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1.
Environ Monit Assess ; 186(8): 5261-71, 2014 Aug.
Article in English | MEDLINE | ID: mdl-24788840

ABSTRACT

The goal of this study was to investigate the activity of the coagulant extracted from the cactus Opuntia ficus-indica (OFI) in the process of coagulation/flocculation of textile effluents. Preliminary tests of a kaolinite suspension achieved maximum turbidity removal of 95 % using an NaCl extraction solution. Optimization assays were conducted with actual effluents using the response surface methodology (RSM) based on the Box-Behnken experimental design. The responses of the variables FeCl3, dosage, cactus dosage, and pH in the removal of COD and turbidity from both effluents were investigated. The optimum conditions determined for jeans washing laundry effluent were the following: FeCl3 160 mg L(-1), cactus dosage 2.60 mg L(-1), and pH 5.0. For the fabric dyeing effluent, the optimum conditions were the following: FeCl3 640 mg L(-1), cactus dosage 160 mg L(-1), and pH 6.0. Investigation of the effects of the storage time and temperature of the cactus O. ficus-indica showed that coagulation efficiency was not significantly affected for storage at room temperature for up to 4 days.


Subject(s)
Industrial Waste/analysis , Opuntia/chemistry , Textiles , Waste Disposal, Fluid/methods , Water Pollutants, Chemical/chemistry , Coagulants/chemistry , Environmental Monitoring , Flocculation , Water Pollutants, Chemical/analysis , Water Purification/methods
2.
Environ Monit Assess ; 185(3): 2179-87, 2013 Mar.
Article in English | MEDLINE | ID: mdl-22638725

ABSTRACT

Textile industry wastes raise a great concern due to their strong coloration and toxicity. The objective of the present work was to characterize the degradation and mineralization of textile effluents by advanced oxidative processes using either TiO(2) or TiO(2)/H(2)O(2) and to monitor the toxicity of the products formed during 6-h irradiation in relation to that of the in natura effluent. The results demonstrated that the TiO(2)/H(2)O(2) association was more efficient in the mineralization of textile effluents than TiO(2), with high mineralized ion concentrations (NH (4) (+) , NO (3) (-) , and SO (4) (2-) ) and significantly decreased organic matter ratios (represented by the chemical oxygen demand and total organic carbon). The toxicity of the degradation products after 4-h irradiation to Artemia salina L. was not significant (below 10 %). However, the TiO(2)/H(2)O(2) association produced more toxicity under irradiation than the TiO(2) system, which was attributed to the increased presence of oxidants in the first group. Comparatively, the photogenerated products of both TiO(2) and the TiO(2)/H(2)O(2) association were less toxic than the in natura effluent.


Subject(s)
Industrial Waste , Waste Disposal, Fluid/methods , Water Pollutants, Chemical/toxicity , Water Purification/methods , Animals , Artemia , Hydrogen Peroxide/chemistry , Oxidants, Photochemical/chemistry , Photochemical Processes , Textile Industry , Titanium/chemistry , Toxicity Tests , Ultraviolet Rays , Water Pollutants, Chemical/chemistry
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