Perfluorooctanoic acid in the sediment matrices of Arctic fjords, Svalbard.

Per- and polyfluorinated chemicals (PFASs) are very toxic industrial compounds, and fewer studies have been conducted on their presence in the sedimentary environment of the polar region. The present study is a preliminary assessment of the concentration and distribution of PFOA (Perfluorooctanoic acid) in selected fjord systems of the Svalbard archipelago, Norwegian Arctic. The ∑PFOA observed for Smeerenburgfjorden, Krossfjorden, Kongsfjorden Hotmiltonbuktafjorden, Raudfjorden and Magdalenefjorden were 1.28 ng/g, 0.14 ng/g, 0.68 ng/g, 6.54 ng/g, 0.41 ng/g and BDL respectively. Of the twenty-three fjord samples studied, the sediments from Hotmiltonbuktafjorden exhibited the presence of a higher concentration of PFOA in the sediment matrices. More studies are needed to understand their fate in the sedimentary environment with respect to the physio-chemical properties of the sediments.

PCDD/Fs, dioxin-like, and non-dioxin like PCBs in the sediments of high Arctic fjords, Svalbard.

Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) are highly toxic organic compounds, and very few studies on their presence in polar environments have been conducted. This study assessed the concentration and distribution of PCDD/Fs, dioxin-like polychlorinated biphenyls (DL-PCBs), and non-dioxin-like polychlorinated biphenyls in selected fjords of the Svalbard archipelago in Norway. The ∑PCDD/Fs observed for Raudfjorden, Smeerenburgfjorden, Magdalenefjorden, and Kongsfjorden were 22.80 pg/g, 25.65 pg/g, 18.27 pg/g, 33.50 pg/g, and 21.69 pg/g, respectively. The WHO's toxic equivalents values of both ∑PCDD/Fs and ∑DL-PCBs were comparatively higher than those reported in other polar regions. Of the four fjords studied, the sediments from Kongsfjorden exhibited the presence of the most toxic materials, including PCB-126 and PCB-169, of DL-PCBs. More than 80% of the total analysed PCDD/Fs were comprised of highly chlorinated congeners (hexa-to-octa forms). More studies are required to understand the destination and transport of these hazardous pollutants in high Arctic sediments.