Phenolic compounds in water: Review of occurrence, risk, and retention by membrane technology.

Phenolic compounds are one of the main contributors to water source contamination worldwide. In this review, the data collected on Elsevier, Scopus, and Pubmed, considering papers published between 2000 and 2023, showed more than 60 different phenols have been identified in water matrix (<0.065-179,000,000 ng L-1). The highest concentration reported was in surface water canals in India. The most recurrent and studied compound was bisphenol A (n = 93) in concentrations ranging from 0.45 to 2,970,000 ng L-1. The solid phase extraction (HBL Oasis cartridge) and methanol as solvent was the method of pre-concentration most used followed by gas chromatography for the determination of phenols in water samples. The importance of drinking water guidelines incorporating more phenolic compounds was emphasized given the variety of these compounds quantified in water matrix. The human health risk assessment (HRA) was performed for the min-max concentrations of the pollutants reported in the literature. High HRA even at the lowest concentrations for 2-nitrophenol, 2,6-dichlorophenol, 3,4,5-trichlorophenol, 2,3,4,6-tetrachlorophenol, and 2,4-dinitrophenol was recognized. The cancer risk estimated was considered possible for 3-methylphenol, 2,4-dimethylphenol, 2,4,6-trichlorophenol, pentachlorophenol, and 2,4-dinitrophenol in the highest concentrations. The in-depth discussion of mechanisms, advantages, challenges, and carbon footprint of membrane technologies in water treatment and phenols retention demonstrated the great potential and trends for the production of safe drinking water, highlighting reverse osmosis, as a mature technology, and membrane distillation, as an emergent technology.

Influence of humic substances on the landfill leachate biodegradability with a focus on temporal seasonality.

The high resilience to biological treatments from the landfill leachate is generally associated with the presence of humic substances (HS). The brown color characteristic of this effluent is also related to these substances. Landfill leachate with low biodegradability can make biological treatments unfeasible, which can drive up the cost for the treatment of large leachate volumes. In this context, this research aimed to characterize the leachate in different seasonal periods, and verify the influence of HS species on the biodegradability of the effluent to assist in the selection of adequate treatment techniques. The HS quantification was performed using the modified Lowry method and speciation through fractionation according to the molar masses of the HS species. The tropical regions can be the precursor for the rapid stabilization of biodegradable organic matter. The warmer climate contributed to a reduced BOD/COD ratio (0.03) and the predominance of compounds of lower mass (e.g.: fulvic acids). The tests showed an HS concentration of 26.9% of the total COD in the raw leachate in the rainy season, which increased to 37.3% in the dry season. Approximately 70% of HS species refer to fulvic acids, a fraction identified as having the highest biologic treatment resilience.

Hybrid MF and membrane bioreactor process applied towards water and indigo reuse from denim textile wastewater.

This work investigates the application of a microfiltration (MF)-membrane bioreactor (MBR) hybrid process for textile dyeing process wastewater reclamation. The indigo blue dye was efficiently retained by the MF membrane (100%), which allows its recovery from the concentrate stream. MF promotes 100% of colour removal, and reduces the chemical oxygen demand (COD) and conductivity by about 65% and 25%, respectively, and improves the wastewater biodegradability. MF flux decline was mostly attributed to concentration polarization and the chemical cleaning was efficient enough to recover initial hydraulic resistance. The MBR provides to be a stable process maintaining its COD and ammonia removal efficiency (73% and 100%, respectively) mostly constant throughout and producing a permeate that meets the reuse criteria for some industry activities, such as washing-off and equipment washdown. The use of an MF or ultrafiltration (UF) membrane in the MBR does not impact the MBR performance in terms of COD removal. Although the membrane of MBR-UF shows permeability lower than MBR-MF membrane, the UF membrane contributes to a more stable operation in terms of permeability.