitability for different plant species. This review discusses the potentials and limitations of hydrogel in different application conditions. We present the state of knowledge on hydrogel production and crosslinking methods, hydrogel characteristics, water absorption and release mechanisms of hydrogel, hydrogel advantages and limitations, and current and future applications in urban farming.

Drying Regimes on Regenerated Cellulose Films Characteristics and Properties.

Abundant water content and its interaction with cellulose macromolecules through hydrogen bonding engenders a complex drying process, the circumstances of which have not yet been unveiled. For instance, excessive drying on regenerated cellulose membranes (RCM) causes cracking and severe shrinking, affecting the produced regenerated cellulose film (RCF). Thus, mathematical models in estimating the drying kinetics and required energy to dry RCM are necessary. This study evaluated two drying techniques of oven drying and infrared (IR) drying on RCM at different temperatures of 50-80 °C. Five mathematical models were used, namely Newton, Page, Handreson-Pabis, logarithmic, and Wang-Singh, to adjust the obtained experimental data and were statistically validated using ANOVA to review their effect on the quality of the produced RCF. A logarithmic model and a Wang-Singh model were the best models for oven drying and IR drying of RCM, respectively. It was found that the physical property of the RCF was similar to all drying types. Meanwhile, for mechanical properties, the high temperature of oven drying affected the tensile properties of RCF compared with IR drying. This study is beneficial by approximating the drying kinetics of RCM and defining appropriate drying conditions, which controls the quality of its predictive physical and mechanical properties.

Mechanical Properties and Water Absorption Capacity of Hybrid GFRP Composites.

Hybrid glass fibre reinforced polymer (GFRP) composites have been used for decades in various engineering applications. However, it has a drawback with its application in marine/flood environments due to a lack of water resistance and frail mechanical stability. Floods have been considered one of the most periodic hazards that could hit urban areas, due to climate change. The present paper aims to address this gap and to investigate the mechanical properties (tensile, compressive, and flexural strength) and water absorption capacity of hybrid GFRP composite comprising woven E-glass fabric and epoxy resin, various reinforcing materials (kenaf and coconut fibres), and various filler materials (fly ash, nano-silica, and calcium carbonate (CaCO3). The composites with 30 wt.% GFRP, 50 wt.% resin, 15 wt.% fly ash, 5 wt.% CaCO3, 10 wt.% GFRP, 60 wt.% resin, and 30 wt.% fly ash showed the lowest water absorption property of 0.45%. The results revealed that the GFRP composite reinforced kenaf fibres with nano-silica, fly ash, and CaCO3 improved the water absorption resistance. At the same time, GFRP reinforced the coconut fibres with fly ash, and kenaf fibres with CaCO3 showed no favourable impact on water absorption. The identification of a hybrid GFRP composite with various reinforcing materials and fillers would assist future developments with a more compatible, enhanced, and reliable water-resistant composite, specifically for structural applications in flood-prone areas.

Impact of Drying Regimes and Different Coating Layers on Carboxymethyl Cellulose Cross-Linked with Citric Acid on Cotton Thread Fibers for Wound Dressing Modification.

The oldest preservation techniques used are drying techniques, which are employed to remove moisture and prevent microorganisms' growths, prolonging a material's shelf life. This study evaluates the effects of drying methods on carboxymethyl cellulose (CMC) + citric acid (CA) coating layers on cotton threads. For this reason, cotton threads were washed and then coated with different layers of CMC cross-linked with CA, followed by drying using an oven (OD), infrared (IR), and a combination of oven + IR (OIR) drying methods at 65 °C. Our investigations revealed that CMC + CA yields a pliable biopolymer. The differences in drying regimes and coating layers of CMC + CA have a significant effect on the coated cotton thread strength and absorption capability. The study concluded that the IR drying regime is more effective to dry a single-layered cotton thread with a single layer of CMC + CA coating to enhance desirable properties for wound dressing modification.

Regenerated Cellulose Products for Agricultural and Their Potential: A Review.

Cellulose is one of the most abundant natural polymers with excellent biocompatibility, non-toxicity, flexibility, and renewable source. Regenerated cellulose (RC) products result from the dissolution-regeneration process risen from solvent and anti-solvent reagents, respectively. The regeneration process changes the cellulose chain conformation from cellulose I to cellulose II, leads the structure to have more amorphous regions with improved crystallinity, and inclines towards extensive modification on the RC products such as hydrogel, aerogel, cryogel, xerogel, fibers, membrane, and thin film. Recently, RC products are accentuated to be used in the agriculture field to develop future sustainable agriculture as alternatives to conventional agriculture systems. However, different solvent types and production techniques have great influences on the end properties of RC products. Besides, the fabrication of RC products from solely RC lacks excellent mechanical characteristics. Thus, the flexibility of RC has allowed it to be homogenously blended with other materials to enhance the final products' properties. This review will summarize the properties and preparation of potential RC-based products that reflect its application to replace soil the plantation medium, govern the release of the fertilizer, provide protection on crops and act as biosensors.

Production of Rigid Polyurethane Foams Using Polyol from Liquefied Oil Palm Biomass: Variation of Isocyanate Indexes.

Development of polyurethane foam (PUF) containing bio-based components is a complex process that requires extensive studies. This work reports on the production of rigid PUFs from polyol obtained via liquefaction of oil palm empty fruit bunch (EFB) biomass with different isocyanate (NCO) indexes. The effect of the NCO index on the physical, chemical and compressive properties of the liquefied EFB-based PUF (EFBPUF) was evaluated. The EFBPUFs showed a unique set of properties at each NCO index. Foaming properties had affected the apparent density and cellular morphology of the EFBPUFs. Increasing NCO index had increased the crosslink density and dimensional stability of the EFBPUFs via formation of isocyanurates, which had also increased their thermal stability. Combination of both foaming properties and crosslink density of the EFBPUFs had influenced their respective compressive properties. The EFBPUF produced at the NCO index of 120 showed the optimum compressive strength and released the least toxic hydrogen cyanide (HCN) gas under thermal degradation. The normalized compressive strength of the EFBPUF at the NCO index of 120 is also comparable with the strength of the PUF produced using petrochemical polyol.

An improved physico-mechanical performance of macropores membrane made from synthesized cellulose carbamate.

Under hydrothermal condition, kenaf cellulose carbamate (KCC) was synthesized using urea and kenaf core pulp (KCP) without catalyst and organic solvent. The KCC was prepared with various urea/KCP ratios (2:1, to 4:1 and 6:1) with the aid of autoclave and oil bath, whereas the regenerated KCC membranes were formed via solution casting method. The physical and thermal properties of KCC were studied. The urea/KCP ratio used in preparing KCC corresponds with the nitrogen percentage obtained in KCC. The formation of the regenerated KCC membranes could be confirmed by the existence of cellulose II through X-ray diffraction (XRD) study. As examined by Field emission scanning electron microscope (FESEM), the regenerated KCC membranes possessed the greater pore size structures at higher urea concentration. Mechanical results showed the tensile strength and modulus of regenerated KCC membranes have improved up to 43.4% and 76.9%, respectively, as compared to native KCP membrane. It can be concluded from the findings that synthesizing KCC and its membranes with improved mechanical properties has broad prospects for potential industrial applications such as biomembranes and packaging materials.

Interconnected macropores cryogel with nano-thin crosslinked network regenerated cellulose.

Dissolved oil palm empty fruit bunch cellulose (EFBC) and sodium carboxymethylcellulose (NaCMC) were chemically crosslinked with epichlorohydrin (ECH) to generate designated hydrogel. After swelling process in distilled water, the swollen hydrogel was frozen and freeze-dried to form cryogel. The swelling phenomenon of hydrogel during the absorption process gave substantial effects on thinning of crosslinked network wall, pore size and volume, steadiness of cryogel skeletal structure, and re-swelling of cryogel. The swelling effects on hydrogel were confirmed via microscopic study using variable pressure scanning electron microscope (VPSEM). From the retrieved VPSEM images, nano-thin crosslinked network wall of 24.31 ± 1.97 nm and interconnected pores were observed. As a result, the amount of water, the swelling degree, and the freeze-drying process indirectly affected the VPSEM images that indicated pore size and volume, formation of interconnected pores, and re-swelling of cryogel. This study determined the intertwined factors that affected both hydrogel and cryogel properties by investigating the swelling phenomenon and its ensuing effects.

Superabsorbent hydrogel from oil palm empty fruit bunch cellulose and sodium carboxymethylcellulose.

A green regenerated superabsorbent hydrogel was fabricated with mixtures of dissolved oil palm empty fruit bunch (EFB) cellulose and sodium carboxymethylcellulose (NaCMC) in NaOH/urea system. The formation of hydrogel was aided with epichlorohydrin (ECH) as a crosslinker. The resultant regenerated hydrogel was able to swell >80,000% depending on the NaCMC concentrations. The hydrogel absorbed water rapidly upon exposure to water up to 48 h and gradually declined after 72 h. The crosslinked of covalent bond of COC between dissolved EFB cellulose (EFBC) with NaCMC was confirmed with Attenuated total reflectance Fourier transform infrared (ATR-FT-IR) spectroscopy. Crystallinity and thermal stability of the hydrogel samples were depended on the concentrations of NaCMC, crosslinking, and swelling process. The strength and stability of crosslinked network was studied by examining the gel fraction of hydrogel. This study explored the swelling ability and probable influenced factors towards physical and chemical properties of hydrogel.

Chemically crosslinked hydrogel and its driving force towards superabsorbent behaviour.

Dissolved oil palm empty fruit bunch (EFB) cellulose in NaOH/urea solvent was mixed with sodium carboxymethylcellulose (NaCMC) to form a green regenerated superabsorbent hydrogel. The effect of concentration of epichlorohydrin (ECH) as the crosslinker on the formation, physical, and chemical properties of hydrogel was studied. Rapid formation and higher gel content of hydrogel were observed at 10% concentration of ECH. The superabsorbent hydrogel was successfully fabricated in this study with the swelling ability >100,000%. Hydrogel with higher concentration of ECH showed opposite trend by having higher superabsorbent property than that of lower concentration. The covalent bond of COC was observed with Attenuated total reflectance fourier transform infrared (ATR-FT-IR) spectroscopy to confirm the occurrence of crosslinking. The physical and chemical properties of hydrogel were affected by swelling phenomenon. Hydrogel with higher degree of swelling exhibited lower moisture retention and higher transparency. Moreover, the weight of the superabsorbent hydrogel increased with the decrement of pH value of external media (distilled water). This study provided substantial information on the effect of different percentage of ECH as crosslinker on hydrogel basic properties. Furthermore, this study affords correlation of many essential driving forces that affected hydrogel superabsorbent property.