Geochemical behavior of rare earth elements in agricultural soils along the Syr Darya River within the Aral Sea Basin.

The widespread use of rare earth elements (REEs) across various industries makes them a new type of pollutant. Additionally, REEs are powerful indicators of geochemical processes. As one of the two main rivers in the Aral Sea, identifying the geochemical behavior of REEs in agricultural soils of the Syr Darya River is of great significance for subsequent indicative studies. In this study, the geochemical characteristics, influencing factors, and potential application significance of REEs in agricultural soils from three sampling areas along the Syr Darya River were analyzed using soil geography and elemental geochemical analyses. The results showed that the highest total concentration of REEs in the agricultural soil was in Area I, with a mean value of 142.49 µg/g, followed by Area III with a mean value of 124.56 µg/g, and the lowest concentration was in Area II with a mean value of 122.48 µg/g. The agricultural soils in the three regions were enriched in light rare earth elements (LREEs), with mean L/H values of 10.54, 10.13, and 10.24, respectively. The differentiation between light and heavy rare earth elements (HREEs) was also high. The concentration of REEs in agricultural soil along the Syr Darya River was primarily influenced by minerals such as monazite and zircon, rather than human activities (the pollution index of all REEs was less than 1.5). The relationship between Sm and Gd can differentiate soils impacted by agricultural activities from natural background soils. The results of this study can serve as a basis for indicative studies of REEs in Central Asia.

Identifying Seasonal and Diurnal Variations and the Most Frequently Impacted Zone of Aerosols in the Aral Sea Region.

With the desiccation of the Aral Sea, salt-alkali dust storms have increased in frequency and the surrounding environment has deteriorated. In order to increase our understanding of the characteristics and potential impact zone of atmospheric aerosols in the Aral Sea region, we evaluated seasonal and diurnal variation of aerosols and identified the zone most frequently impacted by aerosols from the Aral Sea region using CALIPSO data and the HYSPLIT model. The results showed that polluted dust and dust were the two most commonly observed aerosol subtypes in the Aral Sea region with the two accounting for over 75% of observed aerosols. Occurrence frequencies of polluted dust, clean continental, polluted continental/smoke, and elevated smoke showed obvious seasonal and diurnal variations, while occurrence frequency of dust only showed obvious seasonal variation. Vertically, the occurrence frequencies of all aerosol subtypes except dust showed significant diurnal variation at all levels. The thickness of polluted dust layers and dust layers exhibited same seasonal and diurnal variations with a value of more than 1.0 km year-round, and the layer thickness of clean continental and polluted continental/smoke shared the same seasonal and diurnal variation features. The zone most severely impacted by aerosols from the Aral Sea region, covering an area of approximately 2 million km2, was mainly distributed in the vicinity of the Aral Sea region, including western Kazakhstan, and most of Uzbekistan and Turkmenistan. The results provide direct support for positioning monitoring of aeolian dust deposition and human health protection in the Aral Sea region.

Spatial and Vertical Variations and Heavy Metal Enrichments in Irrigated Soils of the Syr Darya River Watershed, Aral Sea Basin, Kazakhstan.

In the Syr Darya River watershed, 225 samples from three different layers in 75 soil profiles were collected from irrigated areas in three different spatial regions (I: n = 29; II: n = 17; III: n = 29), and the spatial and vertical variation characteristics of potentially toxic elements (Cd, Co, Cu, Ni, and Zn) and a metallic element (Mn) were studied. The human health risks and enrichment factors were also evaluated in the Syr Darya River watershed of the Aral Sea Basin in Kazakhstan. There were significant differences in the contents of heavy metals in the different soil layers in the different sampling regions. Based on element variation similarity revealed by hierarchical cluster analysis, the elemental groupings were consistent in the different layers only in region I. For regions II and III, the clustered elemental groups were the same between surface layer A and B, but differed from those in the deep layer C. In sampling region I, the heavy metals in surface soils were significantly correlated with the ones in deep layers, reflecting that they were mainly affected by the elemental composition of parent materials. In region II, the significant correlations only existed for Cu, Mn, and Zn between the surface and deep layers. The similar phenomenon with significant correlation was also observed for heavy metals in sampling region III, except for Cd. Finally, enrichment factor was used to study the mobilization and enrichment of potentially toxic elements. The enrichment factors of Zn, Cu, and Cd in surface layer A that were greater than 1.5 accounted for 1.16%, 6.79%, and 24.36% of sampling region I, respectively. In sampling region II, the enrichment factors of Zn, Cu, Cd, and Co that were greater than 1.5 accounted for 0.03%, 4.76%, 0.54%, and 9.03% of the total area, respectively. In sampling region III, only the enrichment factors of Zn, Cu, and Cd that exceeded 1.5 accounted for 0.24%, 4.90%, and 6.89% of the total area, respectively. Although the contents of the heavy metals were not harmful to human health, the effects of human activities on the heavy metals in the irrigated soils revealed by enrichment factors have been shown in this study area.

Hydrochemical characteristics and irrigation suitability of surface water in the Syr Darya River, Kazakhstan.

The surface water hydrochemistry of the Syr Darya River in Kazakhstan was investigated at 39 locations to analyze regional hydrochemical characteristics and evaluate the irrigation suitability of the studied regions. The cations in the surface water are mainly Na+, Ca2+, and Mg2+, while the anions are mainly SO42-. The main hydrochemical type is Ca-Mg-SO4-Cl. From the perspective of natural factors, the hydrochemical characteristics in the study area are derived from the dual effects of rock weathering and evaporation-concentration; however, the influence of anthropogenic factors include industrial and agricultural production near the river and the inflow of urban domestic sewage on the hydrochemical characteristic is also present. The irrigation suitability evaluation of the surface water based on SAR, Na% and KI showed that the majority of the water is suitable for irrigation, and from the TDS content analysis, 71.43% of the samples are in a critical state, indicating that the influence of TDS concentration on irrigation suitability cannot be ignored. The results have practical significance for maintaining the sustainable use of water resources in the Syr Darya River.