ABSTRACT
We report detailed investigations on the structural, magnetic, magneto-transport and calorimetric aspects of a partially ordered Heusler compound Pd2MnIn. The sample shows antiferomagnetic (AFM) state below around 120 K, though positive paramagnetic Curie temperature signifies a complex magnetic ground state with the presence of both ferromagnetic (FM) and AFM correlations. A clear spin-flop type metamagnetic transition is observed as evident from the magnetization and resistivity data. However, non-saturation of magnetization even at 145 kOe of applied field implies that the high field state may be a spin canted state, originating from the enhanced FM correlations by field induced conduction electron spin polarization. The sample shows a profound quadratic temperature dependence of resistivity below about 20-25 K indicating a spin-fluctuation dominated low temperature region. Previous electronic structure calculations show the existence of a subtle balance between superexchange mediated AFM state and an RKKY (Ruderman-Kittel-Kasuya-Yoshida) interaction mediated FM state in Pd2MnIn. Such competing AFM-FM correlations can be accounted for the observed spin fluctuations.
ABSTRACT
The observation of ultrasharp metamagnetic jumps in the field variation of magnetization (M versus H) data for the highly insulating metal oxide Er2Cu2O5 is investigated. The compound orders antiferromagnetically below about T N1 = 28 K and shows conventional 'not-so-sharp' metamagnetism around 13 kOe on the field-increasing leg in the polycrystalline sample. The uniqueness of the ultrasharp jumps in Er2Cu2O5 resides in the fact that they are only observed in the field-decreasing segment of the magnetization curve. We observe that the jumps are affected by the sweep rate of the magnetic field, similarly to several other systems that show such ultrasharp jumps. Er2Cu2O5 shows a considerable amount of thermo-remanent magnetization when it is cooled in a field that is higher than the critical field of 13 kOe. Our analysis indicates that above 13 kOe the system remains phase separated, with the coexistence of antiferromagnetic and field-induced ferromagnetic-like phases. The jumps in the return leg occur because of the shear-dominated martensitic-like phase transition of the ferromagnetic-like phase to an antiferromagnetic phase, and interfacial strain plays a major role in the observed jumps.
ABSTRACT
Both Ba4Mn3O10 and Sr4Mn3O10 crystallize in an orthorhombic crystal structure consisting of corrugated layers containing Mn3O12 polydedra. The thermal variation of magnetic susceptibility of the compositions consists of a broad hump like feature indicating the presence of low dimensional magnetic correlation. We have systematically investigated the magnetic data of these compounds and found that the experimental results match quite well with the two dimensional Heisenberg model of spin-spin interaction. The two dimensional nature of the magnetic spin-spin interaction is supported by the low temperature heat capacity data of Ba4Mn3O10. Interestingly, both the samples show dielectric anomaly near the magnetic ordering temperature indicating multiferroic behavior.
ABSTRACT
The mixed valent multiferroic compound CaMn7O12 is studied for its magnetic and electric properties. The compound undergoes magnetic ordering below 90 K with a helimagnetic structure followed by a low temperature magnetic anomaly observed around 43 K. This study shows that the magnetic anomaly at 43 K is associated with thermal hysteresis indicating the first order nature of the transition. The compound also shows field-cooled magnetic memory and relaxation below 43 K, although no zero-field-cooled memory is present. A clear magnetic hysteresis loop is present in the magnetization versus field measurements, signifying the presence of some ferromagnetic clusters in the system. We doped trivalent La at the site of divalent Ca expecting to enhance the fraction of Mn(3+) ions. The La doped samples show reduced magnetization, although the temperatures associated with the magnetic anomalies remain almost unaltered. Interestingly, the spontaneous electrical polarization below 90 K increases drastically on La substitution. We propose that the ground states of the pure as well as the La doped compositions contain isolated superparamagnetic like clusters, which can give rise to metastability in the form of field-cooled memory and relaxation. The ground state is certainly not spin glass type, as is evident from the absence of zero-field-cooled memory and frequency shift in the ac susceptibility measurements.
ABSTRACT
We report a diffuse phase transition (extending over a finite temperature range of â¼50 K) in sol-gel derived nanoparticles (â¼25 nm) of the ferromagnetic double perovskite La(2)NiMnO(6). The macroscopic polarization (P-E hysteresis loop), validity of the Vogel-Fulcher relation and high dielectric permittivity (â¼9 × 10(2)) confirm relaxor ferroelectric phenomena in these magnetic nanoparticles. Compared to the corresponding bulk sample, appreciably large enhancement of the magnetocapacitive effect (MC â¼ 30%) is observed even under low magnetic field (0.5 T) around the broad relaxor dielectric peak temperature (â¼220 K), which is close to the ferromagnetic transition temperature (θ(f) â¼ 196 K). All of these features establish the multiferroic character of the La(2)NiMnO(6) nanoparticles. The inhomogeneities arising from chemical and valence mixing in the present La(2)NiMnO(6) nanoparticles and the inter-site, Ni/Mn-site disorder along with surface disorder of the individual nanoparticles resulting in local polar regions are attributed to the observed dielectric behaviour of the nanoparticles. The wave vector dependent spin-pair correlation is considered to be the plausible cause of the colossal magnetocapacitive response near the transition temperature. High permittivity and large magnetocapacitive properties make these ferromagnetic La(2)NiMnO(6) nanoparticles technologically important.
