Ultrasound-assisted adsorption on porous ceramic for removal of iron in water.

This study proposes the use of an ultrasound-assisted adsorption system coupled to porous ceramic fragments to improve the removal of iron from FeSO4 aqueous solution. Ultrasound was applied using an ultrasound bath at a low frequency (37 kHz, 330 W). The optimized conditions for Fe removal were achieved by 7 g of adsorbent, 40 min of sonication, 20 mg L-1 of initial Fe concentration, and 30 °C of reaction temperature. After optimizing the conditions, the method was applied for the removal of iron in groundwater. A central composite design and response surface methodology were used to evaluate the degree to which different variables had a significant effect on iron removal. The efficiency of iron removal using the selected conditions for FeSO4 solution was near to 100%. However, for groundwater samples, the maximum iron removal efficiencies of the system with and without ultrasound were 80.7% and 51.1%, respectively, indicating that the adsorption with ultrasound was significantly higher than that without ultrasound. It was shown that the proposed ultrasound-assisted adsorption system can be used to enhance the removal of inorganic iron from groundwater.

Base oil recovery from waste lubricant oil by polar solvent extraction intensified by ultrasound.

This paper proposes a greener approach to the intensification of base oil recovery for truck engines (32,500 km of use) using ethanol, propan-2-ol, 2-methylpropan-1-ol, and butan-1-ol as solvents for the extraction of base oil, combining mechanical stirring (220 rpm) and ultrasound (25 °C, 24 kHz, and 400 W). The results indicated that the recovery yields of the base oil, using the mechanical stirring and ultrasound (MS-US) system, for ethanol, propan-2-ol, 2-methylpropan-1-ol, and butan-1-ol were approximately 3.1, 25.6, 71.6, and 85.5%, respectively. By contrast, the recovery yields using only mechanical stirring were 8.8, 28.9, 58.9, and 76.1%, respectively. The system with pre-extraction could effectively remove Ca (85.3-93.0%), Mg (67.2-82.9%), Na (31.7-62.5%), and Zn (0.0-71.7%). Finally, the results showed a reduction of almost 100% for the concentrations of Al, Cr, Fe, and Mo in the pre-extraction system. The mechanical stirring (5 min) and ultrasound (5 min) system were able to intensify the extraction process using environmentally friendly solvents.

Chloride determination by ion chromatography in petroleum coke after digestion by microwave-induced combustion.

Microwave-induced combustion was applied to petroleum coke digestion in closed vessels for further chloride determination by ion chromatography. Samples were pressed as pellets and placed on a quartz holder. Combustion was performed using oxygen pressure of 2 MPa and 50 microl of 6 moll(-1) NH(4)NO(3) as aid for ignition. Recoveries from 97 to 102% were obtained for all studied absorbing solutions (water, H(2)O(2), Na(2)CO(3) or (NH(4))(2)CO(3)). Accuracy was evaluated using certified reference materials with agreement better than 98% using water as absorbing solution with reflux step. The limit of quantification was 3.8 microg g(-1).

Jato de bicarbonato: o clínico necessita conhecê-lo melhor / Bicarbonate jet: the knwoledge of the clinic need

O uso do sistema abrasivo do bicarbonato mostrou-se efetivo nas áreas coronárias na remoçäo de placa bacteriana e manchas extrínsecas, quando comparou-se com a técnica convencional com taça de borracha e pedra-pomes. Entretanto o jato de bicarbonato removeu as manchas completamente mais rapidamente com menos fadiga para o operador. O sistema abrasivo sob microscopia mostrou-se näo injuriar o epitélio da gengiva marginal. Seu uso também verifica-se no tratamento da hipersensibilidade na área cervical com um menor desconforto para o paciente