Recent developments on sustainable biobutanol production: a novel integrative review.

Renewable and sustainable biofuel production, such as biobutanol, is becoming increasingly popular as a substitute for non-renewable and depleted petrol fuel. Many researchers have studied how to produce butanol cheaply by considering appropriate feedstock materials and bioprocess technologies. The production of biobutanol through acetone-butanol-ethanol (ABE) is highly sought after around the world because of its sustainable supply and lack of competition with food. The purpose of this study is to present the current biobutanol production research and to analyse the biobutanol research conducted during 2006 to 2023. The keyword used in this study is "Biobutanol," and the relevant data was extracted from the Web of Science database (WoS). According to the results, institutions and scholars from the People's Republic of China, the USA, and India have the highest number of cited papers across a broad spectrum of topics including acetone-butanol-ethanol (ABE) fermentation, biobutanol, various pretreatment techniques, and pervaporation. The success of biobutanol fermentation from biomass depends on the ability of the fermentation operation to match the microbial behaviour along with the appropriate bioprocessing strategies to improve the entire process to be suitable for industrial scale. Based on the review data, we will look at the biobutanol technologies and appropriate strategies that have been developed to improve biobutanol production from renewable biomass.

Comprehensive review on toxic heavy metals in the aquatic system: sources, identification, treatment strategies, and health risk assessment.

Heavy metal pollution in water sources has become a major worldwide environmental issue, posing a threat to aquatic ecosystems and human health. The pollution of the aquatic environment is increasing as a result of industrialization, climate change, and urban development. The sources of heavy metal pollution in water include mining waste, leachates from landfills, municipal and industrial wastewater, urban runoff, and natural events such as volcanism, weathering, and rock abrasion. Heavy metal ions are toxic and potentially carcinogenic. They can also buildup in biological systems and cause bioaccumulation even at low levels of exposure, heavy metals can cause harm to organs such as the nervous system, liver and lungs, kidneys and stomach, skin, and reproductive systems. There were various approaches tried to purify water and maintain water quality. The main purpose of this article was to investigate the occurrence and fate of the dangerous contaminants (Heavy metal and metalloids) found in domestic and industrial effluents. This effluent mixes with other water streams and is used for agricultural activities and other domestic activities further complicating the issue. It also discussed conventional and non-conventional treatment methods for heavy metals from aquatic environments. Conclusively, a pollution assessment of heavy metals and a human health risk assessment of heavy metals in water resources have been explained. In addition, there have been efforts to focus on heavy metal sequestration from industrial waste streams and to create a scientific framework for reducing heavy metal discharges into the aquatic environment.

Status and future trends in wastewater management strategies using artificial intelligence and machine learning techniques.

The two main things needed to fulfill the world's impending need for water in the face of the widespread water crisis are collecting water and recycling. To do this, the present study has placed a greater focus on water management strategies used in a variety of contexts areas. To distribute water effectively, save it, and satisfy water quality requirements for a variety of uses, it is imperative to apply intelligent water management mechanisms while keeping in mind the population density index. The present review unveiled the latest trends in water and wastewater recycling, utilizing several Artificial Intelligence (AI) and machine learning (ML) techniques for distribution, rainfall collection, and control of irrigation models. The data collected for these purposes are unique and comes in different forms. An efficient water management system could be developed with the use of AI, Deep Learning (DL), and the Internet of Things (IoT) structure. This study has investigated several water management methodologies using AI, DL and IoT with case studies and sample statistical assessment, to provide an efficient framework for water management.

A comprehensive review on bio-stimulation and bio-enhancement towards remediation of heavy metals degeneration.

Pollution of heavy metals is one of the risky contaminations that should be managed for all intents and purposes of general well-being concerns. The bioaccumulation of these heavy metals inside our bodies and pecking orders will influence our people in the future. Bioremediation is a bio-mechanism where residing organic entities use and reuse the squanders that are reused to one more form. This could be accomplished by taking advantage of the property of explicit biomolecules or biomass that is equipped for restricting by concentrating the necessary heavy metal particles. The microorganisms can't obliterate the metal yet can change it into a less harmful substance. In this unique circumstance, this review talks about the sources, poisonousness, impacts, and bioremediation strategies of five heavy metals: lead, mercury, arsenic, chromium, and manganese. The concentrations here are the ordinary strategies for bioremediation such as biosorption methods, the use of microbes, green growth, and organisms, etc. This review demonstrates the toxicity of heavy metal contamination degradation by biotransformation through bacterioremediation and biodegradation through mycoremediation.

Identifying global status and research hotspots of heavy metal remediation: A phase upgrade study.

Impact of heavy metal (HM) pollution and its understanding on environment as well as human beings has grown a lot during the last few decades. The goal of this study is to create a scientometric study on heavy metal contamination, in the period 1989 to 2020, in order to provide futuristic goals for the new researchers on wastewater treatment. For this, a search was conducted in the Web of Science (WoS) and Scopus databases, related to heavy metal pollution. Totally, 37,154 records were collected during the study period from 1989 to 2020. The findings revealed that China, the United States, and India has most referenced papers across a wide range of trans disciplinary issues such as toxicity, technology, and pollution. As a result, this study concludes that more research on various treatment methods is required in order to obtain high-quality water for consumption and routine activities, with the incorporation of various treatment tasks poses various challenges for the upcoming future studies.

Effect of green synthesized nano-titanium synthesized from Trachyspermum ammi extract on seed germination of Vigna radiate.

The current work investigates the conditional influence on Vigna radiate seed germination in vitro and in vivo using the green chemistry approach for the manufacture of titanium dioxide nanoparticles (TiO2 NPs) from seed extract of Trachyspermum ammi (T. ammi). Ultraviolet spectroscopy (UV-Vis), Fourier transform infrared spectroscopy (FTIR), Transmission electron microscopy (TEM), and X-ray diffraction (XRD) were used to analyze the TiO2 NPs produced. The crystalline nature of TiO2 NP was revealed by XRD data, and TEM investigation revealed an irregularity in TiO2 NP shape with a size of 17.5 nm. UV absorbance at 315 nm for the TiO2 NPs was observed using Ultraviolet-visible spectrophotometer. The antioxidant potential of the synthesized nanoparticle was discovered to be good. In case of seed germination studies, six concentrations (25, 50 100, 150, 200, and 250 µg mL- 1) of TiO2 NPs were examined along with the control on Vigna radiata seeds. Germination parameters such as seed vigor index (SVI), germination percentage (GP), germination value (GV) root length (RL) and shoot length (SL) of the Vigna radiata seedlings were observed and results revealed that the green synthesized TiO2 NPs were significantly improved. The results indicated that the TiO2 NP affected the plant growth more specifically at lower concentration (50 µg mL-1) of TiO2 NPs. Overall, the findings of this present study stipulated that the green TiO2 NP production can enhance the growth of Vigna radiate under in vitro and in vivo conditions.

Green synthesis of titanium dioxide nanoparticles using plant biomass and their applications- A review.

Biosynthesized nanoparticles have sparked a lot of interest as rapidly growing classes of materials for different applications. Plants are considered to be one of the most suitable sources for Green synthesis (GS) as they follow the environment-friendly route of biosynthesis of nanoparticles (NPs). This article focuses on the excavation of Titanium dioxide (TiO2) NP from different parts of plants belonging to a distinct classification of taxonomic groups. During the process of biological synthesis of titanium NPs from plants, the extract derived from plant sources such as from root, stem, leaves, seeds, flowers, and latex possesses phytocompounds that tend to serve as both capping as well as reducing agents. TiO2NP is one of the most commonly used engineered nanomaterials in nanotechnology-based consumer products. This article will provide an overview of the GS and characterization of TiO2NPs from plant extracts of different taxonomic groups. Lastly, this review summarizes the current applications of TiO2NPs.

Synthesis of magnesium nanocomposites decked with multilayer graphene (MG) and its application for the adsorptive removal of pollutant.

Fossil fuel burning is the exclusive of key causes for greenhouse fume Carbon dioxide (CO2). Magnesium nanocomposites synthesized in combination with graphene were characterized and their performance in adsorbing CO2 is validated. The novelty of this work is the use of magnesium oxide decked MG to capture CO2. The magnesium nanocomposites decked with multilayer graphene (MG) were prepared using a simple combustion process. BET surface area of 1480 m2g-1 makes it desirable for adsorbing CO2 molecules. FTIR analysis after adsorption of CO2 shows peak mid position at 3470.45 cm-1, 1300-1000 cm-1, 1603 cm-1, and 1114.30 cm-1 corresponding to the functional groups R-C-O, R-OH, R-COOH, -alkyne, Si-O-Si, and R-C-O-H shifted, signifying that chemisorption has taken place. The effect of many experimental parameters like adsorbent mass, period, and concentration of CO2 was optimized during the experiments. A maximum of 92.2% of CO2 was adsorbed at a concentration of 5 × 10- 4 M at the optimum contact of 70 min. During the experiment, the saturation point was attained at 70 min. Experiment results were best fitting to Langmuir adsorption isotherm; the maximum monolayer adsorption capacity of MG was 7.067 × 10-3 mol/g/min. The kinetics of CO2 on MG was labeled by Pseudo-second-order and R2 value nearly 0.988.

Impact of Erbium (Er) and Yttrium (Y) doping on BiVO4 crystal structure towards the enhancement of photoelectrochemical water splitting and photocatalytic performance.

An efficient BiVO4nanocatalyst with Erbium (Er) and Yttrium (Y) doping was synthesized via a facile microwave irradiation route and the obtained materials were further characterized through various techniques such as p-XRD, FT-IR, FE-SEM, HR-TEM, UV-Vis DRS, PL, LSV, and EISanalysis. The obtained results revealed that the rare metals induce the stabilization of the monoclinic-tetragonal crystalline structure with a distinct morphology. The yttrium doped BiVO4 (Y-BiVO4) monoclinic-tetragonal exhibited anefficient photoelectrochemical water splitting and photocatalytic performanceare compared to bare BiVO4. TheY-BiVO4 indicated increased results of photocurrent of 0.43 mA/cm2and bare BiVO40.24 mA/cm2. Also, the Y-doped BiVO4 nanocatalyst showed the maximum photocatalytic activity for the degradation of MB, MO, and RhB. A maximum degradation of 93%, 85%, and 91% was achieved for MB, MO, and RhB respectively, within 180 min under the visible light illumination. The photocatalytic decomposition of acetaldehyde also was performed. The improved photoelectrochemical water splitting and photocatalytic activity are due to the narrowing the bandgap, leading to extending the photoabsorption capability and reducing the recombination rate of photoexcited electron-hole pairs through the formation inner energy state of the rare earth metals. The current study disclosed that the synthesis of nanomaterials with crystal modification could be a prospectivecontender forhydrogen energy production as well as to the photocatalytic degradation of organic pollutants.To the best of our knowledge, both photocatalytic and photoelectrochemical studies were never been reported before for this type of material.

Bibliometric analysis and recent trends on MXene research - A comprehensive review.

MXene, identified as a high performance material with superior properties, has gained significant importance in the field of applications including energy storage, photo catalysis, sensing of components and environmental pollution control. This review article is a comprehensive study on scientometric review on the research studies involving MXene and its derivatives for various applications. The aim of this study is to identify the areas of priority focused during the study period (2012-2020) and evaluate the impact of the studies in terms of different parameters. Using the suitable key words, a total of 3332 documents are identified and screened with respect to yearly count of literature, type of literature, language of publication, authors, Web of science (WoS) categories, most cited literature, author contribution, name of the affiliated institution, country of author affiliation, journals and key words. In addition, collaboration behavior and citation network are reviewed using the mapping tool. The total local citation score (TLCS) and total global citation score (TGCS) are evaluated. Based on the review data, the developments in the field of MXene applications are presented with more focus on sensing applications and photocatalysis. The top two contributing countries in the chosen field of MXene research are China and USA. Based on the number of documents published, ACS Applied Materials & Interfaces and Journal of Materials Chemistry "A" are identified as the best two journals.

Methods of synthesis, characteristics, and environmental applications of MXene: A comprehensive review.

MXene, comprised of two-dimensional transition metal carbides/nitride, has emerged as a novel material suitable for environmental remediation of toxic compounds. Due to their inherent and superior physical and chemical properties, MXene is employed in separation techniques like photocatalysis, adsorption, and membrane separation. MXene is equipped with a highly hydrophilic surface, ion exchange property, and robust surface functional groups. In this review paper, a comprehensive discussion on the structural patterns, preparation, properties of MXene and its application for the removal of toxic pollutants like Radionuclide, Uranium, Thorium, and dyes is presented. The mechanism of removal of the pollutants by MXene is extensively reviewed. Synthesis of MXene based membranes, their properties, and application for water purification and properties were also discussed. This review will be highly helpful to understand critically the methods of synthesis and use of MXene material for priority environmental pollutants removal. In addition, the challenges behind the synthesis and use of MXene for decontamination of pollutants were reviewed and reported.

Facile synthesis and characterization of microporous-structured activated carbon from agro waste materials and its application for CO2 capture.

Biomass-derived activated carbon was prepared from the agro waste materials, (wild sugarcane (WS) and saw dust (SD)) by chemical activation using phosphoric acid. The crystallinity, morphology, functional groups of the synthesized activated carbon were investigated. The effects of contact time (10-60 min), mass of adsorbent (0.05-0.2 g) and concentrations of CO2 (1 × 10-4 to 10 × 10-4 M) were analysed and the optimum adsorption conditions were found. Freundlich, Langmuir, Temkin, Dubinin-Radushkevich and Sips isotherm were used to analyse the adsorption data. The adsorption process was fitted with the Freundlich model. Adsorption capacity of agro waste-based sorbent was 5.225 × 10-3 mol/g. Thermodynamic parameters, such as ΔH0, ΔG0, ΔS0 , were calculated and it was found that the present system was a spontaneous process. From the kinetic studies, it was inferred that the Pseudo-second-order kinetics describes the kinetics of CO2 on AC-WSSD with an equilibrium point attained at 50 minutes with a high R2 value of 0.9602. The Brunauer Emmett Teller (BET) surface area of 1220 m2/g and an iodine value of 1360 m2/g were better indications for adsorption process. The interaction between CO2 and functional groups on the surface of the activated carbon was confirmed by FTIR. Desorption studies were carried out for three cycles with an efficiency of 93.2%.