Lanthanide molecular cluster-aggregates as the next generation of optical materials.

In this perspective, we provide an overview of the recent achievements in luminescent lanthanide-based molecular cluster-aggregates (MCAs) and illustrate why MCAs can be seen as the next generation of highly efficient optical materials. MCAs are high nuclearity compounds composed of rigid multinuclear metal cores encapsulated by organic ligands. The combination of high nuclearity and molecular structure makes MCAs an ideal class of compounds that can unify the properties of traditional nanoparticles and small molecules. By bridging the gap between both domains, MCAs intrinsically retain unique features with tremendous impacts on their optical properties. Although homometallic luminescent MCAs have been extensively studied since the late 1990s, it was only recently that heterometallic luminescent MCAs were pioneered as tunable luminescent materials. These heterometallic systems have shown tremendous impacts in areas such as anti-counterfeiting materials, luminescent thermometry, and molecular upconversion, thus representing a new generation of lanthanide-based optical materials.

Dual magnetic field and temperature optical probes of controlled crystalline phases in lanthanide-doped multi-shell nanoparticles.

The engineering of core@multi-shell nanoparticles containing heterogeneous crystalline phases in different layers constitutes an important strategy for obtaining optical probes. The possibility of obtaining an opto-magnetic core@multi-shell nanoparticle capable of emitting in the visible and near-infrared ranges by upconversion and downshifting processes is highly desirable, especially when its optical responses are dependent on temperature and magnetic field variations. This work proposes the synthesis of hierarchically structured core@multi-shell nanoparticles of heterogeneous crystalline phases: a cubic core containing DyIII ions responsible for magnetic properties and optically active hexagonal shells, where ErIII, YbIII, and NdIII ions were distributed. This system shows at least three excitation energies located at different biological windows, and its emission intensities are sensitive to temperature and external magnetic field variations. The selected crystalline phases of the core@multi-shell nanoparticles obtained in this work is fundamental to the development of multifunctional materials with potential applications as temperature and magnetic field optical probes.